• Title/Summary/Keyword: rate capacity effect

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The Effect of Synthesis Conditions on the Electrochemical Properties of LiFePO4 for Cathode Material of Secondary Lithium Ion Batteries (리듐 2차 전지용 약극활물질 LiFePO4의 합성 조건에 다른 전기화학적 특성)

  • Kim, Do-Gyun;Park, Hyun-Min;Jeong, Yeon-Uk;Lee, Joon-Hyung;Kim, Jeong-Joo
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.121-125
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    • 2006
  • [ $LiFePO_4$ ] is one of the promising materials for cathode material of secondary lithium batteries due to its high energy density, low cost, environmental friendliness and safety. $LiFePO_4$ was synthesized by the solid-state reaction method at 500 - 800°C. The crystal structure of $LiFePO_4$ was analyzed by X-ray powder diffraction. The samples synthesized at 600 and $700^{\circ}C$ showed a single phase of a olivine structure. The particle sizes were increased and the specific surface areas were decreased with heating temperatures. The electrochemical performance was investigated by coin cell test. The discharge capacities at 0.1 C-rate were 118 mAh/g and 112 mAh/g at $600^{\circ}C,\;700^{\circ}C$, respectively. In an attempt to improve the electrical conductivity of cathode materials, $LiFePO_4/graphite$ composite was prepared with various graphite contents. The electrical conductivity and discharge capacity were increased with increasing the graphite contents in composite samples. The rate capabilities at high current densities were also improved.

Experimental Study on Reduced Amount of Rebound in Wet Process Shotcrete Works by Upon Accelerator Contents (급결제 함유량에 따른 습식 Shotcrete 리바운드 감소량에 대한 실험적 연구)

  • Jeon, Jun Tai;Park, Hong Tae;Lee, Yang Kyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.6D
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    • pp.615-622
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    • 2012
  • The aim of shotcrete is to increase the bearing capacity and to protect the excavated surface from erosion by preventing falling of rock mass. Shotcreting method is divided into two types as dry process and wet process. Since 1997, wet process method has been used more frequently than dry process method in field works. The failure to bond, so called rebound, occurs in many case during shotcrete works. The excess amount of rebound has a significant effect on the total construction cost. For example, material and craft-man cost increases, the shooting time delays due to deceleration of work execution stage, work efficiency of craft-man decreases and additional cost to remove the muck generates. In this study, therefore, the experimental analysis of rebound amount and strength was conducted by analyzing the actual construction data for wet process type of shotcreting method upon accelerator contents. Also, the effective and rational method was suggested, which can be actually implemented in the Korea construction sites.

Investigation on optimum protection potential of high-strength Al alloy(5456-H116) for application in ships (선박용 고강도 Al합금(5456-H116)의 최적 방식 전위결정에 관한 연구)

  • Kim Sung-Jong;Ko Jae-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.157-168
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    • 2006
  • Recently, interest in using Al alloys in ship construction instead of fiber-reinforced plastic (FRP) has increased because of the advantages of A) alloy ships over FRP ships, including high speed, increased load capacity. and ease of recycling. This paper investigated the mechanical and electrochemical properties of Al alloys in a slow strain rate test under various potential conditions. These results will provide reference data for ship design by determining the optimum protection potential regarding hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys do not corrode on formation of a film that has resistance to corrosion in neutral solutions. In seawater, however, $Cl^-$ ions lead to the formation and destruction of a Passive film. In a potentiostatic experiment. the current density after 1200 sec in the Potential range of $-0.68\~-1.5\;V$ was low. This low current density indicates the protection potential range. Elongation at an applied potential of 0 V was high in this SSRT. However, corrosion protection under these conditions is impossible because the mechanical properties are worse owing to decreased strength resulting from the active dissolution reaction in parallel parts of the specimen. A film composed of $CaCO_3\;and\;Mg(OH)_2$ confers corrosion resistance. However, at potentials below -1.6 V forms non-uniform electrodeposition coating, since there is too little time to form a coating. Therefore, we concluded that the mechanical properties are poor because the effect of hydrogen gas generation exceeds that of electrodeposition. Comparison of the maximum tensile strength, elongation, and time to fracture indicated that the optimum protection potential range was from -1.45 to -0.9 V (SSCE).

