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Reduction of Leakage Current and Enhancement of Dielectric Properties of Rutile-TiO2 Film Deposited by Plasma-Enhanced Atomic Lay er Deposition

  • Su Min Eun;Ji Hyeon Hwang;Byung Joon Choi
    • Korean Journal of Materials Research
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    • v.34 no.6
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    • pp.283-290
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    • 2024
  • The aggressive scaling of dynamic random-access memory capacitors has increased the need to maintain high capacitance despite the limited physical thickness of electrodes and dielectrics. This makes it essential to use high-k dielectric materials. TiO2 has a large dielectric constant, ranging from 30~75 in the anatase phase to 90~170 in rutile phase. However, it has significant leakage current due to low energy barriers for electron conduction, which is a critical drawback. Suppressing the leakage current while scaling to achieve an equivalent oxide thickness (EOT) below 0.5 nm is necessary to control the influence of interlayers on capacitor performance. For this, Pt and Ru, with their high work function, can be used instead of a conventional TiN substrate to increase the Schottky barrier height. Additionally, forming rutile-TiO2 on RuO2 with excellent lattice compatibility by epitaxial growth can minimize leakage current. Furthermore, plasma-enhanced atomic layer deposition (PEALD) can be used to deposit a uniform thin film with high density and low defects at low temperatures, to reduce the impact of interfacial reactions on electrical properties at high temperatures. In this study, TiO2 was deposited using PEALD, using substrates of Pt and Ru treated with rapid thermal annealing at 500 and 600 ℃, to compare structural, chemical, and electrical characteristics with reference to a TiN substrate. As a result, leakage current was suppressed to around 10-6 A/cm2 at 1 V, and an EOT at the 0.5 nm level was achieved.

Comparison of Solar Power Generation Forecasting Performance in Daejeon and Busan Based on Preprocessing Methods and Artificial Intelligence Techniques: Using Meteorological Observation and Forecast Data (전처리 방법과 인공지능 모델 차이에 따른 대전과 부산의 태양광 발전량 예측성능 비교: 기상관측자료와 예보자료를 이용하여)

  • Chae-Yeon Shim;Gyeong-Min Baek;Hyun-Su Park;Jong-Yeon Park
    • Atmosphere
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    • v.34 no.2
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    • pp.177-185
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    • 2024
  • As increasing global interest in renewable energy due to the ongoing climate crisis, there is a growing need for efficient technologies to manage such resources. This study focuses on the predictive skill of daily solar power generation using weather observation and forecast data. Meteorological data from the Korea Meteorological Administration and solar power generation data from the Korea Power Exchange were utilized for the period from January 2017 to May 2023, considering both inland (Daejeon) and coastal (Busan) regions. Temperature, wind speed, relative humidity, and precipitation were selected as relevant meteorological variables for solar power prediction. All data was preprocessed by removing their systematic components to use only their residuals and the residual of solar data were further processed with weighted adjustments for homoscedasticity. Four models, MLR (Multiple Linear Regression), RF (Random Forest), DNN (Deep Neural Network), and RNN (Recurrent Neural Network), were employed for solar power prediction and their performances were evaluated based on predicted values utilizing observed meteorological data (used as a reference), 1-day-ahead forecast data (referred to as fore1), and 2-day-ahead forecast data (fore2). DNN-based prediction model exhibits superior performance in both regions, with RNN performing the least effectively. However, MLR and RF demonstrate competitive performance comparable to DNN. The disparities in the performance of the four different models are less pronounced than anticipated, underscoring the pivotal role of fitting models using residuals. This emphasizes that the utilized preprocessing approach, specifically leveraging residuals, is poised to play a crucial role in the future of solar power generation forecasting.

