• Title/Summary/Keyword: reaction factors

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Service Life Prediction of Components or Materials Based on Accelerated Degradation Tests (가속열화시험에 의한 부품·소재 사용수명 예측에 관한 연구)

  • Kwon, Young Il
    • Journal of Applied Reliability
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    • v.17 no.2
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    • pp.103-111
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    • 2017
  • Purpose: Accelerated degradation tests can speed time to market and reduce the test time and costs associated with long term reliability tests to verify the required service life of a product or material. This paper proposes a service life prediction method for components or materials using an accelerated degradation tests based on the relationships between temperature and the rate of failure-causing chemical reaction. Methods: The relationship between performance degradation and the rate of a failure-causing chemical reaction is assumed and least square estimation is used to estimate model parameters from the degradation model. Results: Methods of obtaining acceleration factors and predicting service life using the degradation model are presented and a numerical example is provided. Conclusion: Service life prediction of a component or material is possible at an early stage of the degradation test by using the proposed method.

액상계면반응에 의한 실라카 중공 다공성 미소구의 제조 및 표면개질에 의한 특성

  • 정원범;고종성
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.13 no.1
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    • pp.15-28
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    • 1987
  • Silica spheres were prepared by interfacial reaction method. Factors in-fluencing to the mean particle size and specific surface area of silica spheres were investigated. The experiment about the surface modification of silica spheres was carried out. It was observed that silica spheres have characteristics of the spherical shape with the vacancy in the inner side, high surface area, and reaction tendency by many silanol group. The mean particle size of silica spheres is dependent on the surfactant concentration and W/O ratio. The specific surface area is influenced by SiO2/Na2O mole ratio in sodium silicate. Silica spheres coated with titanium dioxide or zirconium dioxide improve the UV protection effect. Titanate and silane coupling agent make chemical bond with silica surface and improve the organophile and the dispersibility of silica spheres.

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Studies on Protoplast Isolation and Regeneration of Lyophyllum ulmarium (느티만가닥 버섯의 원형질체 분리와 재생에 관한 연구)

  • 최혜진;김병각;현진원
    • Journal of Life Science
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    • v.13 no.2
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    • pp.143-149
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    • 2003
  • This experiment was undertaken to investigate proper conditions for protoplast isolation and regeneration from the mycelia of Lyophyllum ulmnrium. Protoplast isolation and regeneration are influenced by a variety of factors such as enzyme, osmotic stabilizer, reaction time and age of mycelia. A combination of Novozyme 234 (10mg/ml) and cellulase Onozuka R-10 (10 mg/ml) with 0.6 M $MgSO_4$ was most effective for isolation of the protoplasts. The optimum reaction time of the mycelia with the lytic enzymes was 3.5~4 hours at $28^{\circ}C$ in shaking condition at 120 strokes per min. High yield of the protoplasts were obtained from its 4~5 days old mycelia on complete agar media. Its protoplasts were regenerated to normal hyphae. Regeneration media with 0.6 M sucrose were proper for regeneration of the protoplasts. Their regeneration frequency on complete agar media was 2.3~2.7%.

Finite Element Analysis of Chloride Ion Intrusion into Coastal Concrete Structure

  • Kim, Eun-Kyum;Shin, Chee-Bur;Yeau, Kyong-Yun
    • KCI Concrete Journal
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    • v.11 no.3
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    • pp.175-180
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    • 1999
  • In order to predict the onset of the corrosion of steel bars in concrete, a mathematical model was presented to observe the diffusion of chloride ion in aqueous phase, the adsorption and desorption of chloride ions to and from the surface of solid phase of concrete, and the chemical reaction or chloride ions with solid phase. The finite element method was employed to carry out the numerical analysis. The chlorides enetrating through the wall of the concrete structure from the external environment and the chlorides contained in the concrete admixture were confirmed to be two important factors to determine the onset of the corrosion of steel bars.

