• Journal of the Korean Institute of Gas
• /
• v.8 no.3 s.24
• /
• pp.16-23
• /
• 2004

A membrane reactor concept, which combines the typical characteristics of chemical reaction with separation process, has been analyzed and simulated in this study. The advantages of the use of a membrane reactor include chemical equilibrium shift towards higher reactant conversion and purer product than the traditional reactors. A membrane reactor model which incorporates a catalytic reaction zone and a separation membrane is proposed. The water-gas shift reaction to produce hydrogen was chosen as a model reaction to be investigated. The membrane reactor is divided into smaller parts by number of n and each part (named cell), which contains both reaction and product separation function is modeled. One of the membrane outlet streams is connected to the next cell, which is repeated up to the last cell. The simulation results can be used for various purposes including decision of optimum operating condition and membrane reactor design.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.16 no.3
• /
• pp.247-252
• /
• 2003

In this paper, we made four types of metal particle $Al_2$O$_3$ barrier reactors with and without dielectric of BaTiO$_3$ between metal particle and $Al_2$O$_3$ barrier to investigate NOx removal characteristic and the effect of dielectric on Nox removal. And Nox removal rate is measured when sludge pellets are put at down stream of plasma reactor. Nox removal rate in the reactor with $Al_2$O$_3$ barrier is much better than that in the reactor without $Al_2$O$_3$ barrier, Nox removal rate is not so good in metal particle-Al$_2$O$_3$ barrier reactor with BaTiO$_3$ between metal particle and $Al_2$O$_3$ barrier, however, Nox removal rate is about 40% in metal particle-Al$_2$O$_3$ barrier reactor with TiO$_2$. The most of NO is conversed to NO$_2$ in these kind of reactor. When sludge pellets are put at down stream of plasma reactor, Nox removal rate is greatly improved up to 90%. It indicates that sludge pellets have great effect on the NO$_2$ removal and the improvement of Nox removal rate, however, dielectric materials between metal particle and $Al_2$O$_3$ barrier have not effect. Organic materials included in sludge may react with NO$_2$ and ozone so that Nox removal rate is greatly improved.

• Korean Chemical Engineering Research
• /
• v.45 no.6
• /
• pp.582-590
• /
• 2007

In view of the analysis of the phenomena and the prediction of the performance, mathematical modelling and simulation of a high temperature pilot reactor for water gas shift reaction (WGSR) has been carried out. Multiscale simulation incorporated computational fluid dynamics (CFD) technique, which has the capability to deal with the reactor shape, fluid and energy transport with extensive degree of accuracy, and process modeling technique, which, in turn is responsible for reaction kinetics and mass transport. This research employed multiscale simulation and the results were compared with those from process simulation. From multiscale simulation, the maximum conversion of was predicted approximately 0.85 and the maximum temperature at the reactor was calculated 720 K, resulting from the heat of reaction. Dynamic simulation was also performed for the time transient profile of temperature, conversion, etc. Considering the results, it is concluded that multiscale simulation is a safe and accurate technique to predict reactor behaviors, and consequently will be available for the design of commercial size chemical reactors as well as other commercial unit operations.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.35 no.10
• /
• pp.989-996
• /
• 2011

An understanding of the concentrated solar flux is critical for the analysis and design of solar-energy-utilization systems. The current work focuses on the development of an algorithm that uses the Monte Carlo ray-tracing method with excellent flexibility and expandability; this method considers both solar limb darkening and the surface slope error of reflectors, thereby analyzing the solar flux. A comparison of the modeling results with measurements at the solar furnace in Korea Institute of Energy Research (KIER) show good agreement within a measurement uncertainty of 10%. The model evaluates the concentration performance of the KIER solar furnace with a tracking accuracy of 2 mrad and a maximum attainable concentration ratio of 4400 sun. Flux variations according to measurement position and flux distributions depending on acceptance angles provide detailed information for the design of chemical reactors or secondary concentrators.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.34 no.12
• /
• pp.1093-1099
• /
• 2010

For Very High Temperature Reactors (VHTR), the designs of the Intermediate Heat Transport Loop (IHTL) and the Intermediate Heat Exchanger (IHX) are particularly difficult because of the high-temperature operation (up to $950^{\circ}C$). In this study, Flinak molten salt, a eutectic mixture of LiF, NaF, and KF (46.5:11.5:42.0 mole %) is considered as the heat transporting fluid in the IHTL. To evaluate the flow and heat transfer performance of the Flinak molten salt in small channels with hydraulic diameters in the millimeter range, a double-pipe heat exchanger was constructed using small-diameter tubes for the heat exchange between the Flinak and the gas flow. The experimental data showed that, for laminar Flinak flow, the measured friction factors were close to the 64/Re curve and the Nusselt numbers were generally between 3.66 and 4.36.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
• /
• 2005.05a
• /
• pp.216-227
• /
• 2005