Evaluation of Airflow Control Capability of Natural Ventilators with Various Dampers (자연환기 벤틸레이터의 댐퍼 형태별 환기량 조절능력 평가)

  • Kim, Tae-Hyeong;Ha, Hyun-Chul;Park, Seung-Chul
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.16 no.4
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    • pp.364-374
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    • 2006
  • Natural ventilation technique could be the substitute for or the complement to the local exhaust ventilation system in the sense of protecting work environment. Moreover, it has many strong points ; almost no mechanical parts, no energy use and no noise. If applied appropriately, it could have the very high ventilation rate and save a lot of energy expense. But, it depends on the outdoor environment, especially temperature and wind speed/direction. Predicting the capacity of natural ventilation is not an easy job because it comes from both buoyancy and wind effect. Another problem is too much flow through the ventilator especially in winter time due to too much difference between indoor and outdoor temperature. Thus some ventilators in industries are sealed by door or plastic sheet, resulting in bad work environment. Various types of dampers are used to control the flow rate through ventilators. The capabilities of flow control by damper has not been estimated. In addition, it was not tested whether the damper could obstruct the flow through ventilator when fully opened. To answer these questions, 4 types of dampers were tested by using computational fluid dynamics. 10 different configurations includes no damper, full open and half open. Flow rates were estimated and airflow fields were analysed to clarify the before-mentioned questions. The dual type damper was the best choice for controling the capability of ventilator. In addition, the upward grill type damper was the best for not obstructing the air flow when fully opened.

Built-In-Test Coverage Analysis Considering Failure Mode of Electronics Components (전자부품 고장모드를 고려한 Built-In-Test 성능분석)

  • Seo, Joon-Ho;Ko, Jin-Young;Park, Han-Joon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.43 no.5
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    • pp.449-455
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    • 2015
  • Built-In-Test(hereafter: BIT) is necessary functionality for aircraft flight safety and it requires a high failure detection capacity of more than 95 % in the case of avionics equipment. The BIT coverage analysis is needed to make sure that BIT meets its fault diagnosis capability. FMECA is used a lot of for the BIT coverage analysis. However, in this paper, the BIT coverage analysis based on electronic components is introduced to minimize the analytical error. Further, by applying the failure mode of the electronic components and excluding electronic components that do not affect flight safety, the BIT coverage analysis can be more accurate. Finally, BIT demo was performed and it was confirmed that the performance of the actual BIT matches the analysis of BIT performance.

Adsorption/Desorption Properties of ACF on Toluene and MEK with Operation Condition (공정 조건에 따른 톨루엔 및 MEK에 대한 ACF의 흡·탈착 특성)

  • Baek, Geun-Ho;Kim, Jung-Su;Jang, Hyun-Tae;Cha, Wang-Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.6
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    • pp.2898-2903
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    • 2011
  • Adsorption/desorption characteristics of low concentration methylethylketone(MEK) and toluene vapors in beds packed with activated carbon fibers(ACF) was investigated. Performance of ACF adsorption was characterized by the equilibrium capacity, time to reach equilibrium and desorption efficiency. Experiments were carried out to define the effect of operation variables, such as feed concentration, flow rate, moisture content and bed height. The breakthrough time was shorten with the increase of temperature, flow rate and feed concentration. In addition, an increase of packed height of adsorbents lengthen the breakthrough time. The ACF loaded with MEK and toluene was satisfactorily regenerated by programed heating. It is observed that MEK is more easily removed than toluene at below temperature of $150^{\circ}C$.

Effects of the Mixture of Morphine, Bupivacaine and Antidepressants by Continuous Epidural Infusion in Cancer and Non-cancer Pain (모르핀, 국마제 및 항우울제의 경막외강내 지속혼주의 효과)

  • Shin, Hyung-Chul;Kim, Jung-Soon;Kim, Ill-Ho;Song, Hoo-Bin;Ok, See-Young;Hwang, Kyung-Ho;Park, Wook;Kim, Sung-Yell
    • The Korean Journal of Pain
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    • v.5 no.1
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    • pp.29-36
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    • 1992
  • This study was objected to evaluate clinical progressions about both the degree of pain relief and the occurrence of morphine tolerance while the epidural analgesia with low dose of morphine, bupivacaine and antidepressant continued repeatedly at every 5 day intervals of the constant-rate infusion(0.5 ml/hr, 60 ml capacity). The subjects were divided to 56 cancer and 36 non-cancer patients who failed to respond to palliative treatments. Before the relief of pain, the pain severity was moderate(10%) and severe(90%). The dose escalation of morphine noted to 11(20%)patients in cancer pain and to one(5%) case only in non-cancer. During the epidural analgesia, the effect of pain relief was moderate(11%) and good(89%). It suggest that the morphine tolerance may be reduced to some degree such as an initial minimum dose of epidural morphine with local anesthetic and antidepressant should be adjusted on an individual basis using the constant-rate infusor, even though rapid dose escalation occurrs in some patients who the diseases progress over a short period of time.

