• 제목/요약/키워드: reaction degree

검색결과 1,092건 처리시간 0.027초

UV와 $Fe^{2+}$, 그리고 $H_2O_2$를 조합한 고급산화 공정에서의 Pentachlorophenol의 분해 속도 연구 (A Study on the Comparison of Advanced Oxidation Reactions Including UV, $Fe^{2+}$, and $H_2O_2$ for the Degradation of Pentachlorophenol)

  • 손현석;김문경;조경덕
    • 대한환경공학회지
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    • 제29권7호
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    • pp.846-851
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    • 2007
  • 본 연구는 PCP를 UV, $UV/H_2O_2$, $Fe^{2+}$, $Fe^{2+}/H_2O_2$, 그리고 $UV/Fe^{2+}/H_2O_2$의 공정을 이용하여 처리할 저 각각 공정의 처리효율을 비교하여 각 반응의 결합에 의한 개선 효과와 분해 기전을 규명한 연구이다. 실험의 결과 UV 반응에 $H_2O_2$의 첨가에 따라 약 13배 정도의 유사 일차 반응 속도의 증가를 보였으며, $Fe^{2+}$ 단독 반응에 비해 180 mM과 16 mM의 $H_2O_2$의 첨가는 각각 4배와 7.25배의 반응 속도 증가를 보였다. 또한 $Fe^{2+}/H_2O_2$의 반응에 비해 UV를 조사한 반응의 경우 약 3.1배의 반응 속도의 개선을 보였다. 이러한 반응속도의 증가는 각 반응에서 생성되는 OH 라디칼의 생성과 밀접한 관계가 있었다. $Fe^{2+}/H_2O_2$ 반응에서 일어나는 슬러지 침전 반응은 UV를 조사함으로서 상당부분 제거가 가능하였다.

생체합금 Titanium의 표면처리에 따른 골반응의 변화에 대한 조직학적 관찰 (Histological Observation of Bone Reaction with Relation to Surface Treatment of Titanium)

  • 안면환;최용석;안종철;서재성;이동철;장재혁
    • Journal of Yeungnam Medical Science
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    • 제13권1호
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    • pp.116-133
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    • 1996
  • 생체합금의 생체적합성을 검증하기위해, 표면처리가 되지 않은 타이타늄 봉과 표면처리를 시행한 타이타늄 봉을 실험용토끼의 대퇴골 근위부에 삽입하여 6주, 12주 및 26주후 방사선 관찰 후 광학현미경적 검사를 통한 골 반응을 비교 관찰하였다. 전 례에서 부식에 의한 반응은 관찰되지 않았으며, 신생골의 증식은 타이타늄의 삽입 후 26주까지 경도의 골증식이 관찰되었으나, 표면처리여부에는 관계가 없었다. 표면처리를 시행하지 않은 타이타늄의 삽입한 11례 중 1례의 경우 삽입 후 12주에 경도의 골괴사반응이 관찰되었으며 표면처리를 시행한 타이타늄을 삽입한 후 전 례에서 골괴사가 관찰되지 않았다. 이는 수술적 조작에 의한 것으로 사료되었다. 섬유원세포의 증식은 시기에 관계없이 전 례에서 관찰되었으며, 표면처리 여부 혹은 시간의 경과 정도와 관계가 없었다. 표면처리를 시행하지 않은 타이타늄의 삽입 후 6주에는 침윤정도 및 조직반응정도는 표면처리한 타이타늄의 삽입에 비해 통계적으로 유의하게 증가하였다. 그러나, 12주 및 26주 후에는 유의한 차이가 없었다. 다중회귀분석법의 단계별 투입방식을 이용하여 세포의 침윤율을 시간의 경과와 표면 처리여부에 따라 상관관계를 분석한결과, 세포 침윤율은 시간의 경과 및 표면처리를 하게 됨에 따라 감소하는 경향이 있었다. 조직 반응율의 정도도 침윤율과 유사한 양상을 나타내었다. 이상의 결과, 생체합금의 표면처리에 따라 골반응의 정도가 유의한 차이가 있었으므로 내고정 기구의 제작을 위해서는 보다 생체 적합성이 양호한 제작방법의 개발이 요구될 것으로 사료되었다.

