• Title/Summary/Keyword: reference energy

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Applications of ICP-MS to the Determination of Trace Np and Pu in Environmental Samples with Extraction Chromatography

  • Ji, Yanqin;Li, Jinying;Luo, Shanggeng
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.02a
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    • pp.182-190
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    • 2004
  • An unique extraction chromatographic column (TOA: Tri-n-octylamine on Teflon powder) with a two-stage sample loading was prepared to separate Np and Pu from the environmental matrix. Np and Pu were efficiently retained in 4 M $HNO_3$ medium on the column and easily eluted with 0.02 M oxalic acid in 0.16 M HNO$_3$at $95^{\circ}C$. The separated solutions were free from most of the matrix elements and were aspirated into the ICP-MS directly. The decontamination factor for 238U is more than 104. The instrumental detection limit for 237Np was 0.46 pg mL-l ($1.2{\times}10_{-5}$Bq mL-l), and for 239Pu was 0.48 pg mL-l ($1.1{\times}10_{-3}$ Bq mL-l). The feasibility for the determination of both elements was proved by analysing IAEA-135 reference samples, the measured values agreed with the recommended reference value.

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A Reference Container Concept for Spent Fuel Disposal : Structural safety for dimensioning of the reference container

  • Choi, Jong-Won;Kwon, Sang-Ki;Kang, Chul-Hyung;Kwon, Young-Joo
    • Journal of Radiation Protection and Research
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    • v.29 no.1
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    • pp.49-55
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    • 2004
  • This paper presents the mechanical and thermal stress analysis of a disposal canister to provide basic information for dimensioning the canister and configuration of the canister components. The structural stress analysis is carried out using a finite element analysis code, NISA, and focused on the structural strength of the canister against the expected external pressures due to the swelling of the bentonite buffer and the hydrostatic head, and the thermal load build up in the container.

Comparative studies of density functionals in modelling hydrogen bonding energetics of acrylamide dimers

  • Lin, Yi-De;Wang, Yi-Siang;Chao, Sheng D.
    • Coupled systems mechanics
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    • v.6 no.3
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    • pp.369-376
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    • 2017
  • Intermolecular interaction energies and conformer geometries of the hydrogen bonded acrylamide dimers have been studied by using the second-order Møller-Plesset (MP2) perturbation theory and the density functional theory (DFT) with 17 density functionals. Dunning's correlation consistent basis sets (up to aug-cc-pVTZ) have been used to study the basis set effects. The DFT calculated interaction energies are compared to the reference energy data calculated by the MP2 method and the coupled cluster method at the complete basis set (CCSD(T)/CBS) limit in order to determine the relative performance of the studied density functionals. Overall, dispersion-energy-corrected density functionals outperform uncorrected ones. The ${\omega}B97XD$ density functional is particularly effective in terms of both accuracy and computational cost in estimating the reference energy values using small basis sets and is highly recommended for similar calculations for larger systems.

Fuel Management Study on DUPIC Core

  • Park, Hangbok;Bo W. Rhee;Park, Hyunsoo
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.10a
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    • pp.41-47
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    • 1995
  • A parametric study bas been performed for the various refueling schemes of CANDU 6 reactor loaded with reference DUPIC fuel. The optimum discharge burnup was determined such that the peak bundle power is minimized for the equilibrium core. Based on the results of instantaneous core calculation using patterned random age distributions, it was decided to perform the refueling simulations only for 2-bundle and 4-bundle shift refueling schemes. The 600 FPD simulation has shown that the operational margins of the channel and bundle power to the license limits are 7.9% and 17.1%, respectively, for 2-bundle shift refueling scheme. The 4-bundle shift refueling scheme also satisfies the license limits and the operational margins of the channel and bundle power are 7.1% and 9.8%, respectively. The result of refueling simulation indicate the possibility of using reference DUPIC fuel in current CANDU 6 reactor.

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Speed Control of a Wind Turbine System Based on Pitch Control (피치제어형 풍력발전시스템의 속도제어)

  • Lim, Jong-Hwan;Huh, Jong-Chul
    • Journal of Institute of Control, Robotics and Systems
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    • v.7 no.2
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    • pp.109-116
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    • 2001
  • The paper presents a speed control algorithm for a full pitch-controlled wind turbine system. Torque of a blade generated by wind energy is a nonlinear function of wind speed, angular velocity, and pitch angle of the blade. The design of the controller, in general, is performed by linearizing the torque in the vicinity of the operating point assuming the angular velocity of the blade is constant. For speed control, however the angular velocity is on longer a constant, so that linearization of the torque in terms of wind speed and pitch angle is impossible. In this study, a reference pitch model is derived in terms of a wind speed, angular velocity, and pitch angle, which makes it possible to design a controller without linearizing the nonlinear torque model of the blade. This paper also suggests a method of designing a hydraulic control system for changing the pitch angle of the blade.