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Economic evaluation on heating systems of apartment complex (공동주택단지 난방시스템들에 대한 경제성 평가)

  • 조금남;윤승호;김원배
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.6
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    • pp.773-783
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    • 1998
  • The heating system for apartment complex may be classified as old systems including central system with steam boiler(S1), gas engine driven heat pump system(S2), system using waste heat(S3) and new systems including mechanical vapor re-compression system with flashing heat exchangers(S4), system using methanol(S5), system using metal hydride (S6). The purpose of the present study is to suggest optimal heating system by technically, economically and environmentally evaluating old and new heating systems of apartment complex from 500 to 3,000 households. Economic evaluation based on the technical evaluation results which estimated heat transfer area of heat exchangers and capacity of equipments was estimated initial investment cost, annual operating cost and relative payback period by considering annual increasing rates of energy cost and interest. Environmental evaluation provided annual generation rate of carbon dioxide. Initial investment cost was cheap in the order of S6, S5, S3, S2, S4, S1, annual operating cost was cheap in the order of S1, S2, S4, S5 and relative payback period was short in the order of S6, S5, S2, S3 and S4. Relative payback period was within 8 years for all scenarios of 3,000 households, and was increased as annual increasing rates of energy cost and interest were increased. As transportation pipe length was increased twice, payback period was increased by 1.4~2.6 time. The effect of temperatures of waste gas and waste water on the relative payback period was small within 0.8 years. The annual generation rate of carbon dioxide was big in the order of S4, S2 and S1. S4 was the most economic system among whole scenarios when S1 was replaced with other scenarios.

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Influence of Hypoxic Exercise at Head Down Tilt on Cardiovascular Responses (머리하향기울기 자세에서 운동 중 저산소호흡이 심혈관계반응에 미치는 영향)

  • Kim, Kyong-Tae;Lee, Dae-Taek
    • Aerospace Engineering and Technology
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    • v.8 no.1
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    • pp.207-214
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    • 2009
  • The purpose of this study was to examine the influence of hypoxic exercise at head down tilt (HDT) on cardiovascular responses. Eight men ($23{\pm}2$ yrs, $176{\pm}4$ cm, and $75{\pm}8$ kg) underwent four separate exercise testing sessions; seated normoxia (SN), seated hypoxia (SH), HDT normoxia (HN), and HDT hypoxia (HH). Each participant performed the leg cycling at predetermined 40% of maximal aerobic capacity relevant to each posture for 15 min. Heart rate was higher in SH than SN and higher also in HH than SH (p<0.05). Blood oxygen saturation was lower in SH than SN (p<0.05). During resting, diastolic blood pressure and mean arterial pressure was significantly lower in HDT than seated posture (p<0.05). No differences were found between conditions in hemoglobin and hematocrit and electrolytes including, sodium, potassium, and chloride. Lactate was higher in SH than SN. In conclusion, there was no effect for cardiovascular responses to duplicate stimuli both hypoxia and posture.

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Effect of Gamma Irradiation on Water Uptake Rate and Gelatinization of Brown Rice (감마선 조사가 현미의 수화속도 및 호화양상에 미치는 영향)

  • Lee, You-Seok;Shu, Chung-Sik;Lee, Ju-Woon;Byun, Myung-Woo
    • Korean Journal of Food Science and Technology
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    • v.36 no.6
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    • pp.900-904
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    • 2004
  • Effects of gamma irradiation on brown rice quality were evaluated. Brown rice was irradiated at absorbed dose of 1, 3 or 5 kGy, and ground. Water uptake, pasting properties, and physicochemical characteristics of flour samples were tested. Water uptake rates of irradiated samples were higher than that of control, and were dose-dependent. Hydration capacity decreased in sample irradiated at 5 kGy due to leaching out of soluble compounds, whereas no differences were observed among other irradiated samples and control. Irradiation significantly decreased pasting properties as determined by amylograph. Gamma irradiation accelerated water evaporation at high temperatures (over $300^{\circ}C$) in test of weight-loss profile with thermogravimetric analyzer.