Evaluation of Wear Performance of Corroded Materials in an 800℃ Molten Salt Environment (800℃ 용융염 환경에서 부식된 재료의 마모 성능 평가)

  • Yong Seok Choi;Kyeongryeol Park;Seongmin Kang;Unseong Kim;Kyungeun Jeong;Ji Ha Lee;Tae Woong Ha;Kyungjun Lee
    • Tribology and Lubricants
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    • v.40 no.3
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    • pp.97-102
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    • 2024
  • The next-generation Molten Salt Reactor is known for its high safety because it uses nuclear fuel dissolved in high-temperature molten salt, unlike traditional solid atomic fuel methods. However, the high-temperature molten salt causes severe corrosion in internal structural materials, threatening the reactor's safety. Therefore, it is crucial to investigate the high-temperature corrosion resistance and wear performance of materials used in reactors to ensure safety. In this study, the high-temperature corrosion resistances and wear performances of corrosion samples in a NaCl-MgCl2-KCl (20-40-40 [wt%]) molten salt are investigated to evaluate the applicability of economically viable stainless steels, 316SS and 304SS. Hastelloy C276 and a new alloy containing a small amount of Nb are used as reference samples for comparative analysis. The mass loss, mass loss rate per unit volume, and surface roughness of each sample are measured to understand the corrosion mechanisms. Scanning electron microscopy and energy-dispersive spectroscopy analyses are employed to analyze the corrosion mechanisms. Wear tests on the corroded samples are also conducted to assess the extent of corrosion. Based on the experimental results, we predict the lifespans of the materials and evaluate their suitability as candidate materials for molten salt reactors. The data obtained from the experiments provide a valuable database for structural materials that can enhance the stability of molten salt reactors and recommend high-temperature corrosion-resistant materials suitable for next-generation reactors.

State-of-the-Art in Cyber Situational Awareness: A Comprehensive Review and Analysis

  • Kookjin Kim;Jaepil Youn;Hansung Kim;Dongil Shin;Dongkyoo Shin
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.18 no.5
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    • pp.1273-1300
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    • 2024
  • In the complex virtual environment of cyberspace, comprised of digital and communication networks, ensuring the security of information is being recognized as an ongoing challenge. The importance of 'Cyber Situation Awareness (CSA)' is being emphasized in response to this. CSA is understood as a vital capability to identify, understand, and respond to various cyber threats and is positioned at the heart of cyber security strategies from a defensive perspective. Critical industries such as finance, healthcare, manufacturing, telecommunications, transportation, and energy can be subjected to not just economic and societal losses from cyber threats but, in severe cases, national losses. Consequently, the importance of CSA is being accentuated and research activities are being vigorously undertaken. A systematic five-step approach to CSA is introduced against this backdrop, and a deep analysis of recent research trends, techniques, challenges, and future directions since 2019 is provided. The approach encompasses current situation and identification awareness, the impact of attacks and vulnerability assessment, the evolution of situations and tracking of actor behaviors, root cause and forensic analysis, and future scenarios and threat predictions. Through this survey, readers will be deepened in their understanding of the fundamental importance and practical applications of CSA, and their insights into research and applications in this field will be enhanced. This survey is expected to serve as a useful guide and reference for researchers and experts particularly interested in CSA research and applications.

Implementation of Visible monkey into general-purpose Monte Carlo codes: MCNP, PHITS, and Geant4

  • Soo Min Lee;Chansoo Choi;Bangho Shin;Yumi Lee;Ji Won Choi;Bo-Wi Cheon;Chul Hee Min;Beom Sun Chung;Hyun Joon Choi ;Yeon Soo Yeom
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4019-4025
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    • 2023
  • Recently, a new monkey computational phantom, called Visible Monkey, was developed for non-ionizing radiation studies in animal research. In this study, we extended its applications to ionizing radiation studies by implementing the voxel model of the Visible Monkey into three general-purpose Monte Carlo (MC) codes: MCNP6, PHITS, and Geant4. The implementation work for MCNP and PHITS was conducted using the LATTICE, UNIVERSE, and FILL cards. The G4VNestedParameterisation class was used for Geant4. Then, organ dose coefficients (DCs) for idealized photon beams in the antero-posterior direction were calculated using the three codes and compared, showing excellent agreement (differences <3%). Additionally, organ DCs in other directions (postero-anterior, left-lateral, and right-lateral) were calculated and compared with those of the newborn and 1-year-old reference phantoms. Significant differences were observed (e.g., the stomach DC of the monkey was 5-fold greater than that of the 1-year-old phantom at 0.03 MeV) while the differences tended to decrease with increasing energy (mostly <20% at 10 MeV). The results of this study allows conducting MC simulations using the Visible Monkey to estimate organ-level doses, which should be valuable to support/improve monkey experiments involving ionizing radiation exposures.

