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Synthesis and characterization of sugarcane bagasse/zinc aluminium and apple peel/zinc aluminium biocomposites: Application for removal of reactive and acid dyes

  • Safa, Yusra (Department of Chemistry, Lahore College for Women University) ;
  • Tariq, Saadia Rashid (Department of Chemistry, Lahore College for Women University) ;
  • Bhatti, Haq Nawaz (Department of Chemistry, University of Agriculture) ;
  • Sultan, Misbah (Institute of Chemistry, University of the Punjab) ;
  • Bibi, Ismat (Department of Chemistry, The Islamia University of Bahawalpur) ;
  • Nouren, Shazia (Department of Chemistry, Government College for Women)
  • Received : 2016.12.29
  • Accepted : 2018.01.24
  • Published : 2018.09.25
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Abstract

In this research work, synthesis of sugarcane bagasse/zinc aluminium biocomposite and apple peel/zinc aluminium biocomposite and their application for removal of Reactive Red-241 and Acid Orange-7, respectively, was studied using various parameters. At pH 2 the sorption was the highest for both dyes. The trend showed that the dye sorption declined by decreasing the biocomposite dose and enhanced by increasing the dye concentration and temperature. Equilibrium was achieved at 60 minutes for Reactive Red-241 onto sugarcane bagasse/zinc aluminium biocomposite and 90 minutes for Acid Orange-7 onto apple peel/zinc aluminium biocomposite.The research data was good fitted to pseudo-2nd-order kinetic model and Langmuir isotherm. FT-IR analysis was used to confirm the biosorption of the selected dyes at the surface of biosorbent through various binding sites. Surface morphology modification of both biocomposites before and after biosorption was inspected through SEM. Crystallinity of biocomposite was examined through XRD analysis. It was implied that sugarcane bagasse/ zinc aluminium biocomposite and apple peel/ zinc aluminium biocomposite are good adsorbents for dyes elimination from aqueous solutions.

Keywords

References

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