• Title/Summary/Keyword: resin acid

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SHEAR BOND STRENGTH OF RESIN ADHESIVE CEMENT TO ENAMEL AND Ni-Cr-Be ALLOY (접착성 레진 시멘트 와 법랑질 및 닉켈-크롬 합금 간의 전단결합강도)

  • Lee, Sun-Hyung;Yang, Jae-Ho;Chung, Hun-Young;Jang, Il-Seong
    • The Journal of Korean Academy of Prosthodontics
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    • v.35 no.2
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    • pp.365-372
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    • 1997
  • This study was executed to measure the shear bond strength of Panavia EX and Panavia 21 when the Ni-Cr-Be alloy castings were cemented to the enamel surfaces with these cements. The cast metal plates of Ni-Cr-Be alloy were sandblasted and cemented to acid etched enamel surface with Panavia EX or Panavia 21. Their shear bond strength were measured with Instron Universal Testing machine. Within the limits of this study, following conclusions were withdrawn. 1. The mean shear bond strength were 26.85.7MPa, in Panavia EX and 28.35.2MPa, in Panavia 21. 2. t-Test revealed no statistical significance between two groups(.05 level) 3. Macroscopically, bond failures were revealed compound fracture at metal and enamel interfaces, in cases of both cements, as the cement attached partly on both metal and enamel surface.

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Characterization of the PAC Modified Cationic Rosin Size and its Sizing Effect

  • Yan, Yong-Xiang;Chandranupap, Fu-Shan;Wang, Gao-Sheng
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.387-390
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    • 2006
  • Cationic rosin sizes are prepared by premixing extremely pure ployaluminum chloride (PAC) and dispersed rosin size (DRS). It turned out that zeta potential and particle size of the sizing agents took a big change by Plus90 analyzer's and FTIR analyzer's analysis. It turned out that -C=O and -COOH of the DRS have both chemical reaction with PAC to form the muti-hydroxyl aluminum rosin acid and that the cationic rosin sizes modified by PAC has dissymmetric and symmetric flexible vibration two absorbing peaks of the groups (its absorbing peaks $at1596cm^{-1}\;and\;1425cm^{-1}$). By DRS reacting with PAC, zeta potential of the resin size varied from negative to cationic. $Al_{2}O_{3}/rosin=1:0.3$, zeta potential of premixed admixture is tiptop28.8mv, When joined continuously PAC, zeta potential of cationic rosin sizes descend on the contrary.

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Effect of Nozzle Orifice Shape and Nozzle Length-to-Diameter Ratio on Internal and External Flow Characteristics of Diesel and Biodiesel Fuel (노즐 오리피스 형상 및 형상비가 디젤과 바이오디젤 연료의 노즐 내부 및 외부 유동특성에 미치는 영향)

  • Park, Su-Han;Suh, Hyun-Kyu;Lee, Chang-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.3 s.258
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    • pp.264-272
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    • 2007
  • The aim of this study is to investigate the effects of nozzle orifice shapes and the nozzle length-to-diameter ratio(L/D) on the nozzle cavitation formation inside the orifice and the external flow pattern. The nozzle used in this work was tested the taper orifice nozzle and the rectangular orifice nozzle which was made from the transparent acrylic acid resin. For studying the effect of the nozzle L/D ratio, it was used to three L/D ratios of 3.33, 10, and 20. The cavitation flow of nozzle was visualized by using the ICCD camera and optical system. This work revealed that the flow rate and discharge coefficient($C_d$) of the taper orifice nozzle was larger than those of the rectangular orifice nozzle at the same injection pressure. The cavitation flow was observed in the nozzle orifice at the low injection pressure and the breakup of liquid jet was promoted as the L/D ratio is decreased. The cavitation of biodiesel fuel was formed at the lower injection pressure than that of diesel fuel because of higher viscosity and density.

Development of Multi-functional Mulch Papers and Evaluation of Their Performance(Part 3) -Defoaming Treatment during Trial Production of Mulch Papers and Their Influence on Wet End System- (다기능성 멀칭지의 개발 및 적용성 평가(제3보) -시제품 생상시 공정 백수의 거품제거 처리 및 그 영향에 관하여-)

  • 이학래;이진희
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.3
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    • pp.25-31
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    • 2000
  • It is required to use substantial amount of wet strength resin for producing multi-functional mulch papers since these paper products shold maintain its strength properties when they exposed to outdoor weather for several months. While producing mulch papers it is usual to observe significant amount of foam at white water silo. Thus it is imperative to use defoaming or antifoaming agents. In this study diverse defoaming and antifoaming agents have been tested for their effective-ness in eliminating foams that produced. It was shown that combined use of a silicone type defoamer and a fatty acid type anti-foaming agent was msot effective in eliminating foams. These chemicals were used in trial production of mulch papers and their influence on paper-making wet end system was examined including one pass retention cationic demand con-ductivity pH etc. It was found that the defoaming agents were very effective for removing foams in trial production. Tensile strengths of the mulch papers produced were significantly greater than commericial mulch papers produced in Japan.

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A Study on the Film Performance by Physical Properties of Gelatin(Glue) in Dancheong (젤라틴(아교)의 물성에 따른 단청 도막의 성능비교 연구)

  • Park, Ji Hye;Jeong, Seon Hye;Kim, Ik Joo;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.29 no.1
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    • pp.25-33
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    • 2013
  • This study aims to investigate the film performance by physical properties of glue and gelatin in traditional paint(Dancheong). To do this, homemade, commercial glue and gelatin was selected and evaluated water reaction and weatherproof. The result, the highest gel strength, gelatin was better than acrylic acid ester resin, when compared with hygroscopic property and adhesive property. And that was better than in any others, when compared with water-proofing.