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Bordetella 감염증(感染症)의 혈청학적진단(血淸學的診斷): 특히 보균돈검색(保菌豚檢索)을 위한 급속평판응집반응(急速平板凝集反應)의 실용화(實用化) (Serological Diagnosis of Bordetellosis: Application of Rapid Plate Agglutination Technique for the Detection of Carrier in Swine)

  • 강병규
    • 대한수의학회지
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    • 제18권2호
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    • pp.61-67
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    • 1978
  • The detection of Bordetella bronchiseptica which is supposed to be an agent of the infectious atrophic rhinitis of swine, is likely to receive more attention in the future as the pork industry comes to realize that eradication of this infection from breeding herds is a practical possibility. Experiments described here were carried out to establish the rapid plate agglutination test for the detection of the infectious atrophic rhinitis of swine in the field using the criteria of antigen preparation, effects on the antigenecity after storing of the antigen and reaction appearing time. Also, the agglutinabilities between the plate and tube method were compared and the degree of pathological lesions were recorded in relation to tube agglutination titers. Obtained results were as follows: 1. No differences were noted in the agglutinabilities on the plate agglutination test between the treatments in antigen preparation-formolized, merthiolate-killed and living organism. 2. The agglutinability of the antigens did not show any significant changes until 10 weeks of storage at 4 C; however, after 10 weeks of storage, non-specific reaction was observed with the HPCD control sera. 3. The results of the plate and tube agglutination tests were not comparable but the effective use of the plate method in Bordetella bronchiseptica eradication programs in pigs especially in the sow is stressed as a screening test.

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상악 전방견인시 악안면골의 초기반응에 관한 Laser Holography연구 (A LASER HOLOGRAPHIC STUDY ON THE INITIAL REACTION OF MAXILLOFACIAL COMPLEX TO MAXILLARY PROTRACTION)

  • 강흥석
    • 대한치과교정학회지
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    • 제18권2호
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    • pp.367-385
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    • 1988
  • In case of skeletal Class III malocclusion with underdeveloped maxilla, the extraoral orthopedic force for the stimulation of maxillary growth or anterior reposition of the maxilla has been used clinically for the improvement of facial skeletal relationship. The purpose of this investigation was to examine the initial reaction of maxillofacial complex to the maxillary protraction by using extraoral orthopedic force. The dried human skull was used and this investigation was done by means of double exposure holographic interferometry. The protraction forces placed on the canine or the first molar were parallel, $10^{\circ}$ downward, $20^{\circ}$ downward to the occlusal plane. Fringe pattern of each protraction condition was compared and analized. The results were as follows: 1. Each maxillofacial bone displaced saparately. 2. More displacement was shown at the area of the teeth and the alveolar bone. 3. A counterclockwise rotation of the maxilla wa decreased by downward protraction and especially 20 degree downward protraction from the canine showed least rotation. 4. On the zygomatic arch, outward bend was observed and this effect was decreased by downward protraction. 5. On the zygomatic bone, the counter clockwise rotation was increased by the downward protraction. 6. When maxillary expansion was applied at the same time, outward and upward displacement with counterclockwise rotation was observed on the maxilla. 7. The lateral pterygoid plate of sphenoid bone was affected by maxillary protraction.

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자전거로봇의 균형제어 및 주행제어를 위한 LQR 제어기 설계 (LQR Controller Design for Balancing and Driving Control of a Bicycle Robot)

  • 강석원;박경일;이장명
    • 제어로봇시스템학회논문지
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    • 제20권5호
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    • pp.551-556
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    • 2014
  • This paper proposes a balancing control and driving control of a bicycle robot based on dynamic modeling of the bicycle robot, which has been derived using the Lagrange equations. For the balancing control of the bicycle robot, a reaction wheel pendulum method has been adopted in this research. By using the dynamics equations of the bicycle robot, an LQR controller has been designed for a balancing and driving control of a bicycle robot. The performance of the balance control is verified experimentally before the driving control, which shows a stable posture within one degree vibrations. To show the dynamic characteristics of the bicycle robot during driving, a trapezoidal velocity trajectory is selected as the references. Through simulations and real experiments, the effectiveness of the proposed algorithm has been demonstrated.

Least Squares Based PID Control of an Electromagnetic Suspension System

  • Park, Yon-Mook;Nam, Myeong-Ryong;Seo, In-Ho;Lee, Sang-Hyun;Lim, Jong-Tae;Tahk, Min-Jea
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2003년도 ICCAS
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    • pp.2252-2257
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    • 2003
  • In this paper, we develop the so-called functional test model for magnetic bearing reaction wheels. The functional test model has three degree of freedom, which consists of one axial suspension from gravity and the other two axes gimbaling capability to small angle, and does not include the motor. For the control of the functional test model, we derive the optimal electromagnetic forces based on the least squares method, and use the proportional-integral-derivative controller. Then, we develop a hardware setup, which mainly consists of the digital signal processor and the 12-bit analog-to-digital and digital-to-analog converters, and show the experimental results.

