• Title/Summary/Keyword: purge

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Adsorption and Thermal Regeneration of Toluene and Benzene on the Fixed Bed Packed with Activated Carbon and Activated Carbon Fiber

  • Kim, Jong-Hwa;Oh, Ok-Kyun;Haam, Seung-Joo;Lee, Chang-Ha;Kim, Woo-Sik
    • Carbon letters
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    • v.2 no.1
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    • pp.44-54
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    • 2001
  • The characteristics of adsorption and desorption of benzene and toluene were investigated at a fixed bed packed with the activated carbon and activated carbon fiber. Through breakthrough experiments under various feed concentration conditions, it was found that the slope of mass transfer zone and the tailing in the breakthrough curves were different from the feed conditions due to different heats of adsorption. In hot nitrogen desorption, the regeneration time and mass transfer zone of the toluene desorption curve were longer than those of the benzene desorption curve because of the difference in adsorption affinity. With an increase in the regeneration temperature, the height of roll-up and the sharpness of desorption curves increased but the regeneration times decreased. The adsorption capacities of the activated carbon and activated carbon fiber after three-time thermal regenerations decreased about 25% and 37% for benzene and 18% and 25% for toluene, respectively. To investigate the effect of the regeneration temperature on the energetic efficiency, the characteristic desorption temperatures of toluene and benzene were investigated by calculating purge gas consumption and temperature.

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Caspase-dependent and Akt-pathway Regulated Rhus Verniciflua Stokes Extract-induced Apoptosis in Human Breast Carcinoma MDA-MB-231 Cells (인체 유방암세포 MDA-MB-231에서 건칠(乾漆) 추출물이 PI3K/AKT 신호경로를 통한 caspase 의존적 apoptosis 유발에 미치는 영향)

  • Hong, Sang-hoon;Park, Sang-eun
    • The Journal of Internal Korean Medicine
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    • v.38 no.4
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    • pp.409-418
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    • 2017
  • In Korea, Rhus verniciflua Stokes is used to purge hardness, alleviate blood stasis, and treat cancer. However, the mechanisms of related anti-cancer activity are not fully understood in human cancer cells. This study investigated the anti-cancer effects and mechanisms of Rhus verniciflua Stokes on MDA-MB-231 human breast cancer cells and found that treatment with a Rhus verniciflua Stokes extract resulted in time- and concentration-responses that indicated growth inhibition of breast cancer cells by induced apoptosis. This was followed by a decrease in mitochondrial membrane potential; the activation of caspase-3, -8, and -9; and the up-regulation of tBid. Caspase-dependent apoptosis was induced through the inhibition of phosphatidylinositol 3-kinase (PI3K) and the Akt signaling pathway. This study provides evidence that Rhus verniciflua Stokes might be useful for the treatment of breast cancer.

Effects of Packaging Methods on the Meat Quality of ${\alpha}$-Tocopherol Supplemented Broiler Chicks during Refrigerated Storage

  • Ryu, Youn-Chul;Rhee, Min-Suk;Lee, Moo-Ha;Lee, Sung-Ki;Kim, Byoung-Chul
    • Food Science and Biotechnology
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    • v.15 no.2
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    • pp.248-253
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    • 2006
  • This study examined the effects of vacuum packaging and modified atmosphere packaging (MAP) on the meat quality of ${\alpha}$-tocopherol supplemented broiler chicks after prolonged refrigeration. The supplemented ${\alpha}$-tocopherol levels had no effect on the body weight and feed efficiency. The dietary treatments and packaging methods had no significant effects on the level of microbial growth, lightness, and the metmyoglobin content. The vacuum packaging showed the highest level of purge loss. The broilers supplemented with either 200 or 400 IU of ${\alpha}$-tocopherol had a lower level of malondialdehyde than the control group. The vacuum packaged meats from chicks fed the control diet showed the highest levels of lipid oxidation. The lipid oxidative stability was most improved in modified atmosphere (20% $CO_2$ + 80% $N_2$) packaged breast meat from the broilers supplemented with either 200 or 400 IU of ${\alpha}$-tocopheryl acetate.

Experimental Study of Cooling Energy Saving Verification Using Blinds and Phase Change Material(PCM) (창호 블라인드와 상변화물질 적용에 의한 냉방 에너지 사용량 절감효과에 대한 검토 연구)

  • Song, Young-Hak;Kim, Ki-Tae;Koo, Bo-Kyung;Lee, Keon-Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.26 no.1
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    • pp.26-31
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    • 2014
  • This study looks into changing building energy use by application of phase change material (PCM). PCM does not need extra energy for operation and is used for reducing building energy use and, CO2 output by displaying semi-permanent effects after installation. It also is able to avoid the maximum electric power time-zone by inducing a time lag phenomenon of cooling and heating loads with high thermal capacity using latent heat. To verify the efficiency of blinds and PCM, tests about the PCM operation mechanism using air conditioning machinery and nocturnal panel cooling were done. In the test results of the case using PCM installation, a $45^{\circ}$ blind angle with machinery air conditioning and nocturnal panel cooling at the same time shows a 22 percent energy saving effect against general space. The test results of each case were compared and analyzed based on the blind and window opening settings. Finally, the energy reduction of existing buildings using PCM application was reviewed based on the final measurement results.

