• 제목/요약/키워드: pulp strength

검색결과 525건 처리시간 0.024초

극저온용 폴리우레탄 폼에 미치는 케블라 펄프의 영향 (The Effects of Kevlar Pulp on Polyurethane Foam for Cryogenic Temperature)

  • 오종호;배진호;이제명
    • 대한조선학회논문집
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    • 제55권6호
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    • pp.514-520
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    • 2018
  • Polyurethane foam has excellent mechanical strength and insulation performance, and has been adopted as an insulation material for $-163^{\circ}C$ liquefied natural gas carrier. In this study, Kevlar Polyurethane Foams(K-PUF) were synthesized by adding Kevlar pulp with excellent mechanical strength for the purpose of improving the performance of existing polyurethane foam. Since polyurethane foam has mechanical performance depending on the proportions of Kevlar pulp added, the mechanical strength of the K-PUF with ratios of fiber0.2wt.%, 0.4wt.%, 0.6wt.%, 0.8wt.% and 1.0wt.%) was evaluated. The compression tests were performed on the 4 different temperatures($20^{\circ}C$, $-50^{\circ}C$, $-110^{\circ}C$ and $-163^{\circ}C$) in consideration of the environmental characteristics as a cryogenic insulation used in LNG carrier. Besides, the effects of the fiber addition on polyurethane foam with closed cell structure were evaluated in a phenomenological approach through SEM analysis. All the results were compared to Neat-polyurethane foam. As a results, 0.8wt.% K-PUF showed the improved mechanical strength, and the addition of Kevlar pulp in a certain ratio improves the mechanical performance by enhancing the compression resistance.

난연 처리가 종이의 난연성 및 인장강도에 미치는 영향 (Effect of Treatments with Flame-retardant on Flame-resistance and Tensile Strength of Paper)

  • 송한규;이명구
    • 펄프종이기술
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    • 제38권4호
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    • pp.61-67
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    • 2006
  • The effect of several inorganic flame-retardants such as ammonium phosphate, ammonium sulfate, aluminum hydroxide and antimony trioxide on the flame-retardant property and tensile strength of paper has been investigated. Flame-retardants were used preferably as a dry powdered mixture and added to the furnish. Both dipping and coating treatments were employed to apply flame-retardants to paper Flame-retardant paper was manufactured by treatment of $5{\sim}30%$ flame-retardants by weight of the paper on a dry weight. Paper's flame-retardant property and tensile strength were examined by comparison of char length and tensile index. As dosages of flame-retardant chemicals increased, flame-retardant property was improved but tensile index was decreased.

Surface Analysis of Papers Treated with N-chloro-polyacrylamide Using X-ray Photoelectron Spectroscopy: Mechanism of Wet Strength Development

  • Chen Shaoping;Wu Zonghua;Tanaka Hiroo
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 1999년도 Pre-symposium of the 10th ISWPC Recent Advances in Paper Science and Technology
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    • pp.276-281
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    • 1999
  • The surfaces of sheets added with N-chloro-polyacrylamide (N-Cl-PAM) are analyzed using X-ray photoelectron spectroscopy (XPS) to clarify the chemical bonding involved in the paper strength development induced by N-Cl-PAM. The comparison of the observed N1s chemical shift of the sheet with those of the paper strength additives and the model compound, 1-butyryl-3-propyl urea, illustrated the presence of covalent bonds of alkyl acyl urea and urethane on the fiber surfaces. Thus the formation of the covalent bonds by N-Cl-PAM themselves and by N-Cl-PAM with cellulose and hemicellulose may be an explanation for much higher effectiveness of N-Cl-PAM on the improvement of wet strength of paper than A-PAM.

아크릴계 점착제의 박리강도와 점착부여제 (Peel Stength of the Acrylic Copolymer and Pressure Sensitive Adhesives)

  • 김현중
    • 펄프종이기술
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    • 제31권1호
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    • pp.79-88
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    • 1999
  • The stability and performance (peel strength) of the acrylic copolymer and various modified rosin systems were investigated. The peel strength was measured over a wide range of scaling rates, and the influence of the viscoelasticity of the PSA(pressure sensitive adhesive) was considered. In the case of miscible systems, the peak of peel strength (PSA performance) over wide peel rates was changed and modified systematically with increasing glass transition temperature of the blends. The peak of the peel strength for blended systems shifts toward the lower rate side as glass transition temperature ($T_g$) of the blend increased. The influence of esterification of the rosin on performance and stability against deterioration was greatly modified by blending with rosin of glycerol ester and rosin pentaerythritol ester. The failure mode of the blend varies with the combination with acrylic copolymer and modified rosin, and cohesive failure was found at a lower peel rate while interfacial failure was found at a high peel rate. A few systems where a single Tg could be measured, despite the fact that two phases were observed microscopically, were detected.

