• Title/Summary/Keyword: reduction atmosphere

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Variations on the Concentration of Dissolved Gaseous Mercury(DGM) at the Juam Reservoir, Korea (주암호의 용존가스상 수은의 농도변화 특성에 관한 연구)

  • Park, Jong-Sung;Oh, Se-Hee;Shin, Mi-Yeon;Yi, Seung-Muk;Zoh, Kyung-Duk
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.6
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    • pp.667-676
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    • 2006
  • The reduction of $Hg^{2+}$ in the aqueous phase results in the production of dissolved gaseous mercury(DGM), and the volatilization of DGM has been identified as an important mechanism for the loss of Hg from waterbodies to the atmosphere. Although mercury emission in the world is known to be mostly from Asia, there have been few studies of measuring DGM concentrations in lakes in Asia. In this study, DGM concentrations were measured at Juam reservoir($35^{\cir}00'N,\;127^{\circ}14'E$), Korea. The results showed that the average concentrations of DGM at the upper and down stream of the lake during summer time were $95{\pm}8\;and\;130{\pm}15$ pg/L, respectively and the concentration of total mercury(TM) at the upper and down stream was $2.1{\pm}0.7,\;1.7{\pm}0.3$ ng/L respectively. Average DGM concentration during summer time($101{\pm}14pg/L$) was approximately 5.5 times higher than that during fall($18{\pm}0.1pg/L$). The DGM concentrations ai the midstream decreased from 32 to 13.7 pg/L during rain event, while the TM concentrations increased from 2.2 ng/L to 2.7 ng/L indicating the deposition of mercury from the atmosphere. Also, the diurnal patterns between DGM concentrations and UV intensities were observed. Water temperatures and DOC concentrations were significantly related to DGM concentrations, while TM concentrations were negatively related to DGM concentrations(p<0.0001). Comparing with the study of Dill et al.,(2006) the average concentrations of DGM $(109{\pm}15pg/L)\;and\;TM(2.2{\pm} 0.4ng/L)$ at Juam reservoir were approximately 3 and 2.2 times higher than those measured in other lakes(DGM: $38{\pm}16pg/L$, TM: $1.0{\pm}1.2ng/L$).

Surface characteristics and stability of implants treated with alkali and heat (알칼리와 열처리에 의한 임플란트의 표면 특성 및 골유착 안정성에 관한 연구)

  • Song, Yun-Seok;Cho, In-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.46 no.5
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    • pp.490-499
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    • 2008
  • Statement of problem: Bioactive materials must have the ability to spontaneously form a bone like apatite layer on their surface and induce direct biochemical bonding to bone. A simple chemical treatment via alkali and heat has been revealed to induce bioactivity in titanium. Purpose: The purpose of this study was to evaluate the surface characteristics and stability of alkali and heat treated implants. Material and methods: Specimens were divided into three groups; group 1 was the control group with machined surface implants, groups 2 and 3 were treated with alkali solutions and heat treated in the atmosphere and vacuum conditions respectively. The surface characteristics were observed with FESEM, XPS, TF-XRD and AFM. Stability was evaluated with the resonance frequency analysis, periotest and removal torque values. One-way ANOVA and Duncan test were used for statistical analysis. Results: 1. Groups treated with alkali and heat showed similar characteristics. Groups 2 and 3 showed high compositions of Na ions on the surface with sub-micron sized pores compared to group 1. Group 2 showed mixed compositions of anatase and rutile with superior contents of rutile. 2. Resonance frequency analysis : The ISQ of group 2 showed significantly higher values than that of groups 1 and 3 at 12 weeks. The ISQ of groups 1 and 2 showed significant increase after 4 weeks, and the ISQ of group 3 increased significantly after 2 and 4 weeks respectively (P < .05). 3. Periotest: The PTV of groups 1 and 2 showed significant decrease after 4 weeks, and the PTV of group 3 showed significant decrease after 2 and 4 weeks respectively (P < .05). 4. Removal torque analysis: The removal torque value of group 2 was significantly higher than those of groups 1 and 3 at 2, 4 and 8 weeks. The removal torque values of groups 1 and 3 showed increase at 4 and 12 weeks, but the removal torque value of group 2 showed increase after 4 weeks (P < .05). Conclusion: An oxide layer with appropriate crystal structure and amorphous sodium titanate layer can be obtained on titanium implants through alkali and heat treatment in the atmosphere, and even alkali and heat treatment in vacuum conditions, provided a bioactive surface containing sodium. These surface layers can be considered to be effective for enhancement of osseointegration and reduction of healing period for implant treatment.

