• Title/Summary/Keyword: reaction factors

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Electrochemical Effectiveness Factors for Butler-Volmer Reaction Kinetics in Active Electrode Layers of Solid Oxide Fuel Cells

  • Nam, Jin Hyun
    • Journal of Electrochemical Science and Technology
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    • v.8 no.4
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    • pp.344-355
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    • 2017
  • In this study, a numerical approach is adopted to investigate the effectiveness factors for distributed electrochemical reactions in thin active reaction layers of solid oxide fuel cells (SOFCs), taking into account the Butler-Volmer reaction kinetics. The mathematical equations for the electrochemical reaction and charge conduction process were formulated by assuming that the active reaction layer has a small thickness, homogeneous microstructure, and high effective electronic conductivity. The effectiveness factor is defined as the ratio of the actual reaction rate (or equivalently, current generation rate) in the active reaction layer to the nominal reaction rate. From extensive numerical calculations, the effectiveness factors were obtained for various charge transfer coefficients of 0.3-0.8. These effectiveness data were then fitted to simple correlation equations, and the resulting correlation coefficients are presented along with estimated magnitude of error.

A Study on the Reaction towards Damage Related to Health Foods among the Elderly (노인들의 건강식품 관련 문제 경험에 대한 대응 행동에 관한 연구)

  • Kim, Hyo-Chung;Kim, Mee-Ra
    • Journal of the East Asian Society of Dietary Life
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    • v.18 no.4
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    • pp.608-617
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    • 2008
  • This study examined the level of reaction towards damage related to health foods and the factors affecting this reaction among the elderly. Data were collected from 269 elderly individuals living in Seoul, Daejeon, Daegu, Gwangju and Busan. Frequencies, chi-square tests, and a multinomial logistic regression analysis were performed using the SPSS v. 14.0 program. When asked about their reaction towards damage related to health foods, approximately 48% of the respondents answered 'no response', 34% answered 'private response', and 18% answered 'public response'. Multinomial logistic regression analysis revealed that education level and awareness of health food price were significant factors influencing 'private response', and concerns about health foods and awareness of damage redemption were significant factors for 'public response'. These results imply that consumer education for elderly to prevent damage derived from the purchase and consumption of health foods is required.

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Uncertainty Quantification of the Experimental Spectroscopic Factor from Transfer Reaction Models

  • Song, Young-Ho;Kim, Youngman
    • Journal of the Korean Physical Society
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    • v.73 no.9
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    • pp.1247-1254
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    • 2018
  • We study the uncertainty stemming from different theoretical models in the spectroscopic factors extracted from experiments. We use three theoretical approaches, the distorted wave Born approximation (DWBA), the adiabatic distorted wave approximation (ADWA) and the continuum discretized coupled-channels method (CDCC), and analyze the $^{12}C(d,p)^{13}C$, $^{14}C(d,p)^{15}C$ reactions. We find that the uncertainty associated with the adopted theoretical models is less than 20%. We also investigate the contribution from the remnant term and observe that it gives less than 10% uncertainty. We finally make an attempt to explain the discrepancy in the spectroscopic factors of $^{17}C(\frac{3}{2}^+)$ between the ones extracted from experiments and from shell model calculations by analyzing the $^{16}C(d,p)^{17}C$ reaction.

Effect of Target Height on Ground reaction force factors during Taekwondo and Hapkido Dollyuchagi Motion (태권도와 합기도의 돌려차기시 타격 높이가 지면반력에 미치는 영향)

  • Yang, Chang-Soo
    • Korean Journal of Applied Biomechanics
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    • v.12 no.1
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    • pp.193-204
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    • 2002
  • The purpose of this study was to investigate the effect of martial art type and target height on the ground reaction force factors during Dollyuchagi motion. Data were collected using force plate. Five Taekwondo players and five Hapkido players were tested during Dollyuchagi motion to three different target heights(0.8, 1.2, 1.6 m). After analysis of kinetics using force plate data, maximum vertical ground reaction force was 1.62~2.44 BW, and impulse was $0.66\sim1.01 BW{\cdot}s$. Even though there was no difference for maximum ground reaction forces and impulse between Hapkido and Taekwondo, as target height was higher, impulse increased. Anterior-posterior and vertical ground reaction forces at kicking foot take-off were greater with target height, although there was no difference for medio-lateral force with target height. At impact there was significant difference for anterior-posterior ground reaction force between Hapkido and Taekwondo players. Taekwondo players' force (range, -0.23~-0.26 BW) was greater than Hapkido players's force (range, -0.08~-0.14 BW).

A Study of Child Emotion Regulation by the Cluster of Mother's Reaction to Children's Negative Emotion (아동의 부정적 정서표현에 대한 어머니 반응 유형의 군집에 따른 아동의 정서조절 능력 차이 검증)

  • Kim, Jiyoun;Oh, Ji-Hyun
    • Korean Journal of Childcare and Education
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    • v.13 no.3
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    • pp.39-54
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    • 2017
  • Objective: The purpose of this study was to examine natural groupings of the sub-factors of mother's reaction to children's negative emotions. The natural groupings were as follows; the emotion-coaching-reaction, the emotion-minimizing-reaction and oversensitive reaction. In addition, this paper also investigated individual differences in children's emotion regulation by clusters of sub-factors of mother's reaction to children's negative emotions. Methods: The subjects of this study consisted of 318 children. The data were analyzed using cluster analysis and one-way ANOVA. Results: The results suggested four proper clusters, according to the characteristics of mother's reaction to children's negative emotions. Cluster 1 was categorized as 'child centered-emotion coaching', cluster 2 was categorized as 'oversensitive-emotion coaching comorbid', cluster 3 was categorized as 'acception-emotion minimizing confused' and cluster 4 was categorized as 'emotion minimizing-unsupporting.' Additionally, the differences between Emotion regulations in each cluster showed distinct points of interest. In terms of the maladaptive emotion regulation, cluster 3 showed the highest level followed by cluster 4. And cluster 1 and 2 showed the lowest level. Conclusion/Implications: The results of this study helped to find a deeper understanding of the operation of specific clusters of mother's reaction to children's negative emotion and children's emotion regulation.

