• Bulletin of the Korean Chemical Society
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• v.8 no.1
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• pp.15-19
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• 1987

Preparation of optically pure (3R, 4R)-4-acetoxy-3-[(1R)-1-hydroxyethyl]azetidin-2-o ne derivatives, which can be employed as starting materials for synthesis of carbapenem and penem antibiotics, was established in high efficiency from 6-amino-penicillanic acid (6-APA). 6-APA was diazotized and brominated to give 6, 6-dibromopenicillanic acid and its methyl ester was metalated with methylmagnesium bromide and condensed with acetaldehyde. The product, methyl 6-bromo-6-(1-hydroxyethyl)penicillanate was reduced with Zn-$NH_4Cl-NH_4OH$-acetone efficiently to give methyl 6-(l-hydroxyethyl)-penicillanate, which was protected either with ${\beta},{\beta},{\beta}$ -trichloroethoxycarbonyl group or with t-butyldimethylsilyl group. The thiazolidine rings of these compounds were cleaved by treatment of mercury(II) acetate in acetic acid and permangante in acetone in sequence to afford the desired optically pure final products.

• Bulletin of the Korean Chemical Society
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• v.20 no.6
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• pp.643-647
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• 1999

Hydropalladium carboxylates, formed from π-allylpalladium chloride dimer plus carboxylic acids, have been shown to catalyze cyclization of structurally diverse enediynes to form the corresponding six- or five-membered rings depending upon the reaction conditions. Some enediynes having an Oxygen linker in an appropriate position under the similar condition yielded the corresponding cyclopropanation products in highly stereoselective manner. A study using deuterated formic acid has proven that the alkylpalladium intermediates formed in our conditions were reduced by the pendant formate ligand. The dienediyne 10 yielded only the tricyclic product 12 in 67% yield, although it was expected to frrm the cyclic product 11. All these cyclizations seemed to occur via the corresponding alkylpalladium intermediates I. which could proceed to the corresponding cyclic products depending on the reaction conditions and the substrates. The study using ceuterated formic acid could provide an important information to understand the present cyclization mechanism. Overall the present study could play an important role in developing new synthetic methodologies for constructing complex polycyclic compounds.

• Communications of the Korean Mathematical Society
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• v.34 no.1
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• pp.127-136
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• 2019

This article concerns the normal property of elements on Jacobson and nil radicals which are generalizations of commutativity. A ring is said to be right njr if it satisfies the normal property on the Jacobson radical. Similarly a ring is said to be right nunr (resp., right nlnr) if it satisfies the normal property on the upper (resp., lower) nilradical. We investigate the relations between right duo property and the normality on Jacobson (nil) radicals. Related examples are investigated in the procedure of studying the structures of right njr, nunr, and nlnr rings.

• Communications of the Korean Mathematical Society
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• v.38 no.1
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• pp.121-122
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• 2023

In this erratum, we correct a mistake in the proof of Proposition 2.7. In fact the equivalence (3) ⇐ (4) "R is a quasi-regular ring if and only if R is a reduced ring and every principal ideal contained in Z(R) is a 0-ideal" does not hold as we only have Rx ⊆ O(S).

• Bulletin of the Korean Chemical Society
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• v.14 no.5
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• pp.603-610
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• 1993

The crystal structure of dehydrated $Ag_{5.6}K_{6.4}-A$, zeolite A ion-exchanged with $K^+\;and\;Ag^+$ as indicated and dehydrated at 360$^{\circ}$C, has been determined by single-crystal X-ray diffraction techniques. Also determined were the structures of the products of the reactions of this zeolite with 0.1 Torr of Cs vapor at 250$^{\circ}$C for 48 h and 72 h, and with 0.1 Torr of Rb vapor at 250$^{\circ}$C for 24 h. The structures were solved and refined in the cubic space group Pm3m at 21(l)$^{\circ}$C (a= 12.255(l) ${\AA}$ , 12.367(l) ${\AA}$, 12.350(l) ${\AA}$, and 12.263(l) ${\AA}$, respectively). Dehydrated $Ag_{5.6}K_{6.4}$-A was refined to the final error indices $R_1= 0.044\;and\;R_2=0.037$ with 202 reflections for which I>3${\sigma}$(I). The crystal structures of the reaction products were refined to $R_1=0.087\;and\;R_2= 0.089$ with 157 reflections, $R_1=0.080\;and\;R_2= 0.087$ with 161 reflections, and $R_1= 0.071\;and\;R_2=0.061$ with 88 reflections, respectively. In the structure of $Ag_{5.6}K_{6.4}-A,\;K^+$ ions block all 8-oxygen rings, and one reduced Ag atom is found per sodalite cavity. Also, ca. 4.6 $Ag^+ ions\;and\;3.4 K^+ ions$ are found at 6-ring sites in the large cavity. The crystal structures of the reaction products show that all $K^+$ and $Ag^+$ ions have been reduced, and that all K^+$ atoms have left the zeolite. Cs or Rb species are found at three different crystallographic sites: 3.0 $Cs^+\;or\;3.0Rb^+$ ions per unit cell occupy 8-ring centers, ca. 8.0 $Cs^+ ions\;or\;5.7 Rb^+$ ions, are found on threefold axes opposite 6-rings deep in the large cavity, and ca. 2.5 $Cs^+\;or\;2.3 Rb^+ ions are found on threefold axes in the sodalite unit. Also, 1 $Rb^+$ ion lies opposite a 4-ring. Silver atoms, corresponding to 75% or 40% occupancy of hexasilver clusters stabilized by coordination to $Cs^+\;or\;Rb^+$ ions, are found at the centers of the large cavities. In the crystal structures of dehydrated Ag_{5.6}K_{6.4}-A$ reacted with Cs vapor, excess Cs atoms are absorbed and these form (locally) cationic clusters such as $(Cs_4)3^+\;and\;(Cs_6)4^+$.