Effect of operating temperature using Ni-Al-$ZrH_2$ anode in molten carbonate fuel cell (Ni-Al-$ZrH_2$ 연료극을 사용한 용융탄산염 연료전지의 온도의 영향)

  • Seo, Dongho;Jang, Seongcheol;Yoon, Sungpil;Nam, Suk Woo;Oh, In-Hwan;Lim, Tae-Hoon;Hong, Seong-Ahn;Han, Jonghee
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.134-134
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    • 2010
  • Fuel cell is a device that directly converts chemical energy in the form of a fuel into electrical energy by way of an electrochemical reaction. In the anode for a high temperature fuel cell, nickel or nickel alloy has been used in consideration of the cost, oxidation catalystic ability of hydrogen which is used as fuel, electron conductivity, and high temperature stability in reducing atmosphere. Most MCFC stacks currently operate at an average temperature of $650^{\circ}C$. There is some gains with decreased temperature in MCFC to diminish the electrolyte loss from evaporation and the material corrosion, which could improve the MCFC life. However, operating temperature has a strong related on a number of electrode reaction rates and ohmic losses. Baker et al. reported the effect of temperature (575 to $650^{\circ}C$). The rates of cell voltage loss were 1.4mV/$^{\circ}C$ for a reduction in temperature from 650 to $600^{\circ}C$, and 2.16mV/$^{\circ}C$ for a decrease from 600 to $575^{\circ}C$. The two major contributors responsible for the change in cell voltage with reducing operation temperature are the ohmic polarization and electrode polarization. It appears that in the temperature range of 550 to $650^{\circ}C$, about 1/3 of the total change in cell voltage with decreasing temperature is due to an increase in ohmic polarization, and the electrode polarization at the anode and cathode. In addition, the oxidation reaction of hydrogen on an ordinary nickel alloy anode in MCFC is generally considered to take place in the three phase zone, but anyway the area contributing to this reaction is limited. Therefore, in order to maintain a high performance of the fuel cell, it is necessary to keep this reaction responsible area as wide as possible, that is, it is needed to keep the porosity and specific surface area of the anode at a high level. In this study effective anodes are prepared for low temperature MCFC capable of enhancing the cell performance by using zirconium hydride at least in part of anode material.

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Analysis of research trends in methane emissions from rice paddies in Korea

  • Choi, Eun-Jung;Lee, Jae-Han;Jeong, Hyun-Cheol;Kim, Su-Hun;Lim, Ji-Sun;Lee, Dong-Kyu;Oh, Taek-Keun
    • Korean Journal of Agricultural Science
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    • v.44 no.4
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    • pp.463-476
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    • 2017
  • Climate change is considered as the greatest threat to our future and descendants. The Korean government has set a target for 2030 to reduce emission of greenhouse gases (GHGs) by 37% from the business-as-usual levels which are projected to reach 851 million metric tons of $CO_2eq$ (Carbon dioxide equivalent). In Korea, GHGs emission from agriculture account for almost 3.1% of the total of anthropogenic GHGs. The GHGs emitted from agricultural land are largely classified into three types: carbon dioxide ($CO_2$), methane ($CH_4$), and nitrous oxide ($N_2O$). In Korea, rice paddies are one of the largest agricultural $CH_4$ sources. In order to analyze domestic research trends related to $CH_4$ emission from rice paddies, 93 academic publications including peer reviewed journals, books, working papers, reports, etc., published from 1995 to September 2017, were critically reviewed. The results were classified according to the research purposes. $CH_4$ characteristics and assessment were found to account for approximately 65.9% of the research trends, development of $CH_4$ emission factors for 9.5%, $CH_4$ emission reduction technology for 14.8%, and $CH_4$ emission modeling for 6.3%, etc. A number of research related to $CH_4$ emission characteristics and assessment have been studied in recent years, whereas further study on $CH_4$ emission factors are required to determine an accurate country-specific GHG emission from rice paddies. Future research should be directed toward both studies for reducing the release of $CH_4$ from rice paddies to the atmosphere and the understanding of the major controlling factors affecting $CH_4$ emission.

The Effect of Residual Stress on Magnetoresistance in GMR Head Multilayers (자기기록 MR 헤드 용 다층박막의 자기저항에 미치는 잔류응력 효과)

  • Hwang, Do-Guwn
    • Journal of the Korean Society for Nondestructive Testing
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    • v.23 no.4
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    • pp.322-327
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    • 2003
  • Giant magnetoresistance(GMR) NiO multilayer, which has been used to reading head of highly dense magnetic recording, was fabricated, and oxidized in an air during 80 days to study the dependence of magnetoresistance properties on residual stress in the interfaces. The magnetoresistance ratio and the exchange biasing $field(H_{ex})$ of $NiO(60nm)/Ni_{81}Fe_{19}(5nm)/Co(0.7nm)/Cu(2nm)/Co(0.7nm)/Ni_{81}Fe_{19}(7nm)$ spin valves were increased from 4.9% to 7.3%, and 110 Oe to 170 Oe after natural oxidation in the atmosphere for 80 days, respectively. The sheet resistivity ${\rho}$ decreased from $28{\mu}{\Omega}m$ to $17{\mu}{\Omega}m$, but ${\Delta}p$ did not almost change after the oxidation. Therefore, the increase of MR ratio is due to the decrease in the sheet resistivity. the reduced resistance may result from the increase in the reflection of conduction electrons at the oxidized top surface. Also, the increase in the exchange biasing field is originated from the reduction of residual stress at the interface of $NiO/Ni_{81}Fe_{19}$ according as the aging time increases.