Analysis of Biomechanical Differences based on Distance Changes in Connection with Approach Swings of Tour-professional Golfers

  • You, Moon-Seok;Lee, Kyung-Ill
    • Korean Journal of Applied Biomechanics
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    • v.26 no.1
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    • pp.83-92
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    • 2016
  • Objective: This study aimed to compare differences in biomechanical factors according to distance changes in relation to approaches during a round of golf to obtain basic data on golf swings. Methods: The research subjects were 8 KPGA-affiliated professional golfers who performed approach shots that put a ball into a circle of 8 feet in diameter from distances of 30, 50, and 70 m. Data were collected by using six infrared cameras and a ground reaction force device, which were applied to calculate biomechanical factors by using Kwon3D XP. The calculated data were subjected to one-way ANOVA by using SPSS 20.0, with the significance level set at p value of 0.05. Results: Elapsed time, stance width, clubhead position variation, clubhead synthesis speed, and cocking angle significantly differed according to distance change during the approach swing. Clubhead speed was positively related with stance width and clubhead displacement. Ground reaction force significantly differed according to distance change during the approach swing. Factors before and after showed differences in other states, except in the impact state. Conclusion: In the present study, we drew several conclusions regarding biomechanical factors and ground reaction forces according to distance change in the approach swing of professional golfers. According to these conclusions, we suggest that distance control with swing range is more important than power control in maintaining the accuracy and consistency of golf swing and is the most important mechanism of golf swing.

Study on Electrochemical Properties of TBT(Tributyltin)

  • Park, Chil-Nam;Yang, Hyo-Kyung
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_4
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    • pp.173-179
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    • 2001
  • The chemical behavior and properties of the redox state of environmental pollutants was investigated using electrochemical methods. The purpose was to measure the variations in the redox reaction of differential pulse polarograms and cyclic voltammograms. The results observed the influences on redox potential and current of various factors including concentration, temperature, salt, and pH. These were established factors as the effect of the redox reaction. It can be clearly recognized that the electrode reaction are from reversible to irreversible processes. Also, it was mixing with reaction current controlled.

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Chemical Properties of Co(II) Compound Containing Endocrine Disrupter, Bis-Phenol A

  • Park, Chil-Nam
    • Journal of Environmental Science International
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    • v.11 no.2
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    • pp.131-137
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    • 2002
  • The chemical behavior and properties on the redox state of environmental pollutant has been investigated by electrochemical methods. We carried out to measure the variations in the redox reaction of differential pulse polarogram and cyclic voltammogram. The results observed the influences on redox potential and current of various factors with temperature and pH. These were established factors as the effect of the redox reaction. It can be clearly recognized that the electrode reaction are from qusi-reversible to irreversible processes. Also, it was mixing with reaction current controlled. The bits-phenol A in the waste water was made to compound with cobalt ion and it take away from the separation into compound. The $Co(BPA)_2$ compound was not found to be dissociation in waste water. However, this compound is avery unstable(K=1.02) and for a while, it was to be a dissociation. Therefore, we believed that it was likely to a toxic substance.

A Study on the Preparation of the Fly ash Adhesion-Activated Carbon and on the Removal of Heavy Metals (석탄회부착활성탄의 제조 및 중금속 제거에 관한 연구)

  • 문옥란;신대윤;고춘남
    • Journal of environmental and Sanitary engineering
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    • v.14 no.4
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    • pp.1-8
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    • 1999
  • This study was aimed ultimately to develop an adsorption process treating heavy metal wastewater by utilizing activated carbon using flyash. The affecting factors in adsorption process on heavy metal by flyash adhesion-activated carbon are s follows. Factors such as pH, and quality of activated carbon, and reaction time made batch adsorption isotherm described adsorption capacity was made use of the investigation to evaluate adsorptive possibility of heavy metal.As the results of this study, H ion has influence on adsorption of heavy metal if pH is low. As reaction time is transformed, factors such as optimum reaction time is taken into consideration an adsorptive process of heavy metal because an adsorption and a reduction process occur. Adsorption isotherm of adhesion-activated carbon was generally obeyed to Freundlich formular than Langmuir formular and Freundlich constant, l/n were obtained in the range of 0.1~0.5.

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Sulfation Reaction Kinetics of Pulverized Korean Dolomite and Limestone using Thermogravimetric Analyses (열중량분석을 이용한 국내산 미분 백운석과 석회석의 황화 반응 특성 연구)

  • 박영철
    • Journal of Energy Engineering
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    • v.7 no.2
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    • pp.216-222
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    • 1998
  • Thermogravimetric analyses were conducted by isothermal technique in order to characterize the sulfation reaction of calcined sorbents such as Tanyang dolomite, Yongwol dolomite, Tanyang limestone, and Yongwol limestone. Sulfation reaction for 0.08 mm in particle diameter were carried out with respect to various factors.; isothermal reaction temperatures (650~85$0^{\circ}C$), SO$_2$ concentration (0.38~1%), and oxygen concentration (1.2~6.7%). Measured reaction orders of SO$_2$ concentration, oxygen concentration, and activation energy were 0.3~2.2, 0.22~0.51 and 23.6~36 kJ/mol, respectively. The kinetic equations of sulfation reaction of calcined dolomites were correlated with various factors.

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