Heat Effects for the Volatile Organic Compounds emitted from Garlic and Kimchee (열처리가 마늘과 김치에서 발생되는 휘발성 유기화합물에 미치는 영향)

  • 김병순;양성봉
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.615-622
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    • 1998
  • The volatile organic compounds(VOCs) emitted from raw garlic and Kimchee were analyzed with thermal desorption or purge & trap/gas chromatography/mass selective detection method. Very offensive compounds such as methyl allyl sulfide, dimethyl sulfide, dimethyl disulfide, diallyl sulfide, methyl allyl disulfide, diallyl disulfide and dimethyl trisulfide were detected, and among them, dimethyl disulfide and dimethyl trisulfide were confirmed to be generated during the precocity of Kimchee or emitted from the stuff of Kimchee other than the garlic. Malodorous compounds emitted from the garlic or Kimchee were detected in the breath of a Korean and the refregirator keeping Kimchee. It was confirmed that the disufides emitted from the garlic or Kimchee were major components of offensive odor in the alveolar air and the refregirator. It was clarfied that heat process is very effective to reduce odorous VOCs in garlic or Kimchee.

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A Quantitative Analysis on Human Errors in Shifting Hazardous Materials of Semiconductor Plants (반도체공장의 위험물 교체작업시 인적과오에 대한 정량적 분석)

  • 임현교
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.161-168
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    • 1997
  • Most plants producing semiconductors use a lot of chemicals, hazardous materials, and explosive gases. Though those materials are hazardous too much, some works still have to be done manually by human workers. However, according to a historical survey, more than half industrial accidents of those plants resulted from human errors or malfunctions. Thus, this research aimed 1) to diagnose shifting hazardous materials of semiconductor plants, 2) to estimate failure probability of human workers through human reliability analysis, and 3) to find out the tasks on which educational emphasis should be put. Through personal interview and visiting working spots, shifting tasks were analyzed, and modelled into a 24-step work, and after that, THERP and ETA was applied. During the shifting work, estimated human failure probability under the assumption of independency, 2.3004E-05, underestimated that probability 8. l008E-05 which could be calculated under the assumption of dependency. And this analysis showed that gas leakage from an old cylinder occupies 78.27% in the case of independent failures whereas gas leakage from a new cylinder occupies 75.06% in the case of dependent failures. So it was concluded that dependency assumption may gloss real situations. In addition, confirming gauge of regulators and closing valves turned out to be the most important tasks than purge tasks.

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on Applying 3 Slices of Zingiber officinale Roscoe And 2 Pieces of Zizyphus jujuba Mill. (Mainly Oriented Bangyakhappyun) (생강(生薑) 삼편(三片)과 대조(大棗) 이매(二枚)의 사용에 대한 고찰(考察) (방약합편(方藥合編)을 중심으로))

  • Lim, Young-Hwan;Kook, Yoon-Bum
    • Herbal Formula Science
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    • v.14 no.1
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    • pp.1-10
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    • 2006
  • 3 Slices of Zingiber officinale and 2 pieces of Zizyphus jujuba in BangYakHapPyun play a proper role in herbal prescription. Zingiber officinal is roled in protection force(衛) and Zizyphus jujuba is roled in management force(營). 3 Slices of Zingiber officinal and 2 pieces of Zizyphus jujuba in upper location of BangYakHapPyun harmonize management and protection forces(營衛氣). 3 Slices of Zingiber officinale and 2 pieces of Zizyphus jujuba in middle and lower location of BangYakHapPyun compromise and treat inner and outer body condition. 5 or 7 Slices of Zingiber officinale purge noxious vapor and alleviate Pinellia ternata(半夏). Arisaema amurense (南星) poison. Todays, 3-Yangs and 2- Yins an apriority world(先天). use 3 Slices of Zingiber officinale and 2 pieces of Zizyphus jujuba. In the future. 2-Yangs and 3-Yins in a posterior world(後天) may use 2 Slices of Zingiber officinale and 3 pieces of Zizyphus jujuba.