The head penetrations for control rod drive mechanism and instrumentation systems are installed at the reactor pressure vessel head of PWRs. Primary coolant water and the operating conditions of PWR plants can cause cracking of these nickel-based alloy through a process called primary water stress corrosion cracking (PWSCC). Inspection of the head penetrations to ensure the integrity of the head penetrations has been interested since reactor coolant leakages were found at U. S. reactors in 2000 and 2001. The complex geometry of the head penetrations and the very low echo amplitude from the fine, multiple flaws due to the nature of the see made it difficult to detect and size the flaws using conventional pulse-echo UT methods. Time-of-flight-diffraction technique, which utilizes the time difference between the flaw tips while pulse-echo does the flaw response amplitude from the flaw, has been selected for this inspection for it's best performance of the detection and sizing of the head penetration see flaws. This study defines the limits of the detectable and accurately sizable minimum flaw size which can be detected by the General TOFD and the Delta TOFD techniques for circumferentially and axially oriented flaws respectively. These results assures the reliability of the inspection techniques to detect and accurately size for various kind of flaws, and will also be utilized for the future development and qualifications of the TOFD techniques to enhance the detecting sensitivity and sizing accuracy of the flaws of the reactor head penetrations in nuclear power plants.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.6 no.1
• /
• pp.1-11
• /
• 2002

The suitable turbulence model is found to be required in the course of establishing a proper analysis methodology for thermal stripping phenomena which are shown in strong temperature variation area such as reactors and propulsion devices. Three different turbulence models of $\kappa$-$\varepsilon$ model, modified $\kappa$-$\varepsilon$ model, and full Reynolds stress(FRS) model, are applied to analyze unsteady turbulent flows with temperature variation. Three test cases are selected for verification. These are vertical jet flows with water and sodium, and parallel jet flow with sodium. Analysis yields the conclusion that 3-D computation with FRS betters others. However, modified modeling is required to improve its heat transfer characteristic analysis. Further analysis is performed to find momentum variation effects on temperature distribution. It is found that the momentum increase results increase of fluid mixing and magnitude of temperature variation.

• Corrosion Science and Technology
• /
• v.3 no.5
• /
• pp.198-208
• /
• 2004

Although there has been no general agreement on the mechanism of primary water stress corrosion cracking (PWSCC) as one of major degradation modes of Ni-base alloys in pressurized water reactors (PWR's), common postulation derived from previous studies is that the damage to the alloy substrate can be related to mass transport characteristics and/or repair properties of overlaid oxide film. Recently, it was shown that the oxide film structure and PWSCC initiation time as well as crack growth rate were systematically varied as a function of dissolved hydrogen concentration in high temperature water, supporting the postulation. In order to understand how the oxide film composition can vary with water chemistry, this study was conducted to characterize oxide films on Alloy 600 by an in-situ Raman spectroscopy. Based on both experimental and thermodynamic prediction results, Ni/NiO thermodynamic equilibrium condition was defined as a function of electrochemical potential and temperature. The results agree well with Attanasio et al.'s data by contact electrical resistance measurements. The anomalously high PWSCC growth rate consistently observed in the vicinity of Ni/NiO equilibrium is then attributed to weak thermodynamic stability of NiO. Redox-induced phase transition between Ni metal and NiO may undermine the integrity of NiO and enhance presumably the percolation of oxidizing environment through the oxide film, especially along grain boundaries. The redox-induced grain boundary oxide degradation mechanism has been postulated and will be tested by using the in-situ Raman facility.

• Particle and aerosol research
• /
• v.10 no.4
• /
• pp.137-154
• /
• 2014

Prediction of the behavior of radioactive aerosol particles in a containment is of importance for the assessment of the consequences of nuclear power plant severe accidents because most radioactive air pollutants are emitted as aerosol particles upon severe accident. The performance of engineering safety features (ESFs) is also influenced by the characteristics of the aerosol particles. In this article, the characteristics of aerosol particles in reactor containments reported by previous studies were reviewed. The results of the experiments for postulated accidents in test reactors, for aerosol behavior analysis using artificial test aerosols, and for ESF performance evaluation were summarized. The summary of this article will be of use in designing and performance-evaluating ESFs.

• Journal of Aquaculture
• /
• v.13 no.2
• /
• pp.137-145
• /
• 2000

Capacity of water treatment of the three phase fluidized bed reactor as a biofilter in the seawater recirculating system was evaluated. The water treatment system consists of fluidized bed reactor for ammonia removal, cartridge filter for solid removal and ozone contactor for disinfection. Mean concentration of water quality parameters: COD, TAN, $NO_2$-N, $NO_3$-N, SS and alkalinity were 9.0, 0.22, 0.05, 20.0, 9.5 and 70.0 mg/l, respectively; the relevant values were 7.6 for pH and 3.64 NTU for turbidity. These indicate the maintenance of good water quality by the treatment system. The influent TAN loading rate in to the fluidized bed reactor ranged from 4.3 to 32.9 g/$m^3$/day, and averaged to 20 g/$m^3$/day. TAN removal efficiency of each phase of the fluidized bed reactor was 47-60%, indicating the effective ammonia removal. During operation the effluent of fluidized bed reactors also maintained the unionized ammonia nitrogen level below 0.002 mg/l.