• Title/Summary/Keyword: response-surface

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Empirical relationship between band gap and synthesis parameters of chemical vapor deposition-synthesized multiwalled carbon nanotubes

  • Obasogie, Oyema E.;Abdulkareem, Ambali S.;Mohammed, Is'haq A.;Bankole, Mercy T.;Tijani, Jimoh. O.;Abubakre, Oladiran K.
    • Carbon letters
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    • v.28
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    • pp.72-80
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    • 2018
  • In this study, an empirical relationship between the energy band gap of multi-walled carbon nanotubes (MWCNTs) and synthesis parameters in a chemical vapor deposition (CVD) reactor using factorial design of experiment was established. A bimetallic (Fe-Ni) catalyst supported on $CaCO_3$ was synthesized via wet impregnation technique and used for MWCNT growth. The effects of synthesis parameters such as temperature, time, acetylene flow rate, and argon carrier gas flow rate on the MWCNTs energy gap, yield, and aspect ratio were investigated. The as-prepared supported bimetallic catalyst and the MWCNTs were characterized for their morphologies, microstructures, elemental composition, thermal profiles and surface areas by high-resolution scanning electron microscope, high resolution transmission electron microscope, energy dispersive X-ray spectroscopy, thermal gravimetry analysis and Brunauer-Emmett-Teller. A regression model was developed to establish the relationship between band gap energy, MWCNTs yield and aspect ratio. The results revealed that the optimum conditions to obtain high yield and quality MWCNTs of 159.9% were: temperature ($700^{\circ}C$), time (55 min), argon flow rate ($230.37mL\;min^{-1}$) and acetylene flow rate ($150mL\;min^{-1}$) respectively. The developed regression models demonstrated that the estimated values for the three response variables; energy gap, yield and aspect ratio, were 0.246 eV, 557.64 and 0.82. The regression models showed that the energy band gap, yield, and aspect ratio of the MWCNTs were largely influenced by the synthesis parameters and can be controlled in a CVD reactor.

Geographic Variation in Survival Rate and Height Growth of Pinus densiflora S. et Z. in Korea

  • Kim, In-Sik;Ryu, Keun-Ok;Song, Jeong-Ho;Kim, Tae-Su
    • Journal of Korean Society of Forest Science
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    • v.94 no.2 s.159
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    • pp.73-81
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    • 2005
  • This study was conducted to examine the geographic variation among provenances of Pinus densiflora in survival rate and height growth at four test plantations (Jungsun, Chungju, Naju, and Jeju). The plantations were parts of the eleven provenance trials of Pinus densiflora established by Korea Forest Research Institute in 1996. The survival rate and height growth were significantly different among test plantations at $p{\leq}0.01$. Latitude and longitude of test plantation were negatively correlated with survival rate and height growth. On the other hand, annual mean temperature, mean temperature (Nov.~Feb.), extremely low temperature (Dec.~Feb.), and annual mean growing days of test plantation were positively correlated with these two. The relationships between growth variables and geographic variables were analysed with canonical correlation analysis. A considerable amount of variation in survival rate and height growth was explained by latitude, annual mean growing days, extremely low temperature (Dec.~Feb.) and extremely high temperature (Nov.~Feb.) of provenances. It is estimated that up to 47.1% and 67.4% of the genetic variability in survival rate and height growth was attributable to the environmental variability of the provenances, respectively. The response surface curve of survival rate and height growth was plotted against latitude and longitude to examine growth performance of provenances for each test site. Generally, the local provenances showed better survival rate and height growth.

Multiple Targets Detection by using CLEAN Algorithm in Matched Field Processing (정합장처리에서 CLEAN알고리즘을 이용한 다중 표적 탐지)

  • Lim Tae-Gyun;Lee Sang-Hak;Cha Young-Wook
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.10 no.9
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    • pp.1545-1550
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    • 2006
  • In this paper, we propose a method for applying the CLEAN algorithm to an minimum variance distortionless response(MVDR) to estimate the location of multiple targets distributed in the ocean. The CLEAN algorithm is easy to implement in a linear processor, yet not in a nonlinear processor. In the proposed method, the CSDM of a Dirty map is separated into the CSDM of a Clean beam and the CSDM of the Residual, then an individual ambiguity surface(AMS) is generated. As such, the CLEAN algorithm can be applied to an MVDR, a nonlinear processor. To solve the ill-conditioned problem related to the matrix inversiion by an MVDR when using the CLEAN algorithm, Singular value decomposition(SVD) is carried out, then the reciprocal of small eigenvalues is replaced with zero. Experimental results show that the proposed method improves the performance of an MVDR.

