• 청정기술
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• 제8권3호
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• pp.167-172
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• 2002

제지슬러지를 지렁이에게 급이하여 생산된 분변토의 하 폐수 고도처리용 담체로의 적용 가능성에 대하여 알아보았다. 먼저 폐수를 일반 활성슬러지법으로 운전한 후 이를 담체와 유입수의 조건을 달리하여 영양 염류의 제거 효율을 알아보았다. 담체를 적용하기 전엔 T-P및 T-N의 제거율은 각각 평균 52%와 31%정도로 나타났다. Pellet 형 및 pack 형으로 제조된 두 종류의 분변토 담체를 적용한 후에는 T-P의 경우는 제거효율이 약 1.3~1.4배 증가하였으며 T-N의 제거효율은 약 1.9 ~ 2.0 배 증가하여 상당히 뛰어난 영양염류의 제거 효율을 보여주었다. 또한, T-N 및 T-P의 제거효율은 담체의 종류에는 큰 영향을 받지 않아 다양한 미생물이 서식하는 분변토는 성형 방법에 관계없이 뛰어난 성능을 보임을 알 수 있었다. 반면, 담체 적용 전후의 BOD 및 COD의 제거 효율은 큰 차이가 없었다. 본 연구를 통하여 분변토로 제조된 담체는 하 폐수 고도처리용 담체로의 활용 가능성이 매우 높은 것으로 사료된다.

• 기술사
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• 제18권3호
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• pp.28-35
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• 1985

As the paper industry consumes much water in process and discharge wastewater containing suspended solid and COD(chemical oxygen demand), relevant law against this discharge has been set up to limit the total containment of COD in discharge. This study has been carried out to improve the treatment method for the soluble COD in wastewater produced during the process of paste-board production, which is made of semichemical pulp and waste paper. Applicated methods are, O$_2$AS : O$_2$ activated sludge process DAS : Deep well activated sludge process SAS : standard activated sludge process and proper combination of DAS and SAS 1) As a result of this experiment, we get the following conclusion between in COD sludge loading "X" and COD removable rate in the process of treating waste-water. COD removable rate(％)=(0.778+0.0146/X)${\times}$100(％)……(7) 2) In case that the COD sludge loading is high, it has been cleared out that the COD removable rate shall become low due to unknown unsoluble substances contained in the process. Meanwhile, to increase the efficiency rate of treatment, it is thought to be necessary, to provide long-time contacts with activated sludge. 3) Once the COD of original waste-water and the target COD of treated water are decided, COD sludge loading is obtained from equation(7), and capacity of aeration tank in the effective systems such as O$_2$AS, DAS, to bet the required COD removable rate can be decided. Therefore the choice among SAS, O$_2$AS, DAS methods is made in consideration of required COD removable rate and allowable installation area. 4) In the sedimentation tank with sludge bulking, it is possible to increase the COD removable rate by 3～7％ but still there exist many obstacles to manage this operation.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 가을 학술발표회 논문집
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• pp.75-79
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• 1995

The results of an experimental study on the manufacture and the mechanical properties of fiber reinforced calcium silicates-cement composites utilizing by products (fly ash or cement sludge) for construction materials are presented in this paper. As the test results show, compressive, tensile, and flexural strength, fracture toughness of fiber reinforced calcium silicates-cement composites were improved by increasing the fly ash and fiber contents, but were decreased by increasing cement sludge contents. Somehat, especially increasing fiber contents the fracture toughness of the composites were remarkably increased. Also, the mechanical properties of the composites reinforcing alkali-resistance GF were higher than those of the composites reinforcing Samoa Pulp.

• 펄프종이기술
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• 제46권2호
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• pp.30-34
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• 2014

To apply paper mill sludges to soil as fertilizer, paper mill sludges were investigated to predict suitability and maleficence for soil. Newspaper and Printed Paper sludge were analyzed by IC (Ion Chromatography) and ICP-OES (Induced Coupled Plasma Optical Emission Spectrometer). As a results, harmful materials in two types of sludges were below standard by notified Ministy of Environment (ME). Also ionic substances causing the water pollution in sludges were less than the standard value by notified ME. Thus sludges from newspaper and printed paper is presumed that there are no water pollution and soil contamination.