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Characterization of Al2O3 Thin Film Encasulation by Plasma Assisted Spatial ALD Process for Organic Light Emitting Diodes

  • Yong, Sang Heon;Cho, Sung Min;Chung, Ho Kyoon;Chae, Heeyeop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.234.2-234.2
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    • 2014
  • Organic light emitting diode (OLED) is considered as the next generation flat panel displays due to its advantages of low power consumption, fast response time, broad viewing angle and flexibility. For the flexible application, it is essential to develop thin film encapsulation (TFE) to protect oxidation of organic materials from oxidative species such as oxygen and water vapor [1]. In many TFE research, the inorganic film by atomic layer deposition (ALD) process demonstrated a good barrier property. However, extremely low throughput of ALD process is considered as a major weakness for industrial application. Recently, there has been developed a high throughput ALD, called 'spatial ALD' [2]. In spatial ALD, the precursors and reactant gases are supplied continuously in same chamber, but they are separated physically using a purge gas streams to prevent mixing of the precursors and reactant gases. In this study, the $Al_2O_3$ thin film was deposited by spatial ALD process. We characterized various process variables in the spatial ALD such as temperature, scanning speed, and chemical compositions. Water vapor transmission rate (WVTR) was determined by calcium resistance test and less than $10-^3g/m^2{\cdot}day$ was achieved. The samples were analyzed by x-ray photoelectron spectroscopy (XPS) and field emission scanning electron microscope (FE-SEM).

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PEALD과 ALD을 이용한 다공성 기판의 증착 특성 비교

  • Gang, Go-Ru;Cha, Deok-Jun;Kim, Jin-Tae;Yun, Ju-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.155.2-155.2
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    • 2014
  • Plasma Enhanced Atomic Layer Deposition(PEALD)와 Atomic Layer Deposition(ALD) Techniques는 '정확한 두께 조절' 및 '우수한 균일도'를 가지는 신뢰할 수 있는 진공 기술이다. 본 연구에서는 다공성 구조를 가지는 기판을 대상으로 PEALD와 ALD Techniques을 이용한 $Al_2O_3$ 형성 공정의 증착 특성을 비교하였다. 각 공정은 공통적으로 Tris-Methyl-Aluminium(TMA)을 첫번째 전구체로 사용하였고 purge gas로는 Nitrogen를 사용하였다. 그리고 두번째 전구체로 PEALD 공정에서는 Oxygen Plasma를 사용하였고 ALD 공정에서는 Water를 사용하였다. 복잡한 다공성 구조를 가지는 기판은 $TiO_2$ Nano-Particle paste과 colloidal Silver paste를 소결시켜 제작하여 사용하였다. 각 공정의 차이점을 비교하기 위해서 배기단에 Capacitor Diaphram Gauge(CDG)와 Residual Gas Analyzer(RGA)를 통해서 압력과 잔류 가스를 모니터하였다. 그리고 각 공정을 통해서 porous한 Nano-Particles Network에 형성된 $Al_2O_3$막의 특성을 비교하기 위해서 FE-SEM과 EDX를 통해서 관찰하였다. 또한 좀 더 자세한 비교 분석을 위해서 $Al_2O_3$ 막이 형성된 porous한 Nano-Particles Networks의 각 각의 particles들을 분산시켜 TEM과 AFM를 통해서 관찰하였다. 나아가 전기적 물성의 차이점을 비교하기 위해서 IV 및 CV를 측정하였다. 위의 일련의 비교 실험을 통해서 'PEALD과 ALD을 이용한 다공성 기판의 증착 특성'에 대하여 고찰하였다.

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A Study on the Development of Analytical Method for Micro-Odorous Compounds in Water (흡착제를 이용한 수중의 미량 이취물질 분석법 개발에 관한 연구)

  • 김은호;성낙창;최용락
    • Journal of Life Science
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    • v.9 no.5
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    • pp.575-580
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    • 1999
  • Even if odorous compounds remained very low concentration in water, it caused strong odor. Because Geosmin and most of odorous compound had very vaporization, those were difficult to analyze with GC/MSD and Purge & Trap. So, we needed pre-treatment method for decreasing amounts of extracting solvents, improving recovery efficiencies and increasing analytical efficiencies. This study developed efficient technology for analyzing odorous compounds, using various adsorbents and extracting solvents. The optimum adsorbent was XAD resins. Especially, XAD-2, XAD-7 and XAD-2010 were superior, but XAD-2 of these and MTBE was the optimum extraction solvent. Other extraction solvent's efficiency was in order of MTBE>Dichloromethane>n-Hexane>Diethylether. The optimum NaCl dosage for increasing efficiency was 5g in liquid-liquid extraction method. The shaking time(0∼24hr) had no concern with adsorption efficiency. The optimum adsorbent was XAD-2 resin and extraction solvent was MTBE. Dosing NaCl, adsorption efficiency was increased in liquid-liquid extraction method, but NaCl has no effect on liquid-solid extraction method. In this experimental results, this method will apply to not only Geosmin but other well-known odorous compounds (2-MIB, IBMP, IPMP, TCA) and algae toxins (Mycrocystin, Anatoxin etc)

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