• Title/Summary/Keyword: rate dependent

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The Effect of Solvent on the $\alpha$-Effect(3): Nucleophilic Substitution Reactions of Aryl Acetates in $MeCN-H_2O$ Mixtures of Varying Compositions

  • Um Ik-Hwan;Hahn Gee-Jung;Lee Gwang-Ju;Kwon Dong-Song
    • Bulletin of the Korean Chemical Society
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    • v.13 no.6
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    • pp.642-647
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    • 1992
  • Second-order rate constants have been measured spectrophotometrically for the reactions of substituted phenyl acetates with butane-2,3-dione monoximate and p-chlorophenoxide anions in MeCN-H$_2$O mixtures of varying compositions. The reaction rate, unexpectedly, decreased remarkably upon initial additions of MeCN to H$_2$O up to 30-40 mole ${\%}$ MeCN, and followed by a gradual increase upon further additions of MeCN. The change in solvent composition also influenced the magnitude of the ${\alpha}$-effect, i.e., the ${\alpha}$-effect increased as the mole ${\%}$ MeCN increased. The solvent dependent ${\alpha}$-effect for the present system appears to indicate that the differential solvation between the ${\alpha}$-effect nucleophile and the corresponding normal nucleophile is not solely responsible but the difference in the transition-state stabilization is also responsible for the ${\alpha}$ -effect in organic solvent-rich region.

Heat Transfer Characteristics in Impinging Air Jet with Hybrid Rod (하이브리드 로드를 갖는 충돌공기제트의 열전달특성에 관한 연구)

  • 표창기;박상록;김동춘;금성민;임장순
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.3
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    • pp.277-283
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    • 2000
  • The heat transfer characteristics for air jet vertically impinging on a flat plate which had a set of hybrid rod were investigated experimentally. The rod had a cross section made with a half of circular cross section and that of rectangular and was installed in front of the plate. The heating surface was given constant heat flux value of 1020 W/$m^2^{\circ]C$ and the problem parameters investigated were jet Reynolds number, nozzle-to-plate spacing and the rod size. The local and local average Nusselt number characteristics were found to be dependent on the rod size because the flow was disturbed by installing the rod. Higher convective heat transfer rate occurred in the whole plate as well as in the stagnation region.

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The Relationship Between Financial Condition and Business Cycle in Mongolia

  • Doojav, Gan-Ochir;Purevdorj, Munkhbayar
    • East Asian Economic Review
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    • v.23 no.2
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    • pp.203-223
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    • 2019
  • This paper examines the interactions between financial conditions and business cycles in Mongolia, a small open economy, heavily depending on commodity exports. We construct two financial conditions indexes based on the reduced form IS model and the vector autoregression (VAR) model as surveillance tools to quantify the degree of the financial conditions. We find that real short-term interest rate and real effective exchange rate gap get a higher weight in the FCIs. Both business and financial cycles are often more pronounced in Mongolia, and financial condition is dependent of the financial and monetary policies in place. The analysis of the predictive power of the FCIs for business cycles shows that they have predictive information for the near-term economic activities. FCIs are also helpful in signaling inflation turning points.

STUDY OF DYNAMICAL MODEL FOR PIEZOELECTRIC CYLINDER IN FRICTIONAL ANTIPLANE CONTACT PROBLEM

  • S. MEDJERAB;A. AISSAOUI;M. DALAH
    • Journal of applied mathematics & informatics
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    • v.41 no.3
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    • pp.487-510
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    • 2023
  • We propose a mathematical model which describes the frictional contact between a piezoelectric body and an electrically conductive foundation. The behavior of the material is described with a linearly electro-viscoelastic constitutive law with long term memory. The mechanical process is dynamic and the electrical conductivity coefficient depends on the total slip rate, the friction is modeled with Tresca's law which the friction bound depends on the total slip rate with taking into account the electrical conductivity of the foundation both. The main results of this paper concern the existence and uniqueness of the weak solution of the model; the proof is based on results for second order evolution variational inequalities with a time-dependent hemivariational inequality in Banach spaces.

Ultralow Intensity Noise Pulse Train from an All-fiber Nonlinear Amplifying Loop Mirror-based Femtosecond Laser

  • Dohyeon Kwon;Dohyun Kim
    • Current Optics and Photonics
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    • v.7 no.6
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    • pp.708-713
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    • 2023
  • A robust all-fiber nonlinear amplifying loop-mirror-based mode-locked femtosecond laser is demonstrated. Power-dependent nonlinear phase shift in a Sagnac loop enables stable and power-efficient mode-locking working as an artificial saturable absorber. The pump power is adjusted to achieve the lowest intensity noise for stable long-term operation. The minimum pump power for mode-locking is 180 mW, and the optimal pump power is 300 mW. The lowest integrated root-mean-square relative intensity noise of a free-running mode-locked laser is 0.009% [integration bandwidth: 1 Hz-10 MHz]. The long-term repetition-rate instability of a free-running mode-locked laser is 10-7 over 1,000 s averaging time. The repetition-rate phase noise scaled at 10-GHz carrier is -122 dBc/Hz at 10 kHz Fourier frequency. The demonstrated method can be applied as a seed source in high-precision real-time mid-infrared molecular spectroscopy.