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Polyvinylamine의 지력증강 특성 연구 (Study of paper Strengthening Properties with Polyvinylamine)

  • 손동진;김봉용
    • 펄프종이기술
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    • 제37권4호통권112호
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    • pp.26-31
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    • 2005
  • The purpose of this study was to confirm paper strengthening properties with recently commercialized polyvinylamine. Because of its high cationic charge density, polyvinylamine has been investigated as a size retention and surface coating aids. In this study, we tried to confirm polyvinylamine as wet-end additives to improve dry and wet strength using LBKP and BCTMP pulps. As a result, we found improvement of dry and wet tensile properties of polyvinylamine with BCTMP were much better than LBKP condition. This phenomena could be explained that ionic bonding of cationic charge of polyvinylamine with abundant anionic substances of BCTMP was a very important factor to improve dry and wet strength of paper.

바인더가 도공층 구조 및 도공지의 표면 강도에 미치는 영향 (Effect of Binder on Coating Layer Structure and Surface Strength of Coated Paper)

  • 이용규;황석우
    • 펄프종이기술
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    • 제30권3호
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    • pp.63-72
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    • 1998
  • This research was intended to evaluate the effect of carboxymethylcellulose(CMC) on the coating structure and surface strength of coated paper prepared with amphoteric latex based coating color. Printability and optical properties of coated papers were compared. The influence of the consolidation behavior of coating color on the coating structure and the surface strength of coated paper was investigated. Compared with the conventional anionic latex, amphoteric latex formed bulkyer, smoother and more porous coating layer, which in turn, restricted binder migration in the coating layers, and facilitated immobilization of coating colors. However, dry pick strength of coated paper was decreased. The addition of CMC to these systems had strongly influenced on. the consolidation behavior and porosity in the dry state, through forming the network structure of coating layers by the interaction with amphoteric latex particles. Thus, printability and optical properties of coated papers were improved. Results indicated that amphoteric latex could be practically applied to the paper coating to improve printability and optical properties of coated papers.

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인쇄용지의 불투명도 향상을 위한 지료조성 (Stock Preparations for the Opacity Improvement of Printing Paper)

  • 최성훈;김봉용
    • 펄프종이기술
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    • 제32권1호
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    • pp.1-9
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    • 2000
  • This study was carried out to improve the opacity of printing paper. Conventional filler loading enhanced the opacity of paper, but subsequently caused reduction of paper strength of paper. We try to seek a new filler loading method so-called beater loading that enhances opacity of paper as well as sustained desire strength. In our experiment, comparing to direct loading method, the beater loading method enhanced 0.8% of opacity and 0.2% of brightness. This also decreased the rates of strength reduction of paper. Therefore, the results obtained in this study indicated that beater loading was a very effective method to improve the opacity of paper while not to decreased so much of paper strength.

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양이온성 고분자 첨가에 따른 섬유의 응집 및 종이 물성 변화 (Fibers Flocculation and Physical Properties Changes of Paper Depending on Cationic Polymer Addition)

  • 윤두훈;박종문
    • 펄프종이기술
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    • 제37권1호
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    • pp.10-16
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    • 2005
  • Flocculation of fibers and its distribution in paper are related to flocculation mechanisms, retention and drainage. Relationship between flocculation mechanisms and physical properties of paper has not been fully studied. In this study, flocculation of fibers was investigated by changing cationic polymers for flocculation mechanism analysis. Flocculation of stock and physical strength of paper were similar when using branched PAM and linear PAM with fillers and microparticles Flocculation and physical strength were also similar when using branched PAM and linear PAM and microparticles without fillers. In that case excessive flocculation was not produced, so formation was improved but physical strength was decreased. When using branched PAM instead of linear PAM with filler addition, drainage time was decreased, air permeability was improved, and physical strength was increased.