Analysis of control rod driving mechanism nozzle rupture with loss of safety injection at the ATLAS experimental facility using MARS-KS and TRACE

  • Hyunjoon Jeong;Taewan Kim
    • Nuclear Engineering and Technology
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    • v.56 no.6
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    • pp.2002-2010
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    • 2024
  • Korea Atomic Energy Research Institute (KAERI) has operated an integral effect test facility, the Advanced Thermal-Hydraulic Test Loop for Accident Simulation (ATLAS), with reference to the APR1400 (Advanced Power Reactor 1400) for tests for transient and design basis accidents simulation. A test for a loss of coolant accident (LOCA) at the top of the reactor pressure vessel (RPV) had been conducted at ATLAS to address the impact of the loss of safety injections (LSI) and to evaluate accident management (AM) actions during the postulated accident. The experimental data has been utilized to validate system analysis codes within a framework of the domestic standard problem program organized by KAERI in collaboration with Korea Institute of Nuclear Safety. In this study, the test has been analyzed by using thermal-hydraulic system analysis codes, MARS-KS 1.5 and TRACE 5.0 Patch 6, and a comparative analysis with experimental and calculation results has been performed. The main objective of this study is the investigation of the thermal-hydraulic phenomena during a small break LOCA at the RPV upper head with the LSI as well as the predictability of the system analysis codes after the AM actions during the test. The results from both codes reveal that overall physical behaviors during the accident are predicted by the codes, appropriately, including the excursion of the peak cladding temperature because of the LSI. It is also confirmed that the core integrity is maintained with the proposed AM action. Considering the break location, a sensitivity analysis for the nodalization of the upper head has been conducted. The sensitivity analysis indicates that the nodalization gave a significant impact on the analysis result. The result emphasizes the importance of the nodalization which should be performed with a consideration of the physical phenomena occurs during the transient.

Coupled 3D thermal-hydraulic code development for performance assessment of spent nuclear fuel disposal system

  • Samuel Park;Nakkyu Chae;Pilhyeon Ju;Seungjin Seo;Richard I. Foster;Sungyeol Choi
    • Nuclear Engineering and Technology
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    • v.56 no.9
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    • pp.3950-3960
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    • 2024
  • As a solution to the problem of spent nuclear fuels (SNFs), the disposal of SNF has gained attention from nations using nuclear energy because of hazards posed to the ecosystem. Among many proposed solutions, the most promising method is to dispose of SNF in a deep geological repository (DGR) which utilizes the multi-barrier concept developed by Finland and Sweden. Here, a new fully-coupled Thermal-Hydraulic (TH) code HADES (High-level rAdionuclide Disposal Evaluation Simulator) is developed using the MOOSE framework. This new code suggests basic numerical tools, such as a non-linear solver and finite element discretization, to assess the safety performance of disposal systems. The new TH code considered various TH behavior using Richards' flow approach, assuming gas pressure is constant. The HADES showed promising results when it was compared to various TH codes validated from DECOVAELX-THMC projects. When the single-canister model was utilized to estimate the TH behavior of the Korean Reference disposal System, although it showed significant saturation reduction due to the evaporation of water, the temperature was maintained under the thermal criteria limit, which is 100 ℃. In addition, the new code estimated temperature and degree of saturation of the multi-canisters model, considering two or three canisters, it showed a slightly lower temperature, 5 ℃, than the single-canister model. From these results, the following are concluded: (1) the new TH code contribute to an additional integrity by estimating TH behavior of KRS; (2) however, due to limitations in single-canister simulation, it is recommended to use multi-canisters simulation to estimate TH behavior accurately. Therefore, this model is anticipated not only to help licensing applications and estimation of various multi-physics phenomena and multi-canister at the disposal site.

