• 한국건축시공학회지
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• 제8권3호
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• pp.111-117
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• 2008

This study provides the setting time prediction method of super retarding concrete incorporating mineral admixtures at the same time including fly ash(FA), blast furnace slag(BS) based on maturity method. The setting time was retarded, as super retarding agent contents increase and curing temperature decreases. In addition, apparent activation energy by Arrhenius function was ranged from $24{\sim}35KJ/mol$ with slightly difference along with mixture proportion. This value is smaller than existing value $30{\sim}50KJ/mol$. It is Indicated that equivalent age using setting time can be a proper method to predict setting time and it also exhibited comparable relativity between prediction value and measurement value. Therefore, this study provided setting time prediction value with super retarding agent contents and mineral admixture combination. Setting time prediction equation provided herein is possibly valid for estimating precise setting time of the super retarding concrete at the job site.

• Computers and Concrete
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• 제32권2호
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• pp.185-206
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• 2023

This article aimed to explore the optimization of mineral admixtures and retarding admixture for high-performance concrete. In essence, fresh concrete can be regarded as a mixture in which both coarse and fine aggregates are suspended in a cement-based matrix paste. Based on this view, the test procedure was divided into three progressive stages of binder paste, mortar, and concrete to explore their rheological behavior and mechanical properties respectively. At each stage, there were four experimental control factors, and each factor had three levels. In order to reduce the workload of the experiment, the Taguchi method with an L9(3⁴) orthogonal array and four controllable three-level factors was adopted. The test results show that the use of the Taguchi method effectively optimized the composition of high-performance concrete. The slump of the prepared concrete was above 18 cm, and the slump flow was above 50 cm, indicating that it had good workability. On the other hand, the 28-day compressive strength of the hardened concretes was between 31.3-59.8 MPa. Furthermore, the analysis of variance (ANOVA) results showed that the most significant factor affecting the initial setting time of the fresh concretes was the retarder dosage, and its contribution percentage was 62.66%. On the other hand, the ANOVA results show that the most significant factor affecting the 28-day compressive strength of the hardened concretes was the water to binder ratio, and its contribution percentage was 79.05%.

• 한국건축시공학회지
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• 제8권5호
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• pp.119-125
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• 2008

In this paper, the estimation of super retarding concrete incorporating mineral admixtures at the same time including fly ash(FA), blast furnace slag(BS) are studied based on maturity method. The setting time was retarded, as super retarding agent contents increase and curing temperature decreases. In addition, apparent activation energy by Arrhenius function was ranged from $24\sim35$ KJ/mol with slightly difference along with mixture proportion. This value is smaller than existing value $30\sim50$ KJ/mol. Based on strength development estimation. it exhibited comparable relativity between prediction value and measurement value. Therefore, this study provided effective strength development prediction value with super retarding agent contents and mineral admixture combination. Strength development prediction equation provided herein is possibly valid for estimating accurate strength development of the super retarding concrete at the job site.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 봄 학술발표회논문집(II)
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• pp.747-750
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• 1998

The application of spent liquor(BSL) obtained from alkaline sulfite-anthraquinone cooking of pine bark to cement mortar significantly improved the water-reducing ability and decreased the rate of cement hardening. However, the compressive and flexural strength of BSL addition to cement mortar were lower than that of PLAIN. The application of 0.2% antifoamer to BSL slightly decreased water-reducing ability, but remarkably improved the compressive and flexural strength of cement mortar. On the other hand, BSL decreased the rate of hardening of cement, which exhibited the protperties of the lignosulfonated based retarding water-reducing type. but the setting time of cement could be controlled by addition of Na2CO3 could be used to convert BSL to normal or accelerating concrete admixtures.

• 한국안전학회지
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• 제30권3호
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• pp.59-66
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• 2015

본 연구는 슬럼프 감소, 연행 공기 부족, 건조수축 균열, 강도감소 등 굳지 않은 콘크리트와 굳은 콘크리트의 성질에 대한 타설시 고온의 악영향에 대한 원인분석을 실시하고 이를 경감시키기 위한 감수제, 공기연행제, 지연제 등의 화학적 혼화제와 플라이 애쉬, 고로 슬래그 등의 무기질 혼화재의 다양한 적용이 검토되었다. 즉, 서중 콘크리트의 품질향상을 위한 다양한 콘크리트 배합이 설계되고 각 배합에서의 굳지 않은 콘크리트 및 굳은 콘크리트 에 대한 영향이 분석되고 몇 가지의 최적 배합이 도출되었다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2004년도 학술대회지
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• pp.7-10
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• 2004

This paper investigated the possibility of quality restoration of deteriorated concrete caused by long distance delivery using chemical admixtures such as superplasticizer. AE agent and retarding agent. According to test results, long distance delivery lead to reducing fluidity and air content markedly, while setting time accelerated. Quality restoration agent(QRA) was made by combining super- plasticizer. AE agent and retarding agent with the proportion of 1:0.0025:0.1. It was confirmed that deteriorated concrete achieved quality restoration with the level of target slump, air content and setting time without strength loss when using QRA with proper amount.