• Environmental Engineering Research
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• 제25권3호
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• pp.400-408
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• 2020

Hydrodynamic study of Activated Sludge Process (ASP) is important to optimize the reactor performance and detect anomalies in the system. Residence time distribution (RTD) study has been performed using LiCl as tracer on a pilot scale aeration tank (AT) and ASP, treating the pulp and paper mill effluent. The hydraulic performance and treatment efficiency of the AT and ASP at different operating parameters like residence time, recycle rate was investigated. Flow anomalies were identified and based on the experimental data empirical models was suggested to interpret the hydrodynamics of the reactors using compartment modelling technique. The analysis of the RTD curves and the compartment models indicated increase in back-mixing ratio as the mean hydraulic retention time (MHRT) of the tank was increased. Bypassing stream was observed at lower MHRT. The fraction of dead zone in the tank increased by approximate 20-25% with increase in recycle rate. The fraction of the stagnant zone was found well below 5% for all performed experiments, which was under experimental error. The substrate removal of 91% for Chemical oxygen demand and 96% for Biochemical oxygen demand were observed for the ASP working at a hydraulic mean residence time 39 h MRT with a 20% recycling of activated sludge.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.421-426
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• 2001

The pneumatic classification and acidic leaching behaviors of phosphor sludge have been examined to establish the recycling system of rare earth components contained in waste fluorescent lamp. At first, separation characteristic of rare earth components and calcium phosphate in phosphor sludge was investigated by pneumatic classification. After pneumatic classification of phosphor sludge, rare earth components were leached in various acidic solutions and sodium hydroxide solution. For recovery of soluble component in leaching solution, rare earth components were separated as hydroxide and oxalate precipitations. The experimental results obtained are summarized as follows: (1) In classification process, rare earth components in phosphor sludge were concentrated to 29.3% from 13.3%, and its yield was 32.9%. (2) In leaching process, sulfuric acid solution was more effective one as a leaching solvent of rare earth component than other solutions. Y and Eu components in phosphor sludge were dissolved in sulfuric acid solution of 1.5 k㏖/㎥, and other rare earth components were rarely dissolved in leaching solution. Leaching degrees of Y and Eu were respectively 92% and 98% in the following optimum leaching conditions; sulfuric acid concentration is 1.5 k㏖/㎥ , leaching temperature 343 K, leaching time 3.6 ks and pulp concentration 30 kg/㎥. (3) Y and Eu components of phosphor sludge contained in waste fluorescent lamp were, effectively recovered by three processes of pneumatic classification, sulfuric acid leaching and oxalate precipitation methods. Their recovery was finally about 65 %, and its purity was 98.2%.

• 자원리싸이클링
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• 제3권3호
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• pp.32-49
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• 1994

포항제철소에서 발생되는 석회석슬러지의 기본탄산계 특성중의 일부분인 수화반응 연구를 수행하여 다음과 같은 결과를 얻었다. 1. 석회석슬러지는 광물조성상 calcite이며 고품위(CaO 51%) 미분말(15~22$\mu\textrm{m}$) 석회석으로 보통탄산칼슘 영역 (-3mm + 325mesh)에 속하는 것으로 분류되었다. 2. 석회석슬러지는 수세슬러지와 소성로 습식집진 dust의 혼합슬러지이며 약 8:2의 비율로 구성되어 있다. 수차례 시료채취한 소성로 습식집진 dust는 전형적인 calciteduTdmsk 실조업에서는 일부 열분해 시작한 quick lime과 다시 집진수와 수화된 slaked lime의 혼재가 예상되므로 두 공정 슬러지의 분리로 석회석슬러지의 품위를 향상시킬 수 있다. 3. 석회석슬러지를 소성, 수화하여 제조된 slaked lime의 각종 수화반응기 종류별에 변화에 대해 검토하였다. 일반적인 기계적인 교반기인 magnetic stirrer의 shaking incubator, ultrasonic vibration reactor을 비교 검토한 결과 ultrasonic vibration reactor에서 격렬하지 않은 수화반응과 타반응기 보다 미세한 분체생성 및 균일한 입도분포의 특징을 갖고 있었다. 4. Ultrasonic vibration reactor에서 미분말의 slaked limetod성에 최적인 광액 농도는 10wt%이하였으며, 수화완료 시간도 5~10분으로 타반응기 보다 짧았다. 5. 석회석슬러지는 천연산 석회석을 원료로 한 경우 10~20$\mu\textrm{m}$의 불균질 slaked lime 분체를 생성에 반해 석회석슬러지는 균일한 1~5$\mu\textrm{m}$ 분체를 생성하였다.

