• Title/Summary/Keyword: rheological equation of state

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Shear stress analysis of phosphorylated potato starch based electrorheological fluid

  • Hong, Cheng-Hai;Choi, Hyoung-Jin
    • Korea-Australia Rheology Journal
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    • v.19 no.4
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    • pp.221-225
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    • 2007
  • Electrorheological characteristics of a dispersed system of phosphorylated potato starch particles in silicone oil investigated via a rotational rheometer equipped with a high voltage generator is being reanalysized. Flow curves of these ER fluids both under several applied electric field strengths and with different degrees of phosphate substitution were mainly examined via three different rheological constitutive equations of Bingham model, De Kee-Turcotte model and our previously proposed CCJ model. Among these, the CCJ equation was found to fit the data of phosphorylated potato starch well.

Performance Analysis of a Semi-Active Variable Damper Featuring Electro-Rheological Fluids (ER 유체를 이용한 반능동식 가변댐퍼의 성능해석)

  • 최승복;정재천;최용빈;허승진;서문석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.1 no.1
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    • pp.90-100
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    • 1993
  • This paper presents some inherent characteristics of a semi-active variable damper featuring electro-rheological (ER) fluid. The damping force of the damper can be selectively adjusted or controlled by employing electric field to the ER fluid domain. This is possible owing to the pressure drop across the piston occured by field-dependent variable yield stress of the ER fluid. This is fundamentally different than the performance of a conventional adjustable viscous damper. To demonstrate the effectiveness and superiority over the conventional one, the proposed damper is incorporated with a suspension system. A quarter car model with the suspension system is formulated and represented by a state equation. By choosing numerical values based on realistic package size, power requirements and suitable ER properties, the performance characteristics of the suspension system are obtained and evaluated in both frequency and time domains. The effects of constant electric field and on-off controlled electric field which relates to the damping force are also examined.

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Studies on Semisolid Infant Foods (III)-Rheological Properties of the Products- (반고체 이유보충식에 관한 연구 (III)-생물학적 조사-)

  • 이영춘
    • Journal of Nutrition and Health
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    • v.19 no.1
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    • pp.3-15
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    • 1986
  • This study was intended to investigate the rheological properties of the development formula of infant foods and the results are summarized as follow ; 1) Consistency of starch solutions measured by Brabender Anylograph and Brookfield viscometer showed that waxy rice and riece with malt had lower consistency and more rheological stability.The flow type of tested raw materials and formula was found to ? pseudoplastic, as judged by n-value of 0.332 -0.692, and no yield value. 2) The influenced of temperature on consistency could be accounted for by the equation, In (n) = K(1/T) + const. this relationship indicated that consistency of tested sample increased as temperature decreased. The consistency of waxy rice, rice with malt and formula A were less affected by the temperature change. 3) Infant foods with malt(formula A ) ad with waxy rice maintained better freeze-thaw stability in terms of consistency and starch aggregation indicating that this infant food could be stored for a long term in the freezer section of the home refrigeratory without adverse effect on the product quality. 4) From the above experiments, it would necessarily follow that infant food can be easily made at home the food-stuffs generally available around us, and that the easiest and safest way to store them lies in making them into semisolid state, and in keeping them in frozen state.

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RHEOLOGICAL PROPERTIES OF MAGNETIC PARTICLE SUSPENSIONS

  • Kwon, T.M.;Choi, H.J.;Jhon, M.S.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.667-671
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    • 1995
  • The viscometric technique is used to study the effects of microstructure on the viscosity (viscosity vs. concentration or shear rate) of magnetic particle suspensions. In this characterization, measurement of suspension viscosity is used to obtain the dependence of viscous energy dissipation on microstructural state of dispersions. Microstructural shape effects which are related to particle orientation are then indirectly obtained. Empirical formulas from mean field theory and the Mooney equation, which are applicable at high concentration of magnetic particles, are used to relate viscosity to particle concentration. The validity and physical meaning of these equations are discussed.

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Dynamic Rheological Properties of Honey with Invert Sugar by Small-Amplitude Oscillatory Measurements

  • Choi, Hye-Mi;Kang, Kyoung-Mo;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • v.16 no.4
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    • pp.610-614
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    • 2007
  • Dynamic rheological properties of honeys with invert sugar at different mixing ratios of honey and invert sugar (10/0, 812, and 6/4 ratios) were evaluated at various low temperatures (-15, -10, -5, and $0^{\circ}C$) using a controlled stress rheometer for small-deformation oscillatory measurements. Honey-invert sugar mixtures displayed a liquid-like behavior, with loss modulus (G") predominating over storage modulus (G') (G">>G'), showing the high dependence on frequency (${\omega}$). The magnitudes of G' and G" increased with a decrease in temperature while their predominant increases were noticed at -10 and $-15^{\circ}C$. The greater tan ${\delta}$ values were found at higher temperature and ratio of honey to invert sugar, indicating that the honey samples at subzero temperatures become more viscous with increased ratio of honey to invert sugar and temperature. The time-temperature superposition (TTS) principle was used to bring G" values at various temperatures together into a single master curve. The TTS principle was suitable for the honey samples in the liquid-like state. The progress of viscous property (G") was also described well by the Arrhenius equation with high determination coefficients ($R^2=0.99$). Dynamic rheological properties of honey samples seem to be greatly influenced by the addition of invert sugar.