Strategies to improve screening colonoscopy quality for the prevention of colorectal cancer

  • Joo Hye Song;Eun Ran Kim
    • The Korean journal of internal medicine
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    • v.39 no.4
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    • pp.547-554
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    • 2024
  • The incidence and mortality of colorectal cancer (CRC) have decreased through regular screening colonoscopy, surveillance, and endoscopic treatment. However, CRC can still be diagnosed after negative colonoscopy. Such CRC is called interval CRC and accounts for 1.8-9.0% of all CRC cases. Most cases of interval CRC originate from missed lesions and incompletely resected lesions. Interval CRC can be minimized by improving the quality of colonoscopy. This has led to a growing interest in and demand for high-quality colonoscopy. It is important to reduce the risk of CRC and its associated mortality by improving the quality of colonoscopy. In this review article, we provide an overview of colonoscopy quality indicators, including bowel preparation adequacy, the cecal intubation rate, the adenoma detection rate, the colonoscopy withdrawal time, appropriate polypectomy, and complication of the procedure. Because colonoscopy is a highly endoscopist-dependent procedure, colonoscopists should be well-acquainted with quality indicators and strive to apply them in daily clinical practice for the prevention of CRC.

A Study on Smoking Behavior and The Influencing Factors Among High School Male Students in Korea (고등학교(高等學校) 남학생(男學生)의 흡연행위(吸煙行爲)와 관련요인(關聯要因) 분석(分析))

  • Chang, Young Mee
    • Journal of the Korean Society of School Health
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    • v.4 no.2
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    • pp.193-215
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    • 1991
  • This study is aimed at providing basic information applicable to setting up the education programs and strategies to prevent smoking among high school students by analysing smoking behavior and influencing factors. The samples consisted of 814 students, 557 parents and 362 teachers selected randomly from 8 high schools, one from each school district in Seoul. Date Analyses were made through Chi-Square test, Factor Analysis, One Way ANOVA, Multiple Regression, Correlation. SPSS/$PC^+$program was utilized. Smoking behavior (continuous smoking, re-smoking, ex-smoking, never smoking, daily smoking, occasional smoking) were used as dependent variables. Influencing factors (male students, habits, attitudes and knowledge toward smoking, home life, school life, juvenile delinquency, friendship, demographic parent's and teacher's recognition toward male students smoking) were used as in dependent variables. The major findings of the study are as follows : 1. The total smoking rate occupies 41.1% whereas the continuous smoking rate stands at 19.2%, re-smoking rate 9.5%, ex-smoking rate 12.4% and never smoking rate 58.9%. 2. The total smoking rate among high school students is significantly correlated with their monthly expenditures and type of school (p<0.001). The continuous smoking rate also shows the same tendency. As the length of butt get shorter, the current smoking rate increase. The duration of smoking is in proportion to its continuity. The major motive of smoking is curiousity whereas that re-smoking is to follow friend's behavior. The study shows that peer pressure is the most powerful factor influencing smoking behavior of students. Friends and fellow students encourage to pick up smoking and resume smoking even alter one stops smoking. 3. The correlationship between favorable attitudes toward smoking and the current smoking rate and its continuity is statistically significant(p<0.05, p<0.01, p<0.001). 4. The stability and harmony of family life and the current smoking rate show negative correlationship. The daily smoking amount of father is in proportion to the continuity of students' smoking. When parents are in favor of smoking, it is more likely that the experimental smoking rate increase the smoking rate increases, and vice versa. The more acceptable attitudes toward smoking among siblings is also one of the factors to increase the smoking rate and continuity (p<0.001). The more lenient the attitudes of parents toward their children's association with smoking friends, the higher the smoking rate. When students have difficulties in adjusting to school life, it is more likely that the current smoking rate and continuity increase. 5. The continuity of smoking and friendship are significantly correlated (p<0.05, p<0.01, p<0.001). 6. The continuity of smoking and juvenile delinquency are significantly correlated (p<0.001). 7. The difference in attitudes and smoking reasons of parents and students is significantly correlated to different smoking behavior (p<0.01, p<0.001). While smoking knowledge does not significantly influence their smoking behavior, it is noted that in the case of teachers, smoking reason (p<0.05), attitudes (p<0.001) and knowledge (p<0.05) strongly influence their smoking behavior. 8. There is a significantly correlation among the smoking reasons, attitudes and knowledge between students and parents(p<0.001). As for the correlationship between regularity and smoking amount and other influencing factors, the daily smoking amount is in proportion to depth of inhalation and duration of smoking, negative attitudes of parents unstability of family, dissatisfaction of family members, juvenile delinquency, strong smoking reasons and positive attitudes towards smoking. 9. In the case of daily smokers depth of inhalation is significantly correlated to the duration of smoking, juvenile delinquency, acceptability of parents, dissatisfaction of family members and smoking reasons. The duration of smoking motives is significantly correlated to juvenile delinquency, high acceptability of parents, strong smoking motive and positive attitudes toward smoking. 10. It is noted that 40% of parents and 30% of teachers do not recognize the significant correlationship between and the relative influencing factors mentioned above.