The Directivity of Traditional Architectural Space in Korean and Japanese (한국${\cdot}$일본 전통건축공간의 지향성)

  • Kim Dong-Young
    • Journal of the Korean housing association
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    • v.16 no.6
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    • pp.101-109
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    • 2005
  • As a circumstantial-existance character (the human character who takes action after grasping circumstances and fears things with reason) the Japanese were more interested in the active doctrines of Wang Yang-ming than other speculative studies. All of people were inhumanely incorporated into the rigorous class system under pressure in the samurai society. In the atmosphere of the society a natural phenomenon was understood as the ksana of change, and instead of the whole, the part was mainly described with emphasis on the reality. Therefore nature came near to the man after being reduced and then was symbolized in the Interior space. Also the classification of spaces, that is to say, the settlement of borders by the social position was shown in the great interior space like a labyrinth. As a self-existance character(the human style who carves out for and does not have a regard other's feeling), however, the Korean were much influenced by the Taoist Idea as they tried to be similar to nature in nature itself. Therefore the idea of Asaniskrota was in their origin. There was a tendency for space to be extended toward the outdoor in Korea, since the Korean people who are speculative and like to be natural tried to be close to nature. Therefore the division of spaces according to class and sexuality and the settlement of borders were already shown in outside by Che-Na-Num(Divided-Mass:Koren's own style). These are closely related with that houses were built after a village settle down in Korea while built before a village settle down in Japan. Architectural space consists of the interior and the exterior. The layout and (on of architectural space has a great variety of characters by region and culture. In other words, it can be understood which has a priority between the interior and the exterior in developing the layout and the form of architectural space. Belonging to the culture area of Chinese characters with Korea, Japan has maintained its own Identity. It has an identity in the layout and form of architectural space as well. Therefore, the architecture and architectural theories of the two countries were compared and analyzed with priority given to the traditional architecture, also the backgrounds of architecture and architectural theories of two countries were examined in this study. This study shows that each country has different characters in how to introduce nature, how to expand space and how to compose windows, including the view of nature and the cult of space. As a result, the space in Korean architecture has relatively the exterior-oriented character but in Japan architecture spatial character is interior-oriented. The interior-oriented character can be relevant to the word 'reduction' and the exterior-oriented character to 'extension' after all. Also it can be thought that each character has a great relation with climate and idea of people in power.

Evaluation of CO2 Balance in the Barley-Red Pepper and Barley-Soybean Cropping System (보리-고추와 보리-콩 작부체계에서 이산화탄소수지 평가)

  • Kim, Gun-Yeob;Suh, Sang-Uk;Ko, Byung-Gu;Jeong, Hyun-Cheol;Roh, Kee-An;Shim, Kyo-Moon
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.6
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    • pp.408-414
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    • 2008
  • Importance of climate change and its impact on agriculture and environment has increased with the rise Green House Gases (GHGs) concentration in the atmosphere. To slow down the speed of climate change many efforts have been applied in industrial sectors to reduce GHGs emission and to enhance carbon storage. In agricultural sector, many researches have been performed on GHGs emission reduction, but few on the role of carbon sink. In this study, we investigated carbon balance and soil carbon storage in agricultural field in the barley-red pepper and barley-soybean cropping system. With the system for automatic measuring of carbon dioxide, net ecosystem production(NEP) was estimated to be $6.3ton\;CO_2\;ha-1$ for N-P-K chemical fertilizer treatment plot and $10.6ton\;CO_2\;ha^{-1}$ for N-P-K chemical fertilizer with swine manure treatment plot in the barley-soybean rotation cropping. In the barley-red pepper rotation cropping, it was $12.0ton\;CO_2\;ha^{-1}$ for N-P-K chemical fertilizer treatment plot and $13.2ton\;CO_2\;ha^{-1}$ for N-P-K chemical fertilizer with swine manure treatment plot. Soil carbon storage rate was estimated to be $0.7ton\;C\;ha^{-1}$ for the barley-soybean cropping system and $0.5ton\;C\;ha^{-1}$ for barley-pepper cropping system. In appeared that agricultural lands may contribute to the greenhouse effect as a potential carbon sink preserving carbon into soil.

