• Journal of Environmental Health Sciences
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• v.21 no.4
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• pp.10-16
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• 1995

Dyes are released into the environment from industrial wasterwater. They are considered to be a pollution problem because of the wide spread into environment with a variety of colors. In order to biological treatment of industrial dyes waste water, biodegradation of reactive dyes such as Rifacion Red H-3EB, Rifazol Blue BT, Rifacion Yellow P-4G and Rifacion Brown RT were carried out decolorized by Aspergillus sojae B-10. Aspergillus sojae B-10 showed the almost completely biodegradation ability when it was cultivated in a 2.0% glucose, 0.06% sodium nitrite, 0.1% $KH_2PO_4$, 0.5% $MgSO_4\cdot 7H_2O$ containing each reactive dyes (500 ppm) under the optimal conditions of 32$\circ$C and pH 5. The mycelium of Aspergillus sojae B-10 was produced extracellular enzyme which has concerned responsible for dyes biodegradation. Under optimal conditions, reactive dyes started being decolorized within 24 hr and its was almost decolorized c ompletely after 5 days incubation. Rifazol blue RT was not completely decolorized until 5 days of cultivation. Rafacion Red BT, Rifasol blue BT and Rifacion yellow P-4G were completely decolorized after 5 days cultivation.

• 한국생물공학회:학술대회논문집
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• 2003.10a
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• pp.398-401
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• 2003

Azo dyes are aromatic compounds characterized by one or more azo bonds $(R_l-N=N-R_2)$. More than 800,000 tons of dyes are produced annually worldwide, of which 60-70% are azo dyes. During manufacturing, an estimated 10-15% is released into the environment. Aside from their negative aesthetic effects, certain azo dyes have been shown to be toxic and, in some cases, these compounds are carcinogenic and mutagenic. To establish biological wastewater treatment of azo dye, it is essential to discover azo dye-degrading microorganisms. In this report, sludge-contaminated with dyes were gathered through wastewater outlets from the industrial regions. The following to separation of bacteria within them, bacteria which decolorize methyl red, a azo dye, were selected and destined.

• Textile Coloration and Finishing
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• v.6 no.3
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• pp.60-66
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• 1994

With the view of studying on the dual adsorption mechanism of acid dyes in connection with the structural difference of silk fibroin, silk fiber and silk fibroin memberane were used for equilibrium dyeing at $60^{\circ}C$, $70^{\circ}C$, $80^{\circ}C$ and pH 3.2, pH 5.0. The dyes used were C.I.Acid Orange 7 and C.I.Acid Red 88 introduced aromatic hydrocabon into Acid Orange 7. From the adsorption isotherm experiment, the total uptake of dyes can be described by Langmuir sorption and Nernst partition. Nernst partition. Nernst partition coefficient $K_1$ decrease of crystalline regions and orientation. The saturation value S of Acid Red 88 were large than total amino group contents and it was attributed it hydrophobic bond. On the other hand, the standard afficity and enthalpy were increased with the in crease of hydrophobic part of dyes. Both $k_1$ and $K_2$ were decreased with the increase of pH, but $k_2$ were more effected than $K_1$.

• Textile Coloration and Finishing
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• v.9 no.3
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• pp.42-49
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• 1997

In order to study the dyeability of reactive dyes fixable at neutral pH, three reactive dyes(DYE-NC, DYE-PC, and DYE-LC) were prepared by the reaction of Cibacron Brilliant Red 3B-A with nicotinic acid, pyridine, and lutidine, respectively. FT-IR and UV/Vis spectrophometry were used to identify the dyes prepared. While the maximum absorption wavelength (&{\lambda}_{max}&) of Cibacron Brilliant Red 3B-A was 515nm, the &{\lambda}_{max}& of DYE-NC, DYE-PC, and DYE-LC were 522nm, 525nm, and 536nm, respectively. The &{\lambda}_{max}& was shifted to the longer wavelength by introducing the electron donating groups to the pyridine ring of Cibacron Brilliant Red 3B-A. All of the reactive dyes synthesized showed good exhaustion and fixation property to cotton fabric at higher temperature and neutral pH condition. It was regarded that the quaternary pyridinium ion functionated as the leaving group instead of the chloride ion. Among them, DYE-NC showed the best dyeability at the above condition. It was considered that the electron withdrawing carboxylic acid group in nicotinic acid enhanced the cationic property of nitrogn in pyridine ring, resulting the good reactivity with OH group in cellulose.

• YAKHAK HOEJI
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• v.31 no.6
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• pp.361-369
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• 1987

The four azo dyes such as Amaranth (FD & C Red No. 2), Tartrazine (FD & C Yellow No. 4), sunset Yellow (FD & C Yellow No. 5) and Allura red (FD & C Red No. 40) are currently employed as a food additives in Korea. In this study, the effects of these azo dyes on the hepatic microsomal mixed function oxidase systems in Rats. (i.e., Cyt. P-450, Cyt. b$_5$, NADPH cyt. c-reductase and azo reductase) were investigated. Furthermore, to determine the relationship among the electron transport systems, each level of azo reductase, Cyt. P-450 and NADPH cyt. c-reductase was measured upon the administration of phenobarbital (known as an inducer of Cyt. P-450), 3-methylcholanthrene (Known as an inducer of Cyt. P-448), CoCl$_2$ (inhibitor on Cyt. P-450) or $CCl_4$ (inhibitor on Cyt. P-450). The results of these studies are as follows; (1) The levels of Cyt. P-450 and Cyt. b$_5$ were decreased upon the administration of these azo dyes. (2) When the level of Cyt. P-450 was decreased, the azo reductase activity was also decreased. (3) These azo dyes did not show any significant effect on the level of NADPH cyt. c-reductase. (4) The administration of 3-methylcholanthrene resulted in the elevation of azo reductase activity. The 3-methylcholanthrene may be responsible for the induction of CO-insensitive electron transport system.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.44 no.3
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• pp.303-316
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• 2018