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Adsorption Characteristics of Malachite Green Employing Waste Garnet as Adsorbent (폐석류석을 흡착제로 이용한 말라카이트그린 흡착 특성)

  • Baek, Mi-Hwa;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.216-221
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    • 2007
  • The adsorption characteristics of malachite green on waste garnet have been investigated for its treatment from aqueous solution by employing waste garnet which is generated from the abrasive production process as an adsorbent. The influential factors examined were the initial concentration of malachite green in solution, reaction temperature, and the amount of adsorbent. Also, the effect of the modification of the surface of adsorbent on adsorption was examined. As the initial malachite green was increased with reaction temperature and the color removal of malachite green-containing solution was promoted with the amount of adsorbent. Finaly, increased adsorption of malachite green could be attained when the surface of glass was modified by hexamethyldisilazane.

Studies on the Influence of Various Factors on 2, 3, 5-Triphenyl Tetrazolium Chloride Reduction Test(T.T.C. Test) (2, 3, 5-Triphenyl Tetrazolium Chloride 환원시험(還元試驗)(T. T. C. Test)에 미치는 요인(要因)에 관한 연구(硏究))

  • Kim, Kyo-Joon;Kim, Sang Keun
    • Korean Journal of Agricultural Science
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    • v.5 no.2
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    • pp.80-86
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    • 1978
  • This study was carried out in order to know the effect of T. T. C. reaction on antibiotics, cleanser, disinfectants, pH, acidity and station of culture a bacterial Streptococcus thermophilus was used to 2.3.5-triphenyl tetrazolium chloride reduction test for the detection of residual antibiotics in milk were tested. The results obtained were summarized as follows. 1. The T. T. C. reaction was most sensitive in the group of penicillin as 0.02~0.05 IU and also it was less sensitive in Streptomycin and various broad antibiotics except Vibramycin, Synthomycin and Teramycin but it was least sensitive in Streptomycin group. 2. For ther T. T. C. reaction test on cleanser, the positive reaction was appeared above 0.7% of Hi-Ti and 0.1% of NaOH solution respectively. 3. For the T. T. C. test reaction on disinfectants, the positive reaction was occured on 200~500 ppm solution of sodium-hypochlorite and chloride-lime, 0.15~0.35% solution of phenol, cresol and Iode-K. 4. The optimum temperature was $35{\sim}37^{\circ}C$ and proper culturing time was 12 to 18 hours for propagation culturing. 5. The suspect positive reaction was tested above pH 5.0 and the positive reaction was appeared above 0.21% of acidity.

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Optimization of 1(3)-Palmitoyl-2-Oleoyl-3(1)-Stearoyl Glycerol Produced via Lipase-catalyzed Esterification Using the Response Surface Methodology (Camellia Oil로부터 1(3)-Palmitoyl-2-Oleoyl-3(1)-Stearoyl Glycerol을 함유한 효소적 합성반응물의 최적화 연구)

  • Hwang, Yun-Ik;Shin, Jung-Ah;Lee, Jeung-Hee;Hong, Soon-Taek;Lee, Ki-Teak
    • Food Science and Preservation
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    • v.18 no.5
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    • pp.721-728
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    • 2011
  • 1(3)-palmitoyl-2-oleoyl-3(1)-stearoyl-(POS)-glycerol-enriched reaction products were synthesized from camellia oil, palmitic ethyl ester, and stearic ethyl ester via lipase-catalyzed interesterification. Response surface methodology (RSM) was employed to optimize the production of the POS-enriched reaction product (Y1, %) and the stearicand palmitic-acid contents at the sn-2 position due to acyl migration (Y2, %). The reaction factors were the enzyme amount (X1, 2-6%), reaction time (X2, 60-360 min), and substrate molar ratio of camellia oil to palmitic ethyl ester and stearic ethyl ester (X3, 1-3 mol). The predictive models for Y1 and Y2 were adequate and reproducible as no lack of fit was signified (0.128 and 0.237) and as there were satisfactory levels of R2 (0.968 and 0.990, respectively). The optimal conditions for the reaction product for maximizing Y1 while minimizing Y2 were predicted at the reaction combination of 5.86% enzyme amount, 60 min reaction time, and 1:3 substrate molar ratio (3 moles of palmitic ethyl ester and 3 moles of stearic ethyl ester). Actual reaction was performed under the same conditions as above, and the resulting product contained 20.19% TAG-P/O/S and 12.71% saturated fatty acids at the sn-2 position.