Characterization of Plasma Proteins from Bloods of Slaughtered Cow and Pig and Utilization of the Proteins as Adhesives (도축혈액 혈장 단백질의 특성 및 접착제로의 응용)

  • Park, Eun-Hee;Lee, Hwa-Hyoung;Song, Kyung-Bin
    • Applied Biological Chemistry
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    • v.39 no.2
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    • pp.123-126
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    • 1996
  • Simple and rapid method of purification of plasma proteins from bloods of slaughtered animals was developed and the proteins were applied to plywood products as a blood 히ue to utilize waste materials. Plasma protein was obtained by adding 2% trichloroacetic acid (TCA) or 0.6 N HCI as optimal concentration to the supernatant, after centrifugation of bloods. Molecular properties of beef and pig plasma proteins were examined on SDS-PAGE. Application of blood glue to plywood was quite satisfactory compared to the synthetic amino resin by tensile-shear test for the strength of adhesive bonding.

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Studies on the Identification of the Anthocyanins in Plum (자두 Anthocyanin의 구조확인(構造確認)에 관(關)한 연구(硏究))

  • Ahn, Seung-Yo
    • Applied Biological Chemistry
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    • v.16 no.2
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    • pp.53-59
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    • 1973
  • The anthocyanins in Santa rosa plum (widely growing var. in Korea) were extracted with 0.5% methanolic HCl and purified with Amberlite IRC-50 cation exchange resin. The individual pigments were separated by paper chromatography. The two pigments were identified as cyanidin-3-monoglucoside and cyanidin-3-xyloglucoside based on the following evidence: Rf values in various solvents, partical acid hydrolysis, stepwise hydrolysis, sugar moiety, alkaline degradation, and absorption spectra in the visible region. Cyanicin-3-monoglucoside was the abundant pigment of the plum.

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In Situ Detection of the Onset of Phase Separation and Gelation in Epoxy/Anhydride/Thermoplastic Blends

  • Choe, Young-Son;Kim, Min-Young;Kim, Won-Ho
    • Macromolecular Research
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    • v.11 no.4
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    • pp.267-272
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    • 2003
  • The isothermal cure reactions of blends of epoxy (DGEBA, diglycidyl ether of bisphenol A)/anhydride resin with polyamide copolymer (poly(dimmer acid-co-alkyl polyamine)) or PEI were studied using differential scanning calorimetry (DSC). Rheological measurements have been made to investigate the viscosity and mechanical relaxation behavior of the blends. The reaction rate and the final cure conversion were decreased with increasing the amount of thermoplastics in the blends. Lower values of final cure conversions in the epoxy/thermoplastic blends indicate that thermoplastics hinder the cure reaction between the epoxy and the curing agent. Complete miscibility was observed in the uncured blends of epoxy/thermoplastics up to $120^{\circ}C$ but phase separations occurred in the early stages of the curing process at higher temperatures than $120^{\circ}C$. According to the rheological measurement results, a rise of G' and G" at the onset of phase separation is seen. A rise of G' and G" is not observed for neat epoxy system since no phase separation is seen during cure reaction. At the onset of phase separation the rheological behavior was influenced by the amount of thermoplastics in the epoxy/thermoplastic blends, and the onset of phase separation can be detected by rheological measurements.

Interfacial Adhesion of Silk/PLA Biocomposites by Plasma Surface Treatment (플라즈마 표면처리에 의한 Silk/PLA 바이오복합재료의 계면접착)

  • Chu, Bo Young;Kwon, Mi Yeon;Lee, Seung Goo;Cho, Donghwan;Park, Won Ho;Han, Seong Ok
    • Journal of Adhesion and Interface
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    • v.5 no.4
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    • pp.9-16
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    • 2004
  • Silk fibers were subjected to argon and ethylene plasma treatments in order to improve the interfacial adhesion with polylactic acid (PLA). After the plasma surface treatment, the surface morphology and surface adhesion of silk fibers to the PLA resin were largely changed. Various plasma treatment conditions were used in this work: 10, 25, 50, 100 and 150 W of electric power, 1, 3, 5, 7 and 10 minutes of treatment time, and 10 and 50 sccm of a gas flow rate. The interfacial shear strength of plasma-treated Silk/PLA biocomposites was measured by a single fiber micro-droplet debonding test method. The result provided an optimal plasma treatment condition to obtain the improved interfacial adhesion in the Silk/PLA biocomposites.

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Powder Synthesis and Sintering Behavior of Hydroxyapatite by Citrate Method (Citrate법을 이용한 수산화아파타이트 분말합성 및 소결특성)

  • 임병일;최세영;정형진;정형진;오영제
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.1003-1011
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    • 1996
  • Hydroxyapatite powder was synthesized by a citrate method, . Char-like precursor composed of Ca8(HPO4)2(PO4)4.5H2O (OCP) and CaCo3 was found via viscous resin-like intermediate by heating the mixed aqueous solution of Ca(NO3)2.4H2O(NH4)2HPO4 and citric acid. Resulted powder was transformed into hydroxyapatite phase by firing over 120$0^{\circ}C$-135$0^{\circ}C$ for 4 hr using the powder calcined at 90$0^{\circ}C$ for 10 hr composed of mostly single hydroxyapatite phase. The sintered densities increased with firing temperature up to 130$0^{\circ}C$ but the highest relative density was about 94% of theoritical value. indicating the presence of closed pores. The maximum 96 MPa of flexural strength was obtained at 120$0^{\circ}C$ firing but the flexural strength showed lower values over the above sintering condition. Vitro test was performed by immersing of two jointed specimens in SBF for seven days and adhesion was observed between two specimens.

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