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An Experimental Study on the Recovery of Diesel Oil Using a Drum Type Skimmer (드럼식 유회수기의 디젤유 회수에 관한 실험적 연구)

  • Song Dong-Eub;Jung Song-Whoan
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.6 no.4
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    • pp.52-66
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    • 2003
  • Generally we have difficulty in removing oil using mechanical devices because recovery rate and recovery efficiency decrease remarkably when operating in thin oil films or in oils of very high viscosity In the Present study a series of experiments were carried out to study the effect of operating conditions on the rate of recovery for the spilled oil using a drum type skimmer. For each set of experiments depth of immersion, oil film thickness and the circumferential speeds were varied systematically to find the effects on the recovery rate. The results shows that recovery rate is dependent on the contact angle for the depth of immersion and the highest rate of oil recovery shows in the case of a contact angle of 45°(h/d=0.15). For the removal of spilled oil the optimal circumferential speed can be found as the critical value to reach the saturated recovery rate for a given oil film thickness and depth of immersion. Even in thin oil thickness we have enough recovery rate and recovery efficiency within critical circumferential speed this way.

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Bioactivity of $CaO-P_2O_5-SiO_2$ Glasses ($CaO-P_2O_5-SiO_2$계 유리의 생체활성)

  • 조정식;김철영
    • Journal of the Korean Ceramic Society
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    • v.30 no.6
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    • pp.433-440
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    • 1993
  • The bioactivity of glasses in the CaO-SiO2 system and CaO-P2O5-SiO2 system with less than 10mol% of P2O5 was investigated by in vitro test in simulated body flood(SBF). The formation of Ca.P film and hydroxyapatite on the surface of glasses after in vitro test was analysed by X-ray photoelectron spectoscopy (XPS), fourier transform infrared reflection spectroscopy (FT-IRRS), energy dispersive X-ray spectroscopy (EDS), and scanning electron microscopy (SEM) observation. In the early stage of Ca.P film formation after in vitro test for CaO-SiO2 and CaO-P2O5-SiO2 glasses, the rate of Ca.P film formation on the surface of the glasses was dependent of structural parameter (Y) evaluated from the glass composition. First, in the case of the glasses having Y value below 2, Ca.P film and SiO2-rich layer were formed simultaneously, and there were no differences of the rate of Ca.P film formation in terms of the Y values. Second, in the case of the glasses having Y value above 2, the SiO2-rich layer was formed, and then Ca.P.Si mixed layer was formed in the silica gel structure of the SiO2-rich layer, and finally the Ca.P film on the surface of SiO2-rich layer. The rate of Ca.P film formation delayed as the Y values increased. The rate of hydroxyapatite formation of glasses (the rate of transformation from Ca.P film to hydroxyapatite) seems to be propotional to the rate of Ca.P film formation and Y value. The rate of hydroxyapatite formation of glasses belonging to the second group was delayed as structural parameter increased, and the hydroxyapatite crystal showed spherical growth in the early reaction stage, and then showed silkworm-like linear growth as the reaction time increased.

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The Effect of Displacement Rate on Shear Characteristics of Geotextile-involved Ceosynthetic Interfaces (지오텍스타일이 포함된 토목섬유 경계면의 전단특성에 대한 변위속도 효과)

  • 김진만
    • Journal of the Korean Geotechnical Society
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    • v.19 no.1
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    • pp.173-180
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    • 2003
  • In spite of its potential importance in the assessment of geosynthetic-related dynamic problems, no serious attempt has yet been made to investigate a probable dependence of dynamic friction resistance of the geosynthetic interface on shear displacement rate. Hence, an experimental study of geosynthetics was carried out on a shaking table, and the relationship between dynamic friction resistance and shear displacement rate of geosynthetic interfaces was investigated. A cyclic, displacement rate-controlled experimental setup was used. The subsequent multiple rate tests showed that interfaces that involve geotextiles have such unique shearing characteristics that shear strengths tend to increase with displacement rate. In contrast, once submerged with water, the shear strength appears to be no longer dependent on the displacement rate, partly due to lubrication effect of water trapped inside the interface. The results of the experimental study can be used in the seismic safety assessment of a landfill cover and slope where the geosynthetic materials are exposed to a relatively low normal stress.