• Title/Summary/Keyword: pseudo order

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Hydrolysis of p-Nitrophenyl Carboxylic Ester in N,N-Dimethyl-N-dodecyl-N-(2-methylbenzimidazoyl) Ammonium Chloride Micellar Solution (N,N-Dimethyl-N-Dodecyl-N-(2-methylbenzimidazoyl) Ammonium Chloride 미셀 용액속에서 p-Nitrophenyl Carboxylic Ester의 가수분해)

  • Kim, Jeung-Bea;Kim, Hak-Yoon
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.509-516
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    • 2008
  • New functional surfactant, N,N-dimethyl-N-dodecyl-N-(2-methyl benzimidazoyl) ammonium chloride(DDBAC) having benzimidazole(BI) functional group have been synthesized and the critical micellar concentration of DDBAC measured by surface tentiometry and electric conductivity method was $8.9{\times}10^{-4}M$. Micellar effects in DDBAC functional surfactant solution on the hydrolysis of p-nitrophenylacetate(p-NPA), p-nitro-phenylpropionate(p-NPP) and p-nitrophenylvalerate(p-NPV) were observed with change of various pH (Tris-buffer). The pseudo first rate constants of hydrolysis of p-NPA, p-NPP and p-NPV in optimum concentration of DDBAC solution increase to about 160, 280 and 600 times, respectively, as compared with those of aqueous solution at pH 8.00(Tris-buffer). It is considered that benzimidazole functional moiety accelerates the reaction rates of hydrolysis because they act as nucleophile or general base. In optimum concentration of DDBAC solution, the rate constants of hydrolysis of p-NPP and p-NPV increase to about 1.5 and 3.0 times, respectively, as compared with that of p-NPA. It means that the more the carbon numbers of alkyl group of substrates, the larger the binding constants between DDBAC micelle and substrates are. To know the hydrolysis mechanism of p-NPCE(p-NPA, p-NPP and p-NPV), the deuterium kinetic isotope effects were measured in $D_2O$ solutions. Consequently the pseudo first order rate constant ratios in $H_2O$ and $D_2O$ solution, $k_{H_2O}/k_{D_2O}$, were about $2.8{\sim}3.0$ range. It means that the mechanism of hydrolysis were proceeded by nucleophile and general base attack in approximately same value.

Color Transfer Method Based on Separation of Saturation (채색 분리 기반의 색 변환 기법)

  • Kwak, Jung-Min;Kim, Jae-Hyup;Moon, Young-Shik
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.45 no.3
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    • pp.149-159
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    • 2008
  • We present new methods which transfer the color style of a source image into an arbitrary given reference image. Misidentification problem of color cause wrong indexing in low saturation. Therefore, the proposed method do indexing after Image separating chromatic and achromatic color from saturation. The proposed method is composed of the following four steps : In the first step, Image separate chromatic and achromatic color from saturation using threshold. In the second step, image of separation do indexing using cylindrical metric. In the third step, the number and positional dispersion of pixel decide the order of priority for each index color. And average and standard deviation of each index color be calculated. In the final step, color be transferred in Lab color space, and post processing to removal noise and pseudo-contour. Experimental results show that the proposed method is effective on indexing and color transfer.

Hetero-core Spliced Fiber Optical Sensing System for an Environment Monitoring (구조물 모니터링을 위한 헤테로 코어형 광센싱 시스템)

  • Kim, Young-Bok;Lee, Kwon-Soon;Watanabe, Kazuhiro;Sasaki, Hiroyuki;Choi, Yong-Woon
    • Journal of Ocean Engineering and Technology
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    • v.21 no.3 s.76
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    • pp.46-51
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    • 2007
  • A multi-purpose environmental monitoring system has been developed as a commercially available standard using the technique of hetero-core spliced fiber optic sensors, for the purposes of monitoring large-scale structures and preserving natural environments. The monitoring system has been tested and evaluated in a possible outdoor condition, in view of the full-scale operation at actual sites to be monitored. Additionally, the developed system in this work conveniently provides us with various options of sensor modules intended for monitoring such physical quantities as displacement, distortion, pressure, binary states, and liquid adhesion. Two channels of optical fiber line were monitored in each channel, three displacement sensor modules were connected in series, in order to examine the performance to a pseudo-cracking experiment in the outdoor situation and to clarify temperature influences an the system, in terms of the coupling of optical connectors and the OTDR stability. The results from the pseudo-cracking experiment agreed with the actual cracks, by means of calculation, based an the detected displacement values and their geometrical arrangement of the used sensor modules. The temperature change, ranging from 10 to $20^{\circ}C$ resulting from the 10-days free running operation, was found to influence the system stability of ${\pm}10{\mu}m$, primarily due to the coupling instability of the used optical connectors. It was found that fusion splicing, rather than the use of connectors, reduced the fluctuation dawn to ${\pm}2{\mu}m$. The specification and performance of various option modules have been demonstrated to show the capability of inspecting various physical quantities by use of the single system, which would be suitable for multi-purpose environmental monitoring.