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공정 효율 향상을 위한 연료전지전극 개발 (Manufacturing Process Improvement of Electrode for PEMFC)

  • 박석정;이재승;이기섭;노범욱
    • 한국수소및신에너지학회논문집
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    • 제26권6호
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    • pp.547-553
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    • 2015
  • For commercialization of fuel cell electric vehicles, one of the key objectives is to reduce cost of full stack assembly. Regarding Membrane Electrode Assembly, the major issue is to improve fuel cell activation process in the initial Hydrogen Oxidation Reaction and Oxygen Reduction Reaction. In this research, the VD (Vacuum Drying) process has been developed for improvement of activation process. The VD condition is developed by controlling the temperature and degree of vacuum to remove the remaining solvent of electrode. Consequently, the electrode applied to VD process showed the low characteristics such as 3.5% of remaining solvent content and the improved efficiency such as 15% of activation process speed.

콩의 취반속도에 미치는 온도의 영향 (Effect of Temperature on Cooking Rate of Soybean)

  • 김성곤;조광호;김종군
    • 한국식품과학회지
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    • 제18권5호
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    • pp.372-375
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    • 1986
  • 콩을 $106^{\circ}{\sim}121^{\circ}C$의 가압조건에서 일정시간 조리하면서 최대 절단력을 측정하고 이로부터 조리속도를 계산하였다. 콩의 조리속도는 1 차반응의 속도로 표시될 수 있었으며 반응속도상 수는 조리온도가 4 또는 $5^{\circ}C$ 상승함에 따라 약 2배 정도 증가하였다. 동일한 조리도를 나타내는 온도-시간과의 관계로부터 계산한 콩의 연화에 따른 Z-값은 $13.3^{\circ}C$ 이었다.

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1,3-Butadiene diepoxide로 가교된 히아루론산 막의 응용 (Application of Hyaluronic Acid Membrane Cross-linked with 1,3-Butadiene Diepoxide)

  • 정성일;한광선;배정은;김인섭
    • 멤브레인
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    • 제18권2호
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    • pp.124-131
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    • 2008
  • 조직공학용 생체 물질로 사용하고자 가교제 1,3-butadiene diepoxide (BD)를 사용하여 락타이드와 가교시킨 히아루론산 막을 제조하였다. 막의 락타이드 및 BD 반응도는 핵자기 공명 분광볍으로 결정하였다. BD 농도가 높을 경우 6%이하의 성장저해 현상이 나타났으나 그 값은 세포 성장에 문제되지 않을 정도로 충분히 낮았다. 가교온도가 낮을수록 탄성 율은 증가하고 팽윤도는 감소하였다. 막의 생분해속도는 가교온도가 낮을수록 감소하였다. 약물방출 실험 결과 가교 온도가 낮을수록 막을 통한 약물 투과는 감소하였다.

고체산화물 연료전지 시스템을 위한 kW급 마이크로채널 촉매 디젤 자열 개질기 (kW-class Diesel Autothermal Reformer with Microchannel Catalyst for Solid Oxide Fuel Cell System)

  • 윤상호;강인용;배규종;배중면
    • 대한기계학회논문집B
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    • 제32권7호
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    • pp.558-565
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    • 2008
  • Solid oxide fuel cell(SOFC) has a higher fuel flexibility than low temperature fuel cells, such as polymer electrolyte fuel cell(PEMFC) and phosphoric acid fuel cell(PAFC). SOFCs also use CO and $CH_4$ as a fuel, because SOFCs are hot enough to allow the CH4 steam reformation(SR) reaction and water-gas shift(WGS) reaction occur within the SOFC stack itself. Diesel is a good candidate for SOFC system fuel because diesel reformate gas include a higher degree of CO and $CH_4$ concentration than other hydrocarbon(methane, butane, etc.) reformate gas. Selection of catalyst for autothermalr reforming of diesel was performed in this paper, and characteristics of reforming performance between packed-bed and microchannel catalyst are compared for SOFC system. The mesh-typed microchannel catalyst also investigated for diesel ATR operation for 1kW-class SOFC system. 1kW-class diesel microchannel ATR was continuously operated about 30 hours and its reforming efficiency was achieved nearly 55%.