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Coordinated State-of-Charge Control Strategy for Microgrid during Islanded Operation

  • Kim, Jong-Yul;Jeon, Jin-Hong;Kim, Seul-Ki
    • Journal of Electrical Engineering and Technology
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    • v.7 no.6
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    • pp.824-833
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    • 2012
  • In this paper, a coordinated state-of-charge (SOC) control strategy for the energy storage system (ESS) operating under microgrid islanded mode to stabilize the frequency and voltage was proposed. The proposed SOC control loop is made up of PI controller, which uses a SOC state of the energy storage system as an input and an auxiliary reference value of secondary control as an output. The SOC controller changes the auxiliary reference value of secondary control to charge or discharge the ESS. To verify the proposed control strategy, PSCAD/EMTDC simulation study was performed. The simulation results show that the SOC of the ESS can be regulated at the desired operating range without degrading the stabilizing control performance by proposed coordinated SOC control method.

THE DEVELOPMENT OF A SAFETY ASSESSMENT APPROACH AND ITS IMPLICATION ON THE ADVANCED NUCLEAR FUEL CYCLE

  • Hwang, Yong-Soo;Kang, Chul-Hyung
    • Nuclear Engineering and Technology
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    • v.42 no.1
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    • pp.37-46
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    • 2010
  • The development of advanced nuclear fuel cycle(ANFC) technology is essential to meet the national mission for energy independence via a nuclear option in Korea. The action target is to develop environmentally friendly, cost-effective measures to reduce the burden of long term disposal. The proper scenarios regarding potential radionuclide release from a repository have been developed in this study based on the advanced korean Reference Disposal System(A-KRS). To predict safety for the various scenarios, a new assessment code based on the GoldSim software has also been developed. Deterministic analysis indicates an environmental benefit from the ANFC as long as the solid waster from the ANFC act as a proper barrier.

Preliminary analysis and design of the heat exchangers for the Molten Salt Fast Reactor

  • Ronco, Andrea Di;Cammi, Antonio;Lorenzi, Stefano
    • Nuclear Engineering and Technology
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    • v.52 no.1
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    • pp.51-58
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    • 2020
  • Despite the recent growth of interest in molten salt reactor technology and the crucial role which heat transfer plays in the design of power reactors, specific studies on the design of heat exchangers for the Molten Salt Fast Reactor have not yet been performed. In this work we deliver a preliminary but quantitative analysis of the intermediate heat exchangers, based on reference design data from the SAMOFAR H2020-Euratom project. Two different promising reference technologies are selected for study thanks to their compactness features, the Printed Circuit and the Helical Coil heat exchangers. We present preliminary design results for each technology, based on simplified design tools. Results highlight the limiting effects of the compactness constraints imposed on the fuel salt inventory and the allowed size. Large pressure drops on both flow sides are to be expected, with negative consequences on pumping power and natural circulation capabilities. The small size required for the flow channels also represents possible fabrication issues and safety concerns regarding channel blockage.

Application of Multichannel Quantum Defect Theory to the Triatomic van der Waals Predissociation Process

  • Chun-Woo Lee
    • Bulletin of the Korean Chemical Society
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    • v.12 no.2
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    • pp.228-238
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    • 1991
  • Generalized multichannel quantum defect theory [C. H. Greene et al. Phys. Rev., A26, 2441 (1982)] is implemented to the vibrational predissociation of triatomic van der Waals molecules. As this is the first one of such an application, the dependences of the quantum defect parameters on energy and radius are examined carefully. Calculation shows that, in the physically important region, quantum defect parameters remain smoothly varying functions of energy for this system as in atomic applications, thus allowing us very coarse energy mesh calculations for the photodissociation spectra. The choice of adiabatic or diabatic potentials as reference potentials for the calculation of quantum defect parameters as done by Mies and Julienne [J. Chem. Phys., 80, 2526 (1984)] can not be used for this system. Physically motivated reference potentials that may be generally applicable to all kinds of systems are utilized instead. In principle, implementation can be done to any other predissociation processes with the same method.

Adaptive Model Reference Control Based on Takagi-Sugeno Fuzzy Models with Applications to Flexible Joint Manipulators

  • Lee, Jongbae;Lim, Joon-hong;Park, Chang-Woo;Kim, Seungho
    • Journal of Mechanical Science and Technology
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    • v.18 no.3
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    • pp.337-346
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    • 2004
  • The control scheme using fuzzy modeling and Parallel Distributed Compensation (PDC) concept is proposed to provide asymptotic tracking of a reference signal for the flexible joint manipulators with uncertain parameters. From Lyapunov stability analysis and simulation results, the developed control law and adaptive law guarantee the boundedness of all signals in the closed-loop multi-input/multi-output system. In addition, the plant state tracks the state of the reference model asymptotically with time for any bounded reference input signal.