• 제목/요약/키워드: reaction degree

검색결과 1,092건 처리시간 0.028초

IGCC 발전 플랜트에서 복합발전공정-공기분리장치의 연계에 관한 열역학적 성능 평가 (Thermodynamic Performance Evaluation of an Integration Design between the Combined-cycle and Air Separation Unit in an IGCC Power Plant)

  • 원온누리;김현정;박성구;나종문;최경민;김덕줄
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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    • pp.49-51
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    • 2012
  • In this paper, the integration issue, such as an air-side integration design between the gas turbine and air separation unit, is described and analyzed by the exergy and energy balance of the combined-cycle power block in an IGCC power plant. The results showed that the net power of the system was almost same, but that of the gas turbine was decreased as the integration degree increased. The highest exergy loss was occurred in the combustor of gas turbine, which was affected by the chemical reaction, heat conduction, mass diffusion, and viscous dissipation.

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Degradation of Ferroelectric Properties of Pt/PZT/Pt Capacitors in Hydrogen-containing Environment

  • Kim, Dong-Chun;Lee, Won-Jong
    • Transactions on Electrical and Electronic Materials
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    • 제6권5호
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    • pp.214-220
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    • 2005
  • The ferroelectric properties of the $Pt/PZT(Pb(Zr,Ti)O_3)/Pt$ capacitors are severely degraded when they are annealed in hydrogen-containing environment. Hydrogen atoms created by the catalytic reaction of Pt top electrode during annealing in hydrogen ambient penetrate into PZT films and generate oxygen vacancies by the reduction of the PZT films, which is likely to cause the degradation. The degree of hydrogen-induced degradation and the direction of voltage shift in P-E curves of the pre-poled PZT capacitors after annealing in hydrogen ambient is dependent on the polarity of the pre-poling voltage. This implies that oxygen vacancies causing hydrogen induced degradation are generated by hydrogen ions having a polarity. The degraded ferroelectricity of the PZT capacitors can be effectively recovered by the shift of oxygen vacancies toward the Pt top electrode interface during post-annealing in oxygen environment with applying negative unipolar stressing.

稀搏溶液에서의 Polymer의 機械的 切斷. 混合溶媒의 영향 Ⅱ (Mechanical Degradation of Polymers in Dilute Solution. The Influence of the Mixed Solvents II.)

  • 원영무
    • 대한화학회지
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    • 제16권1호
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    • pp.50-55
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    • 1972
  • The mechanical degradation of $poly(\alpha-methyl$ styrene) in several mixed solvents (chlorobenzene-n-butyl alcohol, chlorobenzene-sec-butyl alcohol, chlorobenzene-Kerosene, chlorobenzene-methylketone) was studied using the capillary flow method. The velocity constant of scission reaction (K) and the limited degree of polymerization (g) were compared at the same value of [${\eta}$], which is considered as the parameter of molecular dimension of polymers in solution. As results, (K) did not change much, even if the species and the volume fraction of poor(non-) solvents changed, while the value of (g) changed according to the species of poor (non-) solvents and the value of [${\eta}$] these results were discussed.

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Synthesis, Characterization, and Properties of Ethoxylated Azo Dyes

  • Shen, Kaihua;Choi, Dong Hoon;Li, Zongshi
    • Fibers and Polymers
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    • 제4권1호
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    • pp.32-37
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    • 2003
  • The nonionic surfactant properties of ethoxylated azo dyes, such ai cloud point and surface tension have been investigated. The synthesized ethoxylated azo dyes could dye polyester fabric without any special pre-treatment. When the average number of ethylene oxide (EO) in the ethoxylated azo dye reached 6, its fixation could exceed $90^{\circ}C$ from the thermosol dyeing process. The average degree of condensation of ethylene glycol in the chain was interrelated with the dyeing results and did not affect on the maximum absorption wavelength (λmax) of the polyoxyethylene dye. When the average length of polyoxyethylene chain decreased, the molecular weight of dyes became smaller and the fixation of dyes was improved.

Grinding Method for Increasing Specific Surface Area of Fluidized Bed Fly Ash

  • Lim, Chang Sung;Lee, Ki Gang
    • 한국세라믹학회지
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    • 제56권2호
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    • pp.153-159
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    • 2019
  • In this study, fly ash of a fluidized bed boiler produced in a power plant was stabilized by hydration and carbonation reaction. Then, each raw material was pulverized by two kinds of grinding equipment (Planetary mills and pot mills); the degree of grinding and the agglomeration behavior were observed. It was found that there were changes of specific surface area and particle size distribution according to grinding time. The surface of the raw material was observed using an optical microscope. As a result, agglomerates of about 75 ㎛ or more due to electrostatic phenomenon were formed as the grinding time became longer; it was confirmed that the crushing efficiency slightly increased with use of antistatic agent.