• Bulletin of the Korean Chemical Society
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• v.5 no.4
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• pp.135-140
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• 1984

The reduction of vacuum-dehydrated $Na_xAg_{12-x}-A, 0 {\le} x {\le} 9.2$, and its reoxidation by O$_2$, have been studied by X-ray powder diffraction. Also, the structure of $Na_6Na_6-A$ treated with hydrogen at room temperature has been studied by single crystal methods in the cubic space group Pm3m at $24{\circ}C (a = 12.221(2) {\AA})$. The diffraction pattern of dehydrated Ag$_{12}$-A reduced by H$_2$ contains only the (111) and (200) reflections of silver metal, indicationg that the zeolite structure has been lost, but the zeolite's diffraction pattern and structural integrity can be fully restored by oxidation with O$_2$ at 100 or 200${\circ}C$. In contrast, the structures of $Na_xAg_{12-x}-A$, x = 4.5 and 9.2, were not destroyed by treatment with hydrogen. Dehydrated Na$_6Ag_6$-A treated with 50 Torr of hydrogen gas at 24${\circ}C$ for 30 minutes has $6\; Na^+\;and\;1.27\;Ag^+$ ions at 6-ring sites. These $Ag^+ ions are associated with 2.54 Ag${\circ}$ atoms to form 1.27 $Ag_3^+$ clusters per unit cell. Also found were 0.7 $Ag_3^{2+}$ clusters per unit cell near the 8-rings. The structure was refined to the final error indices R$_1$ = 0.134 and R$_2$ (weighted) = 0.147, using 168 independent reflections for which $I_0 >3{\sigma}(I_0)$.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3506-3511
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• 2007

The energy harvesting using smart materials has been extensively investigated to supply electric power to wireless sensor systems. In this paper, the energy harvesting using eddy current was studied with the integrated magnetic cantilever beam system. If a large conductive metal plate moves through a magnetic field which intersects perpendicularly to the sheet, the magnetic field will induce small rings of current which will actually create internal magnetic fields opposing the change. This eddy current that was induced in the coiled conductive sheet from the mechanical vibration was converted to chemical energy by charging batteries. The experimental results show that the eddy current generated the electric power up to max 31.2mW. Additionally the vibration reduction of the mechanical cantilever beam was observed by the energy dissipation in the electro-magnetic coupled system. The present result shows that the vibration level of the first natural frequency was reduced up to 7.7dB

• Journal of the Korean Mathematical Society
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• v.54 no.3
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• pp.847-865
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• 2017

For a finite or an infinite set X, let $2^X$ be the power set of X. A class of simple graph, called strong Boolean graph, is defined on the vertex set $2^X{\setminus}\{X,{\emptyset}\}$, with M adjacent to N if $M{\cap}N={\emptyset}$. In this paper, we characterize the annihilating-ideal graphs $\mathbb{AG}(R)$ that are blow-ups of strong Boolean graphs, complemented graphs and preatomic graphs respectively. In particular, for a commutative ring R such that AG(R) has a maximum clique S with $3{\leq}{\mid}V(S){\mid}{\leq}{\infty}$, we prove that $\mathbb{AG}(R)$ is a blow-up of a strong Boolean graph if and only if it is a complemented graph, if and only if R is a reduced ring. If assume further that R is decomposable, then we prove that $\mathbb{AG}(R)$ is a blow-up of a strong Boolean graph if and only if it is a blow-up of a pre-atomic graph. We also study the clique number and chromatic number of the graph $\mathbb{AG}(R)$.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.829-834
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• 2004

This research is to development advanced health(condition) monitoring system of superconducting motors. Development of advanced condition monitoring systems offers the prospect of improved performance, assessment, and operation, simplified design, enhanced safety, and reduced overall cost of advanced and next generation superconducting motor. For advanced and next generation superconducting motor design, the opportunity exists to develop and implement real-time and continuous monitoring systems by integrating wireless and computational technique. Generally, condition monitoring and control of temperature is essential for managing the superconducting motor components, rotor and structures. In this research, development of advanced monitoring in low temperature and high speed operating environments offers the potential to greatly improve the control of harsh environments. In conventional method, slip rings have been used to acquire data from these sensors. However, the increase of sensors leads to vibration of the rotation axis and noise signals due to kinematics contact. In this study, the wireless data acquisition technique was employed to develop more stable monitoring system adequate for high speed rotating system.

• Journal of Physiology & Pathology in Korean Medicine
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• v.18 no.5
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• pp.1382-1386
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• 2004

This study was performed for the investigation of vasodilatory efficacy and its underlying mechanisms of Samhwangsasim-tang(SST), herbal remedy. SST relaxed vascular strips precontracted with phenylephrine or KCI(51 mM), but the magnitude of relaxation was greater in phenylephrine(PE) induced contraction. The relaxation effects of SST was endothelium-independent. L-NAME, iNOS inhibitor, and methyl en blue(MB), cGMP inhibitor, did not attenuate the relaxation responses of SST. In the absence of extracellular Ca2+, pre-incubation of the aortic rings with SST significantly reduced the contraction by PE, suggesting that the relaxant action of the SST includes inhibition of Ca/sup 2+/ influx and release of Ca/sup 2+/ from intracellular stores (SR). In addition, the cell death was induced by SST in human aortic smooth muscle cells but not that of human umbilical vein endothelial cells. We conclude that in rat thoracic aorta, SST may induce in part vasodilation through inhibition of Ca/sup 2+/ influx and release of Ca/sup 2+/ from intracellular stores.