• 제목/요약/키워드: reduction-oxidation current

검색결과 117건 처리시간 0.028초

우수한 기계적 특성과 형상치수 확보를 위한 정밀 압출기술개발 (The Precise Extrusion-Technical Development to Get Excellent Mechanical-property and Accurate Shape- Dimension)

  • 이현철;이광식;오개희;박상우
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2009년도 춘계학술대회 논문집 특별세미나,특별/일반세션
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    • pp.311-320
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    • 2009
  • Most advanced countries are researching to apply light weight materials far rolling stock because weight reduction for railway body derives cost-saving, energy-saving, and high-speed. Likewise, current Korea rolling stock field makes arduous effects of weight-reduction, miniaturization, and high-efficiency to achieve a high-speed railway. Aluminum becomes suitable material for these projects because it is much lighter than steel or stainless. Manufacturing the railway car body by using the Aluminum is increasing because Aluminum is not bringing the corrosion by unique oxidation-passivate. Aluminum extrusion profile far railway body requires a high mechanical property, accurate shape dimension, and stable quality because the railway body is composed with many different kinds of extruded profiles. Therefore, it is necessary to research about Aluminum precision-extrusion technology to maintain exit temperature and die load. The goal of this project is applying the Aluminum extrusion profile to next-generation railway car body by developing the Aluminum extrusion profile according to precision-extrusion technology which may maintain isothermal exit temperature.

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Resistive Switching in Vapor Phase Polymerized Poly (3, 4-ethylenedioxythiophene)

  • ;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.384-384
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    • 2012
  • We report nonvolatile memory properties of poly (3, 4-ethylenedioxythiophene) (PEDOT) thin films grown by vapor phase polymerization using FeCl3 as an oxidant. Liquid-bridge-mediated transfer method was employed to remove FeCl3 for generation of pure PEDOT thin films. From the electrical measurement of memory device, we observed voltage induced bipolar resistive switching behavior with ON/OFF ratio of 103 and reproducibility of more than 103 dc sweeping cycles. ON and OFF states were stable up to 104 seconds without significant degradation. Cyclic voltammetry data illustrates resistive switching effect can be attributed to formation and rupture of conducting paths due to oxidation and reduction of PEDOT. The maximum current before reset process was found to be increase linearly with increase in compliance current applied during set process.

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RC조 구조물의 최적 음극방식 조건 설정을 위한 함수율의 영향에 대한 평가 (Effect of Moisture on the Current Density for Optimized Cathodic Protection Condition in RC Structures)

  • 박동천;조규환;안재철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2013년도 춘계 학술논문 발표대회
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    • pp.29-30
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    • 2013
  • Steel corrosion is the most serious problem in RC structures. Even though patch repair method is normally applied in repair system, the effectiveness is not enough. Cathodic protection in active repair method to deteriorated RC structures. FEM model was developed to simulate the optimized cathodic protection condition. Iro oxidation, hydrogen evolution and oxygen reduction were considered to expect current distribution. Moisture content in concrete which can affect the electrolyte conductivity was used as initial condition.

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폴리이미드와 인지질 혼합물의 나노 Langmuir-Blodgett막의 전기화학적 특성에 관한 연구 (A Study on the Electrochemical Properties of Langmuir-Blodgett Nano-film Mixed with Polyimide and Phospholipid)

  • 박근호
    • 한국응용과학기술학회지
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    • 제29권3호
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    • pp.421-428
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    • 2012
  • 우리는 순환전압전류법에 의한 폴리이미드와 인지질혼합 나노LB 필름에 대한 전기화학적 특성을 조사하였다. polyamic acid와 인지질 단분자 LB막은 ITO glass에 Langmuir-Blodgett법을 사용하여 제막하였다. 전기화학적 특성은 $KClO_4$ 용액에서 3 전극 시스템 (Ag/AgCl 기준전극, 백금선 카운터 전극 및 LB 필름이 코팅된 ITO 작업 전극)으로 순환전압전류법을 사용하여 측정하였다. 측정 범위는 연속적으로 1650 mV로 산화시키고, 초기전위인 -1350 mV로 환원시켰다. 주사속도는 각각 50, 100, 150, 200 및 250 mV/s였다. 그 결과 polyamic acid와 인지질 혼합물의 LB 필름은 순환전압전류도표로부터 환원전류로 인한 비가역공정으로 나타났다. Polyamic acid와 인지질혼합 LB막에서 확산계수(D)효과는 LAPC를 사용한 경우가 LLPC를 사용한 것 보다 확산계수 값이 적었다.