Levan으로부터 Levanbiose를 생산하는 미생물의 분리 및 배양 (Isolation and Cultivation of Microorganism Producing Levanbiose from Levan)

  • 이태호;강은정;강수경
    • 한국식품영양과학회지
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    • 제27권3호
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    • pp.441-447
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    • 1998
  • A bacterial strain No. 43 was isolated from soil samples as a levan-assimiating microorganism producing an extracellular levanase and hydrolying levan to levanbiose. According to the taxonomic characteristics of its morphological and physiological properties, the strain was idenified as Pseudomonas sp. No. 43. The optimum culura medium was composed of 10g levan, 5g(NH4)2SO4, 3g NH4Cl, 3g polypepton, 1g K2HPO4, 0.5gMgSO4.7H2O, and 0.2g MnCl2.4H2O per liter. The cultivation for levanase was carried out in pH 7.0 at 4$0^{\circ}C$ for 28hr. The reaction product was a kind of oligosaccharide and it was purified by chilled ethanol precipitation and gel filtration for evalluation of degree of polymerization (DP). The purified product was determined as levanbiose of MW 342 and DP2 by HPLC and FAB-MS.

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붕괴절토사면의 광물조성 특성 (Mineral Composition Properties of Collapsed Cut Slope)

  • 김진환;구호본;박미선;백영식
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2005년도 춘계 학술발표회 논문집
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    • pp.731-734
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    • 2005
  • Cut slopes are collapsed in Korea every year. Cut slope collapses cause a loss of lives and assets. Many researchers make clear collapse factor of cut lope. Fresh rock weathered through reaction undergroundwater and groundwater. During weathering process, weathered minerals are created. Weathered minerals are analysed by X-ray diffraction meter. X-ray diffraction meter make possible quantity assessment of degree of weathering and indicator of potential collapse possibilities. This paper discuss possibilities of cut slope dangerous with analysis of weathered minerals of cut slope.

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POFA를 혼입한 시멘트의 포졸란 반응에 관한 연구 (Study on the Pozzolan Reaction Degree of Palm Oil Fuel Ash as a Mineral Admixture for Sustainable Concrete)

  • 이형민;이한승
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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    • pp.335-336
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    • 2010
  • POFA(Palm oil fuel ash)는 Palm fiber 와 shell의 부산물로써 콘크리트용 혼화재로 사용이 가능하다. 그러나 POFA를 사용한 콘크리트의 포졸란 반응에 관한 연구는 매우 적다. 따라서 본 연구에서는 다른 콘크리트용 혼화재료와 동일한 수준으로 POFA의 혼입 치환율을 달리한 모르타르의 압축강도 및 활성도 지수, 포졸란 활성도 지수(API)를 정량적으로 평가하여 혼화재료로서의 적합성을 평가하였다.

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An Integrated System to Predict Early-Age Properties and Durability Performance of Concrete Structures

  • 왕소용;이한승
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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    • pp.465-466
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    • 2010
  • In this paper, an integrated system is proposed which can evaluate both the early-age properties and durability performance of concrete structures. This integrated system starts with a hydration model which considers both Portland cement hydration and chemical reactions of supplementary cementing materials (SCM). Based on the degree of hydration of cement and mineral admixtures, the amount of reaction products, the early age heat evolution, chemically bound water, porosity, the early age short-term mechanical behaviors, shrinkage and early-age creep are evaluated as a function of curing age and curing conditions. Furthermore, the durability aspect, such as carbonation of blended concrete and chloride attack, are evaluated considering both the material properties and surrounding environments. The prediction results are verified through experimental results.

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정렬불량을 가진 기어 커플링의 동역학적 모델 개발에 관한 연구 (I) - 기어 커플링의 동적모델 구축을 중심으로- (A Study on Development the Dynamic Model to Misaligned Gear Coupling (I) - The Focus on Development of Dynamic Model to n Gear Coupling)

  • 김병옥;김용철
    • 대한기계학회논문집A
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    • 제27권6호
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    • pp.857-863
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    • 2003
  • In rotating machinery, unbalance and misalignment are major concerns in vibration. Unbalance can be eliminated by balancing procedure to some degree. but little work has been done on the vibrations that occur in a misaligned rotor system. Currently, no generalized theoretical model based on a rotor system with flexible coupling is available to describe the vibrations caused by misalignment. As a part of systematic investigation on the misalignment, first of all, the study on flexible coupling with misalignment should be preceded. In this study, the geometry and reaction force and moment of a gear coupling with misalignment was investigated, also the theoretical model of a gear coupling with misalignment was presented by using the relationship between geometry and moment of gear coupling. It is expected that the proposed procedure can be applied to derive the theoretical model of other couplings.