• Title/Summary/Keyword: rate dependent

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Effectiveness of Calcium Nitrite in Retarding Corrosion of Steel in Concrete

  • Abosrra, L.;Youseffi, M.;Ashour, A.F.
    • International Journal of Concrete Structures and Materials
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    • v.5 no.1
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    • pp.65-73
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    • 2011
  • Corrosion of steel bars embedded in concrete admixed with 0%, 2% and 4% calcium nitrite (CN), having compressive strengths of 20 and 46 MPa was investigated. Reinforced concrete specimens were immersed in 3% NaCl solutions for 1, 7 and 15 days where 0.4A external current was applied to accelerate the chemical reactions. Corrosion rate was measured by retrieving electrochemical data via potentiodynamic polarization technique. Pull-out tests of reinforced concrete specimens were then conducted to assess the corroded steel-concrete bond characteristics. Experimental results showed that corrosion rate of steel bars and steel-concrete bond strength were dependent on concrete strength, amount of CN added and accelerated corrosion period. As concrete strength increased from 20 to 46 MPa, corrosion rate of embedded steel decreased. The addition of 2% CN to concrete of 20 MPa was not effective in retarding corrosion of steel at long time of exposure. However, the combination of higher strength concrete and 2% or 4% CN appear to be a desirable approach to reduce the effect of chloride-induced corrosion of steel reinforcement. After 1 day of corrosion acceleration, specimens without CN showed higher bond strength in both concrete mixes than those with CN. After 7 and 15 days of exposure, the higher concentration of CN, the higher bond strength in both concrete mixes achieved, except for the concrete specimen of 20 MPa compressive strength with 2% CN that recorded the highest deterioration in bond strength at 15 days of exposure.

A Study on the Steam Hammering Characteristics by Sudden Closure of Main Stop Valve in the Main Steam Piping System of a Power Plant (화력발전소 주증기배관에서 밸브 차단에 따른 수증기 충격 특성에 관한 연구)

  • Ha, Ji-Soo;Lee, Boo-Youn
    • Journal of the Korean Institute of Gas
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    • v.17 no.2
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    • pp.70-77
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    • 2013
  • The present study has been carried out to analyze the effect of steam hammering on the steam piping system including the final superheater, the high pressure turbine, check valve and the first reheater by sudden stoping of main stop valve in a power plant. For the present steam hammering analysis, the well known Flowmaster software has been used to model the steam piping system and the time dependent characteristics of pressure and steam mass flow rate has been conducted. Using the result of the unsteady pressure and steam mass flow rate, the forces acting on the elbows in the piping system has been derived. From the present analysis, it has been elucidated that the elbow just before the main stop valve and the elbow near the connection pipe between bypass pipe and check valve had the largest force among the elbows in the steam piping system. The structural safety diagnostics study on the elbow and the supporting structures of the steam piping system of a power plant will be conducted in the future by the present results of the forces acting on the elbow.

Parameters Involved in Autophosphorylation in Chronic Myeloid Leukemia: a Systems Biology Approach

  • Kumar, Himansu;Tichkule, Swapnil;Raj, Utkarsh;Gupta, Saurabh;Srivastava, Swati;Varadwaj, Pritish Kumar
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.13
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    • pp.5273-5278
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    • 2015
  • Background: Chronic myeloid leukemia (CML) is a stem cell disorder characterized by the fusion of two oncogenes namely BCR and ABL with their aberrant expression. Autophosphorylation of BCR-ABL oncogenes results in proliferation of CML. The study deals with estimation of rate constant involved in each step of the cellular autophosphorylation process, which are consequently playing important roles in the proliferation of cancerous cells. Materials and Methods: A mathematical model was proposed for autophosphorylation of BCR-ABL oncogenes utilizing ordinary differential equations to enumerate the rate of change of each responsible system component. The major difficulty to model this process is the lack of experimental data, which are needed to estimate unknown model parameters. Initial concentration data of each substrate and product for BCR-ABL systems were collected from the reported literature. All parameters were optimized through time interval simulation using the fminsearch algorithm. Results: The rate of change versus time was estimated to indicate the role of each state variable that are crucial for the systems. The time wise change in concentration of substrate shows the convergence of each parameter in autophosphorylation process. Conclusions: The role of each constituent parameter and their relative time dependent variations in autophosphorylation process could be inferred.