A Study on the Mix Design for the Pozzolanic Cement Treated with High Strength Soilcrete by Using the Statistical Design of Experimental Method (통계적 실험계획법을 이용한 포졸란시멘트계 고강도 고화토의 배합설계에 관한 연구)

  • 천병식;김진춘
    • Journal of the Korean Geotechnical Society
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    • v.16 no.1
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    • pp.227-234
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    • 2000
  • Soilcrete has been a traditional material for pavement and soft ground improvement techniques. However, since the durability is not excellent and the quality is not consistent, it has not been used for various purposes up to date. However, with the increase of naturally oriented needs for light traffic roads such as pedestrian roads of garden, golf courses and sidewalks, the cases of the high strength soilcrete paving have been increased lately. This study aims at making a reference table of mix design in accordance with the required design specifications fur the high strength soilcrete admixtured with the pozzolanic cement by using a statistical experimental method. The treated soil is the clay which is widely found in Korea. As the results of this study, we could derive an effective reference mix design table for the clay treated with the pozzolanic cement stabilizer in accordance with the compressive strength of $50~150kg/cm^2$ soilcrete.

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Production of Levulinic Acid from Chitosan by Acidic-Hydrothermal Reaction (산성 수열반응을 통한 키토산으로부터 레불린산의 생산)

  • Jeong, Gwi-Taek
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.355-359
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    • 2014
  • Recently, many chemicals produced from renewable resources such as lignocellulosics, micro-algae and marine macro-algae, were introduced to chemical industry. Chitin/chitosan is secondly abundant feedstock on Earth. It is easily obtained from crusraceans' shells such as crab, shrimp and insects. In this work, we performed the acidic-hydrothermal hydrolysis to produce levulinic acid from chitosan using statistical approach. By design of response surface methodology, the effect of reaction temperature, catalyst amount, and reaction time and their reciprocal interactions were investigated. As a result, higher reaction temperature and catalyst amount increased the higher concentration of levulinic acid. However, reaction time did not caused large increase of levulinic acid after some reaction period. Levulinic acid of 2.7 g/L produced from chitosan in the optimized condition of reaction temperature of $175^{\circ}C$, sulfuric acid of 2.4% and reaction time of 40.7 min.

Shape Optimum Design of Ship's Bellows Using Statistical Method (통계적 방법을 이용한 선박용 벨로우즈의 형상 최적 설계)

  • Kim, Hyun-Su;Kim, Hyo-Gyeum;Lee, Jae-Sub;Kim, Hyoung-Jun
    • Journal of Ocean Engineering and Technology
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    • v.21 no.5
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    • pp.55-60
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    • 2007
  • Bellows are mechanical components which prevent the damage of system by absorption of the vibration and the displacement of axle and radial direction. Thermal piping system is expanded by the fluid of the high temperature from the heat engine inside. At this time, bellows prevent the damage of the piping due to the thermal expansion. Recently, design of bellows is required to fit some other operational environments which are not suggested in the E.J.M.A code book. And it is difficult to produce and to maintain bellows of high temperature and high pressure bemuse of its complicated shape and this causes the manufacturing cost to rise. The objective of this study is to determine optimum shape of bellows which can endure in the high temperature and high pressure. The maximum stress has an effect on the fatigue life of bellows, therefore it needs to be minimized. This study attempts to find a shape which minimizes the stress occurring in the bellows by the design of experiment. The model used in this study is not presented in the E.J.M.A code book, therefore, from the result of design of experiment we find the factors which give effects on the characteristic value and we presents the recession model using the RSM, which can predict the characteristic values depending on the change of factor values.

Illumination estimation based on valid pixel selection from CCD camera response (CCD카메라 응답으로부터 유효 화소 선택에 기반한 광원 추정)

  • 권오설;조양호;김윤태;송근호;하영호
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.41 no.5
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    • pp.251-258
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    • 2004
  • This paper proposes a method for estimating the illuminant chromaticity using the distributions of the camera responses obtained by a CCD camera in a real-world scene. Illuminant estimation using a highlight method is based on the geometric relation between a body and its surface reflection. In general, the pixels in a highlight region are affected by an illuminant geometric difference, camera quantization errors, and the non-uniformity of the CCD sensor. As such, this leads to inaccurate results if an illuminant is estimated using the pixels of a CCD camera without any preprocessing. Accordingly, to solve this problem the proposed method analyzes the distribution of the CCD camera responses and selects pixels using the Mahalanobis distance in highlight regions. The use of the Mahalanobis distance based on the camera responses enables the adaptive selection of valid pixels among the pixels distributed in the highlight regions. Lines are then determined based on the selected pixels with r-g chromaticity coordinates using a principal component analysis(PCA). Thereafter, the illuminant chromaticity is estimated based on the intersection points of the lines. Experimental results using the proposed method demonstrated a reduced estimation error compared with the conventional method.