Reaction Kinetics and Morphological Changes at Polymer-polymer Interface measured by Rheological Properties (유변학적 성질 측정으로 측정한 고분자 계면에서의 반응 kinetics와 morphology 변화)

  • Kim, Hwang-Yong;Unyong Jeong;Kim, Jin-Kon
    • Proceedings of the Korean Society of Rheology Conference
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    • 2002.05a
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    • pp.25-27
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    • 2002
  • In this study we investigated the reaction kinetics by a convenient but useful method-rheology to characterize the interface between two immiscible blends with a Reactive compatibilizer. Also, we made an attempt to correlate changes of interface roughness with rheological properties. The blend systems employed in this study was mono-carboxylated polystyrene (PS-mCOOH) and an poly(methyl methacrylate-ran-glycidylmethacrylate) (PMMA-GMA). PS-mCOOH was synthesized by an anionic polymerization and PMMA-GMA by a free radical polymerization. We prepared two plates of each polymer using compression molding with a smooth surface molder, then put one upon another. As soon as these two plates welds together inside a rheometer under nitrogen environment, the torque and moduli were obtained with reaction time at different temperatures. Through the analysis of this modulus change with reaction time, we estimated interfacial reaction and roughening. The increment of modulus in initial state can be correlated to the extent of reaction. We obtained the reaction kinetic constant by fitting appropriate kinetic equation into experimental data. We also showed that increment of modulus in later state was due to by roughened interface.

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Control of Automatic Cargo Handling System Using ER Valves (II) -Modeling and Control of Cargo Handling System- (ER밸브를 이용한 자동 하역 시스템의 제어 (II) -하역시스템의 모델링 및 제어-)

  • Sung, Kum-Kil;Chung, Dar-Do;Choi, Seung-Bok
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.9
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    • pp.53-60
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    • 2001
  • This paper presents a position control of a platform at the seaport cargo handling system. After brief description of the operating principles of the cargo handling system, the governing equation of the moving platform is derived. The equation is described in the state space model, and a robust H$_{\infty}$ controller to achieve position tracking of the moving platform. which can carry 200ton of containers, is formulated. In the synthesis of the controller, the weight of the container is treated as uncertain parameter. Both regulating and tracking control responses are analyzed for the loading and unloading procedures of the proposed automatic cargo handling system.

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Rheological Characterization of Dextran Solution (DEXTRAN 용액의 유동학적 특성)

  • Kim, Nam-Hie;Lee, Hyang-Aee
    • YAKHAK HOEJI
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    • v.32 no.1
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    • pp.86-94
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    • 1988
  • Some rheological properties of subfractions for dextran in the molecular weights range from $3{\times}10^4$ to $2{\times}10^6$ was investigated at room temperature. The dependence of the viscosity on concentration, shear rate, pH & ionic strength, temperature and solvent effect was observed. From the experimental data the Mark-Houwink viscosity equation in water at $25^{\circ}C$ was determined for samples having the molecular weight ranging from $3{\times}10^4$ to $2{\times}10^6$ as$[{\eta}]=3.1{\times}10^{-3}\;Mw^{0.39}(in\;dl/g)$. The intrinsic stiffness of the dextran backbone was estimated by evaluating the 'characteristic ratio' $C_{\infty}$, which is below the 0.082. In the concentrated region, the viscosity was decreased with increasing shear rate and was exponentially decreased with raising temperature, the viscosity showed the maximum value at neutral condition. From the experimental data, it was concluded that dextran chain, linked by the ${\alpha}-1$, 6-glucosidic linkage, behaves like a flexible random coil chain in aqueous solution, dextran solutions were pseudoplastic power law fluids among the empirical models of non-Newtonian behavior. Urea was an active reagent which increases the viscosity and swells dextran while pyrididine and glycerol were inactive reagents. Also, it could be estimated that the formation of gel structure is promote to the neutral state, the molecular weight larger than $2{\times}10^5$, when electrolytic concentration is IN and Ureas is use to solvent.

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A novel modeling of settlement of foundations in permafrost regions

  • Wang, Songhe;Qi, Jilin;Yu, Fan;Liu, Fengyin
    • Geomechanics and Engineering
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    • v.10 no.2
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    • pp.225-245
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    • 2016
  • Settlement of foundations in permafrost regions primarily results from three physical and mechanical processes such as thaw consolidation of permafrost layer, creep of warm frozen soils and the additional deformation of seasonal active layer induced by freeze-thaw cycling. This paper firstly establishes theoretical models for the three sources of settlement including a statistical damage model for soils which experience cyclic freeze-thaw, a large strain thaw consolidation theory incorporating a modified Richards' equation and a Drucker-Prager yield criterion, as well as a simple rheological element based creep model for frozen soils. A novel numerical method was proposed for live computation of thaw consolidation, creep and freeze-thaw cycling in corresponding domains which vary with heat budget in frozen ground. It was then numerically implemented in the FISH language on the FLAC platform and verified by freeze-thaw tests on sandy clay. Results indicate that the calculated results agree well with the measured data. Finally a model test carried out on a half embankment in laboratory was modeled.

Computer Simulation for the Cavitation Changes at the Exit of Offset Printing Nip (오프셋 인쇄의 틈새출구에서 공동의 변화에 대한 시뮬레이션)

  • Youn, Jong-Tae;Kim, Yun-Taek;Lim, Soo-Man
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.3
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    • pp.1-10
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    • 2014
  • Offset paper printing is a promising roll-to-roll technique for color printed materials. Although it is no doubt that understanding ink transfer mechanism in offset printing process is necessary to achieve high printing quality, investing the relationship between inks and substrates at the nip is difficult experimentally due to high printing speed. In this paper, rheological behavior and splitting point of the ink at the nip is studied using package software Ployflow and Flow 3D based on Navier-Stokes equation. Polydimethylsiloxane (PDMS) ink and IGT printability tester were used for an model ink and experiment to compare with that of simulation data, respectively. As a result, higher viscosity at state flow and pressure increased ink transfer due to higher possibility of presence of cavitation at the nip and increase in covering area ratio. These results have shown good agreements with experimental data compared by measuring density of print through.