인지질(Sphingomyelin)과 Polyamic Acid 혼합물의 단분자 LB막의 전기화학적 특성에 관한 연구 (A Study on the Electrochemical Properties of Langmuir-Blodgett Monolayer Film Mixed with Polyamic Acid and Sphingomyelin)

  • 박근호
    • 한국응용과학기술학회지
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    • 제30권1호
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    • pp.64-70
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    • 2013
  • 우리는 순환전압전류법에 의한 인지질(sphingomyelin)과 polyamic acid 혼합물의 단분자 LB막에 대한 전기화학적 특성을 조사하였다. Sphingomyelin과 polyamic acid 혼합물의 단분자 LB막은 ITO glass에 LB법을 사용하여 제막하였다. 전기화학적 특성은 $KClO_4$ 용액에서 3 전극 시스템으로 측정하였다. 측정 범위는 연속적으로 1650 mV로 산화시키고, 초기 전위인 -1350 mV로 환원시켰다. 주사속도는 각각 50, 100, 150, 200 및 250 mV/s로 설정하였다. 그 결과 sphingomyelin과 polyamic acid 혼합물의 LB막은 순환전압전류도표로부터 환원전류로 인한 비가역공정으로 나타났다. Sphingomyelin과 polyamic acid 혼합물 LB막에서 전해질농도가 0.1N과 0.2N에서 확산계수(D)는 각각 $2.67cm^2s^{-1}{\times}10^5$$5.23cm^2s^{-1}{\times}10^6$을 얻었다.

용존산소 측정을 위한 무선통신 기반 휴대형 포텐쇼스탯 개발 (Development of a Portable Potentiostat with Wireless Communications for Measuring Dissolved Oxygen)

  • 이현석;한지훈;박정호
    • 전기학회논문지
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    • 제67권12호
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    • pp.1641-1647
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    • 2018
  • In this paper, we describe a portable potentiostat which is capable of cyclic voltammetry(CV) and amperometry for electrochemical dissolved oxygen sensor. In addition, this portable potentiostat can also transmit the measured data wirelessly to android devices such as smart phone, tablet, etc. through Bluetooth. The potentiostat system consists of three parts; a voltage generator circuit which is controlled by Arduino nano and 12-bit DAC(digital to analog converter) to generate necessary electric potential for operating the electrochemical sensor, an oxidation/reduction current measurement circuit, and a Bluetooth module to transmit data wirelessly to an android device. Once measurements are carried out with the android application, the measured data is transmitted to the android device via Bluetooth and displayed using the android app. in real time. In this paper, we report the measured reduction current with a fabricated dissolved oxygen sensor in both saturated-oxygen state and zero-oxygen states. The results of the developed portable potentiostat system are in good agreement with those of the commercial portable potentiostat (${\mu}stat200$, Dropsens inc.). The measured peak reduction currents using the developed potentiostat and the commercial ${\mu}stat200$ potentiostat were $-0.755{\mu}A$ and $-0.724{\mu}A$, respectively. The reduction currents measured at zero-oxygen state were $-0.005{\mu}A$ and $-0.004{\mu}A$. The discrepancy between those two systems seems very small, which implies successful development of a portable and wireless potentionstat.

Evaluating productive performance, meat quality and oxidation products of Italian White breed rabbits under free-range and cage rearing system

  • Tufarelli, Vincenzo;Tateo, Alessandra;Schiavitto, Michele;Mazzei, Domenico;Calzaretti, Giovanna;Laudadio, Vito
    • Animal Bioscience
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    • 제35권6호
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    • pp.884-891
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    • 2022
  • Objective: Free-range systems have been increasingly available to the consumer due to increased demand for more sustainable meat-products. In the current study, the effect of free-range (FR) and cage system (CS) was explored on growth performance, meat quality and oxidation products in Italian White breed rabbits during the growing-fattening phase (5 to 13 weeks of age). Methods: Forty rabbits were randomly allotted to two treatment groups according to the rearing system, and each treatment group was replicated five times with four subjects in each replicate (20 rabbits per treatment-group). All rabbits fed the same diet as pelleted, and under FR system, no additional feeds were available to animals. Results: Rearing system had significant effect on rabbit growth performance, where CS group resulted in higher final body weight (p<0.045) and gain (p<0.029) and better feed efficiency (p<0.025) compared to FR rabbits. Most carcass traits were not affected by rearing system; however, a reduction of abdominal fat content (p<0.015) and meat lipids (p<0.034) was observed in FR rabbits. Rearing system had no effects on meat fatty acid profile, whereas meat from FR rabbits resulted less susceptible to lipid and protein oxidation compared to caged animals. Conclusion: In overall, FR system could be suggested as a substitute for conventional caged system because of FR system preserved rabbit meat from oxidation.