Expression Profiles of Cellular Retinol-binding Protein, Type II (CRBP II) in Erlang Mountainous Chickens

  • Yin, H.D.;Tian, K.;Li, D.Y.;Gilbert, E.R.;Xiao, L.H.;Chen, S.Y.;Wang, Y.;Liu, Y.P.;Zhao, X.L.;Zhu, Q.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.3
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    • pp.310-315
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    • 2014
  • Cellular retinol-binding protein II (CRBP II) belongs to the family of cellular retinol-binding proteins and plays a major role in absorption, transport, and metabolism of vitamin A. In addition, because vitamin A is correlated with reproductive performance, we measured CRBP II mRNA abundance in erlang mountainous chickens by real-time PCR using the relative quantification method. The expression of CRBP II showed a tissue-specific pattern and egg production rate-dependent changes. The expression was very high (p<0.05) in jejunum and liver, intermediate in kidney, ovary, and oviduct, and lowest (p<0.05) in heart, hypothalamus, and pituitary. In the hypothalamus, oviduct, ovary, and pituitary, CRBP II mRNA abundance were correlated to egg production rate, which increased from 12 wk to 32 wk, peaked at 32 wk relative to the other time points, and then decreased from 32 wk to 45 wk. In contrast, the expression of CRBP II mRNA in heart, jejunum, kidney, and liver was not different at any of the ages evaluated in this study. These data may help to understand the genetic basis of vitamin A metabolism, and suggest that CRBP II may be a candidate gene to affect egg production traits in chickens.

Short-term protein intake increases fractional synthesis rate of muscle protein in the elderly: meta-analysis

  • Gweon, Hyun-Soo;Sung, Hee-Ja;Lee, Dae-Hee
    • Nutrition Research and Practice
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    • v.4 no.5
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    • pp.375-382
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    • 2010
  • The precise effects of protein intake on fractional synthesis rate (FSR) of muscle protein are still under debate. The sample size of these studies was small and the conclusions in young and elderly subjects were inconsistent. To assess the effect of dietary protein intake on the FSR level, we conducted a meta-analysis of controlled protein intake trials. Random-effects models were used to calculate the weighted mean differences (WMDs). Ten studies were included and effects of short-term protein intake were evaluated. In an overall pooled estimate, protein intake significantly increased the FSR (20 trials, 368 participants; WMD: 0.025%/h; 95%CI: 0.019-0.031; P < 0.0001). Meta-regression analysis suggested that the protein dose was positively related to the effect size (regression coefficient = 0.108%/h; 95%CI: 0.035, 0.182; P = 0.009). A subgroup analysis indicated that protein intake significantly increased FSR when the protein dose was ${\leq}$ 0.80 g/kg BW (16 trials, 308 participants; WMD: 0.027%/h; 95%CI: 0.019-0.031; P < 0.0001), but did not affect FSR when the protein dose was > 0.80 g/kg BW (4 trials, 60 participants; WMD: 0.016%/h; 95%CI: 0.004-0.029; P = 0.98). In conclusion, this study is the first integrated results showing that a short-term protein intake is effective at improving the FSR of muscle protein in the healthy elderly as well as young subjects. This beneficial effect seems to be dose-dependent when the dose levels of protein range from 0.08 to 0.80 g/kg BW.

A NUMERICAL STUDY ON THE COATING THICKNESS IN CONTINUOUS HOT-DIP GALVANIZING (연속 아연 도금 두께에 관한 수치 해석적 연구)

  • Lee, Dong-Won;Shin, Seung-Young;Cho, Tae-Seok;Kwon, Young-Doo;Kwon, Soon-Bum
    • Journal of computational fluids engineering
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    • v.14 no.1
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    • pp.1-8
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    • 2009
  • To control the coating thickness of zinc in the process of continuous hot-dip galvanizing, it is known from early days that the gas wiping through an air knife system is the most effective because of the obtainable of uniformity of coating thickness, possibility of thin coating, working ability in high speed and simplicity of control. But, the gas wiping using in the galvanizing process brings about a problem of splashing from the strip edge for a certain high speed of coating. Also, it is known that the problem of splashing directly depends upon the galvanizing speed and nozzle stagnation pressure. In theses connections, in the present study, we proposed two kinds of air knife systems having the same expansion rate of nozzle, and the jet structures and coating thicknesses from a conventional and new proposed nozzles are compared. In numerical analysis, the governing equations consisted of two-dimensional time dependent Navier-Stokes equations, standard k-e turbulence model to solve turbulence stress and so on are employed. As a result, it is found that it had better to use the constant rate nozzle from the point view of the energy saving to obtain the same coating thickness. Also, to enhance the cutting ability at the strip, it is advisable to use an air knife with the constant expansion rate nozzle.

A Study on the Ester Interchange Reaction of Dimethyl Naphthalate with Ethylene Glycol (Dimethyl Naphthalate와 Ethylene Glycol의 에스테르 교환반응에 관한 연구)

  • Sho, Soon-Yong;Cheong, Seong-Ihl
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.25-32
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    • 2001
  • The kinetics of ester interchange reaction of dimethyl naphthalate(DMN) with ethylene glycol(EG) has been studied in the range of 180-200 $^{\circ}C$ using zinc and manganese catalysts. The reaction was performed in a semibatch reactor under nonisothermal condition and the degree of reaction was calculated from experimental data of methanol removal rate and reaction temperature. As a reaction model, both the functional group model and the molecular species model were applied and analysed. In case of zinc catalyst, the ratio of reaction rate of methyl hydroxyethyl naphthalate(MHEN) with EG on that of DMN with EG is about 1.4, whereas in case of manganese catalyst the ratio is about 4.3, which implies that the reaction rate is quite dependent on the type of catalyst. In case of zinc catalyst, the reaction order of catalyst concentration on either DMN or MHEN and EG is less than 1, whereas in case of manganese catalyst, the reaction order is larger than 1. The activation energy for zinc and manganese catalyst, irrespective of the type of molecular species, e.g., DMN and MHEN, were found to be 25000 and 28750 cal/mol, respectively. As a result of comparing two reaction model, the molecular species model fits well for the experimental data.