• 청정기술
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• 제15권3호
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• pp.154-164
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• 2009

2007년을 기준으로 울산에 위치한 사업장으로부터 발생된 유기성 폐수슬러지의 94%가 해양처분되었다. 유기성 슬러지의 해양처분은 2012년에는 완전 금지될 예정이다. 그러나 아직까지 울산에 위치한 사업장으로 부터의 유기성 슬러지는 소각 이외에 다른 대안이 없는 실정이며, 현재 울산석유화학산업단지의 사업장들은 슬러지의 육상처리 및 처분기술의 확보가 매우 중요한 과제이다. 본 연구에서는 울산의 석유화학사업장 슬러지와 하수처리 슬러지를 연료로 활용하기 위해 건조슬러지와 탄화슬러지의 재료적 측면에 대한 평가를 실시하였다. 연구결과 저위발열량 3,000 kcal/kg이상을 초과하는 테레프탈산, BTX, 프로필렌, 화학섬유 등을 생산하는 사업장으로부터의 건조슬러지와 탄화슬러지는 연료로서의 가능성이 높지만 건조할 경우 2,100 kcal/kg 이하, 탄화할 경우 1,100 kcal/kg 이하인 좀 더 무기성분이 많은 펄프, 제지, 메틸아민, 아마이드 등을 생산하는 사업장의 폐수슬러지는 연료로서의 가치가 적은 것으로 나타났다. 연구결과 대부분의 슬러지들이 에너지 측면에 있어서 탄화보다는 건조가 더 좋은 결과를 보여주었다.

• 펄프종이기술
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• 제40권1호
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• pp.41-46
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• 2008

In this study, dewaterability, one of the important properties of wastewater sludge, was investigated using a simple capillary suction time (CST) measurement method. It turned out that one could use the results of CST to find optimum flocculants ratio to improve drainage in wastewater treatment for the printing paper, tissue paper, and newsprint paper mill. Since the optimum ratio of flocculants could be determined with the value of CST, COD removal efficiency could be improved and optimum floc strength could be achieved with precise ratio of flocculants. It was thus that using CST for determining the optimum ratio of flocculants could be economical by reducing the amount of flocculants. Dewaterability could be measured within several seconds using the values of CST in a precise way. The dewaterability could also be useful in investigating the optimum ratio of flocculants.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.441-444
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• 2006

A lot of water is using in the paper mill for dilution, washing, sealing, and other process operation. As the regulation of water environment has been more tightened than ever before, water management in the paper mill becomes the most important task. Topics on reducing fresh water and increasing recycling water have been studied. Further, an interest in zero-effluent system has been increased. The pH of waste water in paper mill is usually weak acidic or neutral. The waste water in the paper mill includes water insoluble organic materials that are not easy to be dissolved in the water, inorganic materials that never react with water and chemical additives that are used to recycled fiber. This study investigated on the effect of various materials used in paper mill on COD. This data could be used to control the environmental load in paper mill. COD caused by raw materials and NBDCOD (Non Bio Degradable COD) after the activated sludge process are investigated in this study. Results obtained in this study can be used in a simulation program designed to control environmental load in the paper mill.