FPGA SoC를 이용한 네모파 전압전류법의 주파수 변화에 따른 계측 분석 (Determination of Frequency for decision of heavy metal ion concentration in Square Wave Voltammetry with FPGA SoC)

  • 이재춘
    • 디지털산업정보학회논문지
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    • 제14권4호
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    • pp.101-107
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    • 2018
  • In the stripping scan square wave voltammetry (SV+SWV) polarography that is often used to analyze the concentration of heavy metals in water, we must measure the point where the faradic current that flows by the pure oxidation-reduction reaction at the electrode is greater than the capacitive current, the frequency cannot be too high. Therefore we wanted to find the frequency range that can be measured. In order to do this, we came up with a method to analyze the signal using FPGA Soc. With this method, the frequency of the square wave was increased from 10Hz to 400Hz by 10Hz, and the measuring time of the square wave was changed from 96.695% to 96.765% by 0.005% while 1600 experiments were conducted. As a result, the frequency of the square wave maintained a stable area of potential-current within 320Hz and it was possible to measure the potential-current signal when calculating the measuring time within the frequency range of 96.7155%.

$O_2$RTA 방법으로 제조된 $Ta_2O_{5-x}$ 박막의 전기적 특성 (A Study on Electrical Properties of $Ta_2O_{5-x}$ Thin-films Obtained by $O_2$ RTA)

  • 김인성;송재성;윤문수;박정후
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제51권8호
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    • pp.340-346
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    • 2002
  • Capacitor material utilized in the downsizing passive devices and integration of passive devices requires the physical and electrical properties at given area such as capacitor thickness reduction, relative dielectric constant increase, low leakage current and thermal stability. common capacitor materials, $Al_2O_3$, $SiO_2$, $Si_3N_4$, $SiO_2$/$Si_3N_4$, TaN and et al., used until recently have reached their physical limits in their application to integration of passive devices. $Ta_2O_{5}$ is known to be a good alternative to the existing materials for the capacitor application because of its high dielectric constant (25~35), low leakage current and high breakdown strength. Despite the numerous investigations of $Ta_2O_{5}$ material, there have little been established the clear understanding of the annealing effect on capacitance characteristic and conduction mechanism. This study presents the dielectric properties $Ta_2O_{5}$ MIM capacitor structure Processed by $O_2$ RTA oxidation. X-ray diffraction patterns showed the existence of amorphous phase in $600^{\circ}C$ annealing under the $O_2$ RTA and the formation of preferentially oriented-$Ta_2O_{5}$ in 650, $700^{\circ}C$ annealing and the AES depth profile showed $O_2$ RTA oxidation effect gives rise to the $O_2$ deficientd into the new layer. The leakage current density respectively, at 3~1l$\times$$10_{-2}$(kV/cm) were $10_{-3}$~$10_{-6}$(A/$\textrm{cm}^2$). In addition, behavior is stable irrespective of applied electric field. the frequency vs capacitance characteristic enhanced stability more then $Ta_2O_{5}$ thin films obtained by $O_2$ reactive sputtering. The capacitance vs voltage measurement that, Vfb(flat-band voltage) was increase dependance on the $O_2$ RTA oxidation temperature.

화학제염공정에서 환원공정조건에 따른 Inconel 600의 부식손상 특성 (Corrosion Damage Characteristics of Inconel 600 with Reduction Conditions in Chemical Decontamination Process)

  • 한민수;정광후;양예진;박일초;이정형;김성종
    • 한국표면공학회지
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    • 제50권5호
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    • pp.332-338
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    • 2017
  • In this study, we evaluated tendency and degree of corrosion damages of Inconel 600 after chemical decontamination treatments under three different conditions. In the decontamination processes, the oxidation and reduction were performed as one cycle. Each process was continued up to 5 cycles. Characteristics of corrosion under decontamination processes were evaluated by Tafel analysis and weight loss. Characteristics of surface damage were observed by scanning electron microscope(SEM) and three-dimensional(3D) microscope. As the cycle proceeded, weight loss and corrosion current density increased. Intergranular corrosion damage occurred on the surface of the materials. The result revealed that the surface of Inconel 600 was attacked by the strong acid solution under all chemical decontamination processes, but the degree of the corrosion damage was different depending on the processes.