In this study, I investigated the applicability of fluorescein-derived xanthene dyes to fluorescent pigment and the controllability of the optical properties of manufactured pigments. Eosin Y (D&C Red No.22) and phloxine B (D&C Red No.28) were mainly used as a dye to prepare the pigment. Dyes dissolved in a solvent were poured into a powder dispersed in the solvent, then dried and pulverized to fabricate the pigments. Optical characteristics related with fluorescence of the prepared pigment were measured. The optical properties of pigments were varied depending on the solvent used, content of the dye in the pigment, and the ratio of dyes when more then two dyes were mixed. According to the experiment result, it seems that some of the dyes attached to the powder showed fluorescence while the rest did not contribute to it. From the result of pigment washing experiment to explore the binding (or interaction) strength and characteristics of the powder-dye system constituting the pigment, it seems that there are two or more different interactions existing in the pigment system, one of which is relatively stronger than the solvent-dye interaction.

• KSBB Journal
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• v.8 no.2
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• pp.150-155
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• 1993

This study describes biodegradation of dyes which are used in textile industries. Dyes released into the environment from industrial waste water are considered to be a serious pollution problem because of the wide spread into environment with a variety of colors. The microorganisms used in this experiment were Pseudomonas species, which had been screened from aeration tank of waste water treatment. It was found that optimum concentrations for culture media were 14g of glucose, 6g of peptone, 160 mg of Na2HPO4, 200mg of KCl, 140mg of MgSO4,.7H2O,1.0g of KH2PO4, 400mg of NaCl, 200mg of CaCl2 and dye 10ppm per litre of distilled water. The high efficiency of dye degradation was obtained at pH 7-8 and $30-35^{\circ}C$. Strains screened are excellent for removal of azo and reactive dyes, which are relatively stable and difficult to degrade. Dyes of 10ppm such as mono-azo (Lot No. 180), di-azo (Lot No. 138) and reactive red(Lot No. 2) were mostly decolorlzed within 2 days and di-azo (Lot No. 151) and reactive red(Lot No. 34, No. 00166) were decolorized within 5 days in the controlled fermenter. In the case of reactive dyes, oxygen supplies showed lower biodegradability compared to anaerobic culture.

• Textile Coloration and Finishing
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• v.6 no.3
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• pp.67-73
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• 1994

The adsorption behaviors of acid dye and disperse dye on silk and nylon fabrics were examined, in one bath dyeing system on silk/nylon blend fabric with disperse dyes and acid dyes. In the dyeing of nylon fabric with C. I. Disperse Red 19 (Red 19) and C. I. Disperse Red 60 (Red 60), dye uptake of Red 19 was higher than that of Red 60. When silk/nylon blend fabric was dyed with Red 19 and Red 0, the dye uptake on nylon was influenced by the ffinity of the dye to the silk fabric. In the dyeing of silk/nylon with C. I. Acid Blue 80 and C. I. Acid Yellow 121, solid shade could not be obtained with the conventional method but could be obtained with the dyeing resist agent for nylon. There was not any relationship between K/S value and Munsell value, but Munsell value tended to change with the K/S value.

• Biotechnology and Bioprocess Engineering:BBE
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• v.9 no.4
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• pp.309-312
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• 2004

Aspergillus sojae B-l0 was immobilized and used to treat model dye compounds. The model wastewater, containing 10 ppm of azo dyes such as Amaranth, Sudan III, and Congo Red, was treated with cells attached to a rotating disc contactor (RDC). Amaranth was decolorized more easily than were Sudan III and Congo Red. Decolorization of Amaranth began within a day, and the dye was completely decolorized within 5 days of incubation. Both Sudan III and Congo Red were almost completely decolorized after 5 days of incubation. Semicontinuous decolorization of azo by reusing attached mycelia resulted in almost complete decolorization in 20 days. This experiment indicated that decolorization was successfully conducted by removing azo dyes with Aspergillus sojae B-10.

• Membrane and Water Treatment
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• v.9 no.5
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• pp.301-307
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• 2018

In this research work, synthesis of sugarcane bagasse/zinc aluminium biocomposite and apple peel/zinc aluminium biocomposite and their application for removal of Reactive Red-241 and Acid Orange-7, respectively, was studied using various parameters. At pH 2 the sorption was the highest for both dyes. The trend showed that the dye sorption declined by decreasing the biocomposite dose and enhanced by increasing the dye concentration and temperature. Equilibrium was achieved at 60 minutes for Reactive Red-241 onto sugarcane bagasse/zinc aluminium biocomposite and 90 minutes for Acid Orange-7 onto apple peel/zinc aluminium biocomposite.The research data was good fitted to pseudo-2nd-order kinetic model and Langmuir isotherm. FT-IR analysis was used to confirm the biosorption of the selected dyes at the surface of biosorbent through various binding sites. Surface morphology modification of both biocomposites before and after biosorption was inspected through SEM. Crystallinity of biocomposite was examined through XRD analysis. It was implied that sugarcane bagasse/ zinc aluminium biocomposite and apple peel/ zinc aluminium biocomposite are good adsorbents for dyes elimination from aqueous solutions.