Prediction on the Effect of Multi-Constellation SBAS by the Application of SDCM in Korea and Its Performance Evaluation (SDCM의 국내 적용 및 성능 평가를 통한 다중 위성군 SBAS의 효과 예측)

  • Lim, Cheol-soon;Seok, Hyo-jeong;Hwang, Ho-yon;Park, Byungwoon
    • Journal of Advanced Navigation Technology
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    • v.20 no.5
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    • pp.417-424
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    • 2016
  • Russia recently began broadcasting the SDCM signal in order to provide SBAS service for the civil aviation in the Russian territory using its own geostationary satellites. The service coverage of the SDCM geostationary satellite, LUCH-5A and LUCH-5B, includes Korea peninsula, where the test signal from the pseudo random number (PRN) 140 is received. This paper shows that the position accuracy at the Chulwon GNSS site is improved to 0.8749 m (horizontal) and 0.9589 mm (vertical) by applying the received SDCM message to the RINEX data. Considering that the SDCM augments both GPS and GLONASS, the performance of multi-constellation SBAS was compared to that of GPS-only SBAS, and APV-I availability was improved by decreasing the protection level about 30 %. From the results, we can expect that the mult-constellation SBAS can contribute to the performance enhancement of the future KASS.

A Design of a Robust Vector Quantizer for Wavelet Transformed Images (웨이브렛벤환 영상 부호화용 범용 벡터양자화기의 설계)

  • Do, Jae-Su;Cho, Young-Suk
    • Convergence Security Journal
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    • v.6 no.4
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    • pp.83-90
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    • 2006
  • In this paper, we propose a new design method for a robust vector quantizer that is independent of the statistical characteristics of input images in the wavelet transformed image coding. The conventional vector quantizers have failed to get quality coding results because of the different statistical properties between the image to be quantized and the training sequence for a codebook of the vector quantizer. Therefore, in order to solve this problem, we used a pseudo image as a training sequence to generate a codebook of the vector quantizer; the pseudo image is created by adding correlation coefficient and edge components to uniformly distributed random numbers. We will clearly define the problem of the conventional vector quantizers, which use real images as a training sequence to generate a codebook used, by comparing the conventional methods with the proposed through computer simulation. Also, we will show the proposed vector quantizer yields better coding results.

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Rocking behavior of bridge piers with spread footings under cyclic loading and earthquake excitation

  • Hung, Hsiao-Hui;Liu, Kuang-Yen;Chang, Kuo-Chun
    • Earthquakes and Structures
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    • v.7 no.6
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    • pp.1001-1024
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    • 2014
  • The size of spread footings was found to be unnecessarily large from some actual engineering practices constructed in Taiwan, due to the strict design provisions related to footing uplift. According to the earlier design code in Taiwan, the footing uplift involving separation of footing from subsoil was permitted to be only up to one-half of the foundation base area, as the applied moment reaches the value of plastic moment capacity of the column. The reason for this provision was that rocking of spread footings was not a favorable mechanism. However, recent research has indicated that rocking itself may not be detrimental to seismic performance and, in fact, may act as a form of seismic isolation mechanism. In order to clarify the effects of the relative strength between column and foundation on the rocking behavior of a column, six circular reinforced concrete (RC) columns were designed and constructed and a series of rocking experiments were performed. During the tests, columns rested on a rubber pad to allow rocking to take place. Experimental variables included the dimensions of the footings, the strength and ductility capacity of the columns and the intensity of the applied earthquake. Experimental data for the six circular RC columns subjected to quasi-static and pseudo-dynamic loading are presented. Results of each cyclic loading test are compared against the benchmark test with fixed-base conditions. By comparing the experimental responses of the specimens with different design details, a key parameter of rocking behavior related to footing size and column strength is identified. For a properly designed column with the parameter higher than 1, the beneficial effects of rocking in reducing ductility and the strength demand of columns is verified.