Real-time simulation and control of indoor air exchange volume based on Digital Twin Platform

  • Chia-Ying Lin;I-Chen Wu
    • International conference on construction engineering and project management
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    • 2024.07a
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    • pp.637-644
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    • 2024
  • Building Information Modeling (BIM) technology has been widely adopted in the construction industry. However, a challenge encountered in the operational phase is that building object data cannot be updated in real time. The concept of Digital Twin is to digitally simulate objects, environments, and processes in the real world, employing real-time monitoring, simulation, and prediction to achieve dynamic integration between the virtual and the real. This research considers an example related to indoor air quality for realizing the concept of Digital Twin and solving the problem that the digital twin platform cannot be updated in real time. In indoor air quality monitoring, the ventilation rate and the presence of occupants significantly affects carbon dioxide concentration. This study uses the indoor carbon dioxide concentration recommended by the Taiwan Environmental Protection Agency as a reference standard for air quality measurement, providing a solution to the aforementioned challenges. The research develops a digital twin platform using Unity, which seamlessly integrates BIM and IoT technology to realize and synchronize virtual and real environments. Deep learning techniques are applied to process camera images and real-time monitoring data from IoT sensors. The camera images are utilized to detect the entry and exit of individuals indoors, while monitoring data to understand environmental conditions. These data serve as a basis for calculating carbon dioxide concentration and determining the optimal indoor air exchange volume. This platform not only simulates the air quality of the environment but also aids space managers in decision-making to optimize indoor environments. It enables real-time monitoring and contributes to energy conservation.

Development Trend of Low Cost Space Launch Vehicle and Consideration of Next Generation Fuel (저비용 우주 발사체 개발 동향 및 이를 위한 차세대 연료에 대한 고찰)

  • Bae, Jinhyun;Koo, Jaye;Yoon, Youngbin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.45 no.10
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    • pp.855-862
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    • 2017
  • Due to the weight reduction and miniaturization of satellites, there is a growing interest in low-cost launch vehicles, which are cheaper to launch than larger launch vehicles. One of the most cost-effective ways to reduce the cost of launch vehicles is the reuse of vehicles. Most companies that are developing low cost launch vehicles are also adopting a vehicles reuse approach. Along with this reuse purpose, the demand for environmentally friendly space launch vehicles has increased, so the choice of fuel used for low cost launch vehicles has also become very important. Methane and hydrogen-enriched compressed natural gas (HCNG), which makes more energy-efficient by adding hydrogen to methane, are considered to be the most suitable when considering other factors such as energy density among the fuels that are eco-friendly and capable of reusing the launch vehicles. This study investigated the trends of low-cost launch vehicle and rocket fuel in the world as a reference for setting up domestic space development after the development of Korea Space Launch Vehicle-II.

A Study on Heat Dissipation Characteristics of PMMA Composite Films with Phase Change Material (상변화물질을 이용한 PMMA 복합필름의 방열 성능 향상에 관한 연구)

  • Kwon, Junhyuk;Yoon, Bumyong;Cho, Seung-hyun;Lee, Stephanie K.;Kim, Hyung-ick;Kim, Donghyun;Park, Kyungui;Suhr, Jonghwan
    • Composites Research
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    • v.30 no.5
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    • pp.288-296
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    • 2017
  • The focus of this study is to experimentally investigate the heat dissipation characteristics of poly (methyl methacrylate) (PMMA) composite films with phase change materials (PCM) to resolve heat build-up problems encountered in various electronic devices. In this study, two different types of phase change materials were used to fabricate the composite films by compression molding method and PCM paste sealing method then compared. It was observed in this study that the heat dissipation capability of PCM/PMMA composite films was remarkably enhanced by applying graphite sheet or graphene film into the composite due to their high thermal conductivity. These PCM/ PMMA composite films were attached on the hot spot inside smart phone and tested its surface temperature change according to time. The heat dissipation capability of PCM/PMMA composite film incorporated smart phone was increased 154% and hybrid PCM/PMMA composite film incorporated smart phone was increased 286% over the reference, respectively.