Thermoelectric Properties of the Hot-pressed n-Type $Bi_2({Te_{0.85}}{Se_{0.15}})_3$ Alloy Prepared by Mechanical Alloying (기계적 합금화 공정을 이용하여 제조한 n형 $Bi_2({Te_{0.85}}{Se_{0.15}})_3$ 가압소결체의 열전특성)

  • Kim, Hui-Jeong;O, Tae-Seong;Hyeon, Do-Bin
    • Korean Journal of Materials Research
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    • v.10 no.3
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    • pp.246-252
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    • 2000
  • Thermoelectric properties of the $Bi_2(Te_{0.85}Se_{0.15})_3$ alloy, prepared by mechanical alloying and hot pressing, were investigated with the variation of the hot-pressing temperature ranging from $300^{\circ}C$ to $550^{\circ}C$. Contrary to the p-type behavior of single crystal, the hot-pressed $Bi_2(Te_{0.85}Se_{0.15})_3$ alloy exhibited n-type conduction without addition of donor dopant. When the $Bi_2(Te_{0.85}Se_{0.15})_3$ powders were annealed in $(50{\%}\;H_2+50{\%}\;Ar)$ atmosphere, the hot-pressed specimens exhibited a positive Seebeck coefficient due to the reduction of the electron concentration by removal of the oxide layer on the powder surface and annealing-out of the excess Te vacancies. Figure-of-merit of the hot-pressed $Bi_2(Te_{0.85}Se_{0.15})_3$ alloy was improved by hot pressing at temperatures above $450^{\circ}C$, and the maximum value of $1.92{\times}10^{-3}/K$ was obtained for the specimen hot-pressed at $550^{\circ}C$.

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Manufacturing of Artificial Lightweight Aggregates using a Coal Fly Ash Discharged from Fluidized Bed Combustor (유동층(流動層) 연소기(撚燒器)로 부터 발생(發生)된 석탄(石炭) 비산(飛散)재를 이용(利用)한 인공경량골재(人工輕量骨材) 제조(製造))

  • Kang, Min-A;Kang, Seung-Gu
    • Resources Recycling
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    • v.20 no.1
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    • pp.54-60
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    • 2011
  • The spherical artificial aggregates (AAs) with a diameter of 8 mm, which contains fly ashes discharged from the fluidized bed combustion in a thermal power plant and clay were manufactured by direct sintering method at $1050{\sim}1250^{\circ}C$ for 10 minutes. The effect of fly ash contents on the bloating phenomenon in the AAs was analyzed. The AAs containing fly ash of the amount under 50 wt% showed the black-coring and bloating phenomena. The AAs containing fly ash of the amount over 5Owt%, however, the specific gravity was increased and the color of specimens fully changed to black. These color change phenomena were caused from the formation of FeO by the reduction reaction of almost $Fe_2O_3$ component by the excessive reducing atmosphere formed simultaneously with the rapid emission of the gases generated from the high contents of unburned carbon of with increasing the added fly ash amount. Specific gravity was decreased as fly ash contents increased in the case of sintering at the same temperature condition. Water absorption of all specimens except of the specimens containing 10 wt% fly ashes decreased with increasing sintering temperature. These were because a liquid phase was formed as the increasing the sintering temperature. In the case of the specimens manufactured in this study containing fly ashes discharged from the fluidized bed combustor in a the thermal power plant and 10~90 wt% of clay, the specific gravity was 0.9~1.8 and the water absorptivity was 8~60%, therefore it is considered that those results can be applied to the light or heavy aggregates.

Energy efficiency improvements in part load for a marine auxiliary diesel engine (선박발전기용 디젤엔진의 부분부하에서 에너지 효율 개선에 관한연구)

  • Jung, Kyun-Sik
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.7
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    • pp.877-882
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    • 2014
  • The reduction of CO2 emission has been discussed in the Marine Environment Protection committee in the International Maritime Organization as the biggest causes of GHG for the purpose of indexing CO2 amounts released into the atmosphere from ships. Accordingly, various methods including the change in the hull design to improve energy efficiency, the coating development to reduce friction resistances, the additives development for improving thermal efficiency in an engine, the low-speed operation to reduce fuel consumptions, and etc. have been applied. The main engine of a ship is an electronic engine for improving the efficiency of the whole load area. However, marine generator engines still use mechanical drive engines in intake, exhaust, and fuel injection valve drive cams. In addition, most of marine generator engines in ships apply a part-load operation of less then 80% due to an overload protection system. Therefore, marine auxiliary diesel engine set at 100% load is necessary to readjust in order to efficient operation because of part-load operation. The objective of this study is to report the results of the part-load fuel consumption improvement by injection timing readjust to identifying the operational characteristics of a marine generator engine currently operated in a ship.