A Study on Optimization of 3D Auxetic Pyramid Structure (3D Auxetic Pyramid 구조의 최적화 연구)

  • Kim, Gyu-Young;Kim, Soo-ho;Yun, Gi-Won
    • Proceeding of EDISON Challenge
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    • 2017.03a
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    • pp.241-250
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    • 2017
  • Auxetic is a structure that behave as negative Poisson's ratio. It is known for high mechanical property like energy absorption and destruction toughness so far. In this paper, we aimed to design auxetic structure which has small internal energy when force is applied and high NPR and over 50N/mm stiffness by using optimization method. We defined length(L), thickness(t), angle(${\theta}_1$, ${\theta}_2$) as design factors and also von-Mises stress, NPR, stiffness as reaction factors. We used Box-Behnken method and conducted 4factors - 3levels experiment design. We also analyzed each models by using CSD_EPLAST, Edison program, and did extra analysis for more accurate results. Finally, we found out the optimal design factors which is satisfied aimed value and increased reliability through factor analysis and validity verification.

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Investigation of Thermal Behavior Characteristic in Chemical Mechanical Polishing Performance (CMP 결과에 영향을 미치는 열적거동 특성에 관한 연구)

  • Jeong, Young-Seok;Kim, Hyoung-Jae;Choi, Jae-Young;Kim, Goo-Youn;Jeong, Hae-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1283-1287
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    • 2004
  • The design rules are being more strict with requirement of operation speed and development of IC industry. For this reason, required minimum line-width has been narrowed under sub-micron region. As the length of minimum line-width is narrowed, local and global planarization are being prominent. CMP(Chemical-Mechanical Polishing), one of the planarizarion technology, is a process which polishes with the ascent of chemical reaction and relative velocity between pad and wafer without surface defects. CMP is performed with a complex interaction among many factors, how CMP has an interaction with such factors is not evident. Accordingly, the studies on this are still carrying out. Therefore, an examination of the CMP phenomena and an accurate understanding of compositive factors are urgently needed. In this paper, we will consider of the relations between the effects of temperature which influences many factors having an effect on polishing results and the characteristics of CMP in order to understand and estimate the influence of temperature. Then, through the interaction of shown temperature and polishing result, we could expect to boost fundamental understanding on complex CMP phenomena.

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The Effects of Age, Gender, and Situational Factors on Take-Over Performance in Automated Driving (연령, 성별 및 상황적 요인이 자율주행 제어권 전환 수행도에 미치는 영향)

  • Myoungouk, Park;Joonwoo, Son
    • Journal of Auto-vehicle Safety Association
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    • v.14 no.4
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    • pp.70-76
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    • 2022
  • This paper investigates the effects of age, gender, and situational factors on take-over performance in automated driving. The existing automated driving systems still consider a driver as a fallback-ready user who is receptive to take-over requests. Thus, we need to understand the impact of situations and human factors on take-over performance. 34 drivers drove on a simulated track, consisting of one baseline and four event scenarios. The data, including the brake reaction time and the standard deviation of lane position, and physiological data, including the heart rate and skin conductance, were collected. The analysis was performed using repeated-measures ANOVA. The results showed that there were significant age, gender, and situational differences in the takeover performance and mental workload. Findings from this study indicated that older drivers may face risks due to their degraded driving performance, and female drivers may have a negative experience on automated driving.