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Dynamic Channel-Time Assignments based on the link status in IEEE 802.15.3 High-rate WPAN (IEEE 802.15.3 고속 무선 PAN(Personal Area Network)에서 링크상태에 따른 동적 채널할당)

  • 곽동원;이승형
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.29 no.7A
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    • pp.844-851
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    • 2004
  • Various types of error are caused due to many factors of various environment in air interface channel of wireless communications. In this case, the reliability of the channel is much lower than that of wired case. IEEE 802.15.3 high-rate WPAN, which operates in an ad hoc networking environment, is more susceptible to such errors. The problem has been investigated for wireless LANs, for example, as follows. If the queue size of a certain node is longer than that of other nodes, the node estimates that its channel state is bad and the resource of the node is decreased. However this method has a disadvantage that a central controller must always monitor the status. To avoid this disadvantage, in this paper, a new MAC protocol that the throughput of overall piconet is increased by LDS (Link-status Dependent Scheduling) is proposed.

Toxicological Efects of Aroclor 1254 on the Embryonic Development of the Olive Flounder Paralichthys olivaceus

  • Min, Eun Young;Kang, Ju Chan
    • Fisheries and Aquatic Sciences
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    • v.16 no.4
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    • pp.253-260
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    • 2013
  • We investigated the toxicological effects of Aroclor 1254 on the fertilized eggs, embryos and larvae of the olive flounder Paralichthys olivaceus. The survival rate and hatching success of the embryos decreased significantly in treated groups in an Aroclor 1254-dose-dependent manner. Significant differences were found at ${\geq}5{\mu}g/L$ Aroclor 1254 compared to the control group. Hatching success occurred at ${{\leq}}10{\mu}g/L$ Aroclor 1254, which was not significantly different to the control. Embryo malformation increased significantly at ${\geq}1{\mu}g/L$, and included yolk-sac and tail-flexure abnormalities. There was a significant decrease in the survival rate of the larvae at ${\geq}5{\mu}g/L$, which was accompanied by the malformations described above. Notably, concentrations as low as $1{\mu}g/L$ caused a significant increase in abnormalities in the larvae, including incidences of multi-focal hemorrhages, pericardial and yolk-sac edema, inhibition of swim bladder inflation and severe developmental delay. The responses to Aroclor 1254-induced toxicity were generally similar among fertilized eggs, embryos and larvae from three separate flounder hatcheries: Cheju Island, Yeosu and Chungnam, South Korea. These results indicate the high acute toxicity of Arolcor 1254 concentrations of which as low as $1{\mu}g/L$ in olive flounder larvae can affect unhatched embryos. To conclude, the average $LC_{50}$ values for Aroclor 1254 in the embryos and larvae were 50.92 and $3.08{\mu}g/L$, respectively. Additionally, the average $EC_{50}$ values, based on the rate of damage were 14.72 and 5.6$1{\mu}g/L$, respectively.

Effects of Chlorhexidine Digluconate on Rotational Rate of n-(9-Anthroyloxy)stearic Acid in Porphyromonas ginginvalis Outer Membranes

  • Jang, Hye-Ock;Cha, Seong-Kweon;Lee, Chang;Choi, Min-Gak;Huh, Sung-Ryul;Shin, Sang-Hun;Chung, In-Kyo;Yun, Il
    • The Korean Journal of Physiology and Pharmacology
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    • v.7 no.3
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    • pp.125-130
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    • 2003
  • The aim of this study was to provide a basis for studying the molecular mechanism of pharmacological action of chlorhexidine digluconate. Fluorescence polarization of n-(9-anthroyloxy)stearic acid was used to examine the effect of chlorhexidine digluconate on differential rotational mobility of different positions of the number of membrane bilayer phospholipid carbon atoms. The six membrane components differed with respect to 2, 3, 6, 9, 12, and 16-(9-anthroyloxy)stearic acid (2-AS, 3-AS, 6-AS, 9-AS, 12-AS and 16-AP) probes, indicating different membrane fluidity. Chlorhexidine digluconate increased the rate of rotational mobility of hydrocarbon interior of the cultured Porphyromonas gingivalis outer membranes (OPG) in a dose-dependent manner, but decreased the mobility of surface region (membrane interface) of the OPG. Disordering or ordering effects of chlorhexidine digluconate on membrane lipids may be responsible for some, but not all of its bacteriostatic and bactericidal actions.