Three-dimensional optimization and sensitivity analysis of dental implant thread parameters using finite element analysis

  • Geramizadeh, Maryam;Katoozian, Hamidreza;Amid, Reza;Kadkhodazadeh, Mahdi
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.44 no.2
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    • pp.59-65
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    • 2018
  • Objectives: This study aimed to optimize the thread depth and pitch of a recently designed dental implant to provide uniform stress distribution by means of a response surface optimization method available in finite element (FE) software. The sensitivity of simulation to different mechanical parameters was also evaluated. Materials and Methods: A three-dimensional model of a tapered dental implant with micro-threads in the upper area and V-shaped threads in the rest of the body was modeled and analyzed using finite element analysis (FEA). An axial load of 100 N was applied to the top of the implants. The model was optimized for thread depth and pitch to determine the optimal stress distribution. In this analysis, micro-threads had 0.25 to 0.3 mm depth and 0.27 to 0.33 mm pitch, and V-shaped threads had 0.405 to 0.495 mm depth and 0.66 to 0.8 mm pitch. Results: The optimized depth and pitch were 0.307 and 0.286 mm for micro-threads and 0.405 and 0.808 mm for V-shaped threads, respectively. In this design, the most effective parameters on stress distribution were the depth and pitch of the micro-threads based on sensitivity analysis results. Conclusion: Based on the results of this study, the optimal implant design has micro-threads with 0.307 and 0.286 mm depth and pitch, respectively, in the upper area and V-shaped threads with 0.405 and 0.808 mm depth and pitch in the rest of the body. These results indicate that micro-thread parameters have a greater effect on stress and strain values.

Drug loaded biodegradable membranes for guided tissue regeneration (약물함유 생체분해성 차폐막의 유도조직재생에 관한 연구)

  • Kim, Dong-Kyun;Lee, Seung-Jin;Chung, Chong-Pyoung
    • Journal of Periodontal and Implant Science
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    • v.25 no.2
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    • pp.192-209
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    • 1995
  • The purpose of this study was to evaluate drug-loaded biodegradable membranes for guided tissue regeneration(GTR). The membranes were made by coating mesh of polyglycolic acid(PGA) with polylactic acid(PLA) containing 10% flurbiprofen or tetracycline. The thickness of membrane was $150{\pm}30{\mu}m$, and the pore size of surface was about $8{\mu}m$ in diameter. The release of drugs from the membrane was measured in vitro. Cytotoxity test for the membrane was performed by gingival fibroblast cell culture, and the tissue response was observed after implant of membrane into the dorsal skin of the rat for 8 wks. Ability to guided tissue regeneration of membranes were tested by measuring new bone in the calvarial defects(5mm in diameter) of the rat for 5 weeks. The amount of flurbiprofen and tetracycline released from membrane were about 30-60% during 7 days. Minimal cytotoxity was observed in the membrane except 20% drug containing membrane. In histologic finding of rat dorsal skin, many inflammatory cells were observed around e-PTFE, polyglactin 910 and PLAPGA membrane after 1 or 2 weeks. PLA-PGA membrane was perforated by connective tissue after 4 or 6 weeks, and divided as a segment at 8 weeks. In bone regeneration guiding potential test, tetracycline loaded membrane was most effective (p

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MARGINAL TISSUE RESPONSE TO DIFFERENT IMPLANT NECK DESIGN

  • Bae, Hanna-Eun-Kyong;Chung, Moon-Kyu;Cha, In-Ho;Han, Dong-Hoo
    • The Journal of Korean Academy of Prosthodontics
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    • v.46 no.6
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    • pp.602-609
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    • 2008
  • STATEMENT OF PROBLEM: Loss of the marginal bone to the first thread have been accepted but continuous effort have been made to reduce this bone loss by varying implant design and surface texture. PURPOSE: This animal study has examined the histomorphometric variations between implants with micro-thread, micro-grooved and turned surfaced neck designs. MATERIAL AND METHODS: Four mongrel dogs have been used the premolars removed and left to heal for three months. One of each implant systems with turned neck, micro-thread and micro-grooved were placed according to the manufacturers’protocol and left submerged for 8 and 12 weeks. These were then harvested for histological examination. RESULTS: The histologically all samples were successfully ossointegrated and active bone remodelling adjacent to implants. With the micro-grooved implants 0.40 mm and 0.26 mm of the marginal bone level changes were observed at 8 and 12 weeks respectively. The micro-threaded implants had changes of 0.79 mm and 0.56 mm at 8 and 12 weeks respectably. The turned neck designed implants had marginal bone level changes of 1.61 mm and 1.63 mm in 8 and 12 weeks specimens. A complex soft tissue arrangement could be observed against micro-threaded and micro-grooved implant surfaces. CONCLUSION: Within the limitations of this study, it could be concluded that implants with micro-grooved had the least and the turned neck designed implants had the most changes in the marginal bone level. The textured implant surfaces affect soft tissue responses.