• 콘크리트학회논문집
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• 제11권4호
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• pp.95-105
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• 1999

When superplasticizer is added to manufacture flowing concrete, the base concrete usually needs the adjustment to assure the sufficient fines contained to obtain flowable consistency without excessive bleeding or segregation. However, this may not only increase the cost, but also cause inconvenience in producing the base concrete. In this paper, the experiments are performed on normal base concrete to achieve a segregation-reducing flowing concrete by adding superplasticizer mixed with viscosity agents and AE admixtures. Three kinds of superplasticizer and two kinds of viscosity agent are selected. According to the results, with regard to the performance and cost of the admixtures, melamine type superplasticizer combined with the PEO viscosity agent and AE admixtures at the ratio 1:0.28:0.001 can acquire good quality and reduce the cost in producing the flowing concrete. With proper addition of combined superplasticizer, even though water to cement ratios of the base concrete are different, the segregation-reducing flowing concrete could be also achieved without reproportioning of the base concrete. However, it would be more desirable if the superplasticizer could be adjusted, before it is put into the practical use in order not to cause some other problems, such as rapid rate of slump loss and retarding of setting time.

• 한국구조물진단유지관리공학회 논문집
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• 제26권4호
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• pp.48-56
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• 2022

시멘트계 재료의 응결시간 제어는 초기 콘크리트 성능 확보를 위한 중요한 평가 요소 중 하나이다. 최근 평균 기온 상승으로 특정 수화물 생성 억제 및 응결시간 제어를 위한 지연제의 사용이 권장되고 있다. 비카트 침 등 관입저항 측정 시험법의 한계를 극복하기 위해 응결시점 평가를 위한 다양한 비파괴 평가 기법이 제안되고 있지만, 지연제 사용에 따른 비파괴 평가법 사용 가능성 확보를 위해서는 여전히 실험적 연구 수행이 요구되고 있다. 본 연구에서는 타타르산 지연제를 사용하여 시멘트 페이스트의 응결 지연을 유도하고, 비카트 침 시험과 함께 전기비저항과 초음파 속도 모니터링을 수행하였다. 두 비파괴 측정 결과의 상승시점 결정을 통해 시멘트 페이스트의 응결시점을 평가하고, 비카트 침 측정을 통한 초결 및 종결 시점과의 분석으로 지연제 사용에 따른 응결 지연 현상 평가 가능성을 확인하였다. 또한 전기비저항 상승시점에 대한 X선 회절 분석을 통해 타타르산 지연제 사용에 따른 수화반응 변화를 측정하고 전기비저항 측정의 응결 지연 평가에 영향을 주는 주요 수화물을 확인하였다.

• 한국세라믹학회지
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• 제31권10호
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• pp.1107-1114
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• 1994

Although various theories have been presented on the mechanism of setting retardation of plaster in addition to organic admixtures. The purpose of this paper is that Hydration studies of plaster of paris in the presence of carboxylic acids under alkalinity are examined in the coordination chemistry. Setting of plaster of paris is retarded by the addition of carboxylic acids except oxalic acid. And setting of plaster of paris contained 5 wt% of Ca(OH)2 is also retarded by the addition of above-mentioned carboxylic acids. The degree of retarding effect under alkalinity is found to be a function of the number of the functional group and the length of carbon chain of carboxyl acids. These reasons are attributed to the soluble complex formation, that is calcium complex formation between calcium ion and carboxylic acids. The author's proposal was confirmed by the results of electrical conductivity measurement. The formation of calcium complex was surpported by IR spectra.

• 한국건설순환자원학회논문집
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• 제8권3호
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• pp.365-371
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• 2020

본 연구에서는 열매를 수확한 후 폐기되는 손바닥 선인장 줄기를 재활용하기 위하여 선인장 줄기 분말을 시멘트계 재료의 혼화제로 적용하고자 하였다. 이를 위해 선인장 줄기 분말을 혼입한 모르타르의 굳지 않은 특성과 강도에 대한 연구를 수행하였다. 또한 그 결과를 기존의 당류계 혼화제인 지연제 설탕과 증점제 메틸셀룰로오스를 혼입한 모르타르의 특성과 비교하였다. 연구 결과, 선인장 줄기 분말은 지연제로서 효과를 뚜렷하게 보여주지 못하였다. 반면, 선인장 줄기 분말 혼입율이 증가할수록 플로 및 공기량이 메틸셀룰로오스를 혼입한 모르타르와 유사한 경향을 나타내어 증점제로서 활용 가능성을 확인하였다. 또한 선인장 줄기 분말의 혼입율이 0.3% 이내일 때에는 모르타르의 강도가 증가하는 것으로 나타났다.