Ecological Characteristics of Phytoplankton Communities in the Coastal Waters of Gori, Wolseong, Uljin and Younggwang Ⅲ. Distribution of Dominant Species and Environmental Variables (고리, 월성, 울진과 영광 연안해역에서 식물플랑크톤 군집의 생태학적 특성 Ⅲ. 우점종 분포와 환경요인들)

  • Gang, Yeon Sik;Choe, Jung Gi;Eom, Hui Mun
    • ALGAE
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    • v.18 no.1
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    • pp.29-47
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    • 2003
  • In order to investigate the distribution of dominant phytoplankton species in the coastal waters of Gori, Wolseong, Uljin and Younggwang, the standing crops of dominant species were studied during 1992-1996 and the relationships between standing crops and environmental variables were analyzed.The standing crops of diatom Skeletonema costatum, Thalassiosira decipiens, Chaetoceros debilis, Pseudo-nitzchia seriata, Paralia sulcata and dinoflgaellate Prorocentrum triestinum were on average from 16,373 to 118,549 cellso$l^{-1}$, from 11,180 to 210,313 cellso$l^{-1}$, from 23,341 to 55,889 cellso$l^{-1}$, from 6,784 to 15,766 cellso$l^{-1}$, from 342 to 41,596 cellso$l^{-1}$ and from 4,828 to 22,397 cellso$l^{-1}$ in the four study areas, respectively. The standing crops of Skeletonema costatum, Thalassiosira decipiens and Paralia sulcata were higher in Younggwang, while Chaetoceros debilis, Pseudo-nitzschia seriata and Prorocentrum triestinum were higher in Wolseong than other areas. The standing crops of silicoflgaellate Distephanus speculum were from 157 to 4,239 cellso$l^{-1}$ in the four study areas, showing an tendency increasing in Uljin. The abundance rates of Skeletonema costatum, Thalassiosira decipiens and Chaetoceros debilis were from 7.04 to 15.74%, from 6.95 to 33.69% and from 5.17 to 13.88% in the four study areas, respectivelyThe results of correlation coefficient between standing crops of dominant species and environmental variables show that phosphates were related with the distribution of dominant species in Gori, Uljin and Younggwang, while nitrogen compounds affected the distribution of dominant species in Wolseong. In addition, salinity and temperature affected the distribution of dominant species in Wolseong and Younggwang, respectively.

Adsorption Equilibrium, Kinetic and Thermodynamic Param (활성탄을 이용한 Acid Green 27의 흡착평형, 동역학 및 열역학 파라미터의 연구)

  • Lee, Jong Jib
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.514-519
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    • 2017
  • Adsorption characteristics of acid green 27 dye using activated carbon were investigated as function of adsorbent dose, pH, initial concentration, contact time and temperature. Freundlich isotherm explained adsorption of acid green 27 dye very well and Freundlich separation factors (1/n=0.293~0.387) were found that this process could be employed as effective treatment method. Kinetic studies showed that the kinetic data were well described by the pseudo second-order kinetic model. Pseudo second rate constant ($k_2$) decreased with the increase in initial acid green 27 concentration. Activation energy (10.457 kJ/mol) and enthalpy (79.946 kJ/mol) indicated that adsorption process was physisorption and endothermic. Since Gibbs free energy decreased with increasing temperature, spontaneity of adsorption reaction increased with increasing temperature in the temperature range of 298 K~318 K.

A Design and Implementation of GNSS Pseudo Range Generation Simulator (GNSS 의사거리 생성 시뮬레이터 설계 및 구현)

  • Yu, Dong-Hui
    • Journal of the Institute of Convergence Signal Processing
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    • v.12 no.4
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    • pp.286-290
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    • 2011
  • LBS(Location Based System) is the essential technology of ubiquitous market and utilizes the GNSS(Global Navigation Satellite). GNSS includes GPS of USA, Galileo of Europe Union, QZSS of Japan, Compass of China, and IRNSS of India. Related researches have recently been conducted. Once the satellite is launched, the maintenance such as modification and verification of its function is difficult. Therefore, before the launch of satellites, more precise and concrete verification of performance and operations are needed. In order to do this, hardware testbed may be developed. but software simulators can provide more flexible and cost effective simulation results. These simulators should provide the essential function handling all kinds of error features experienced upon propagation of the GNSS signal. In this paper, we present a design and implementation results of a window-based simulator applying the modeling of various error features for several GNSS.

Numerical Study on the Inlet Head Configuration of Multi-Phase Separator for Modularization (다상유동 분리기 모듈화를 위한 유입구 형상 설계에 관한 수치해석적 연구)

  • Hong, Chang-Ki;Kim, Youn-Jea
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.9
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    • pp.571-577
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    • 2017
  • In this numerical study, the separation efficiency of three-phase separator in an oil-sand plant was studied with various inlet head configurations. The free water knockout (FWKO) vessel was designed with a flow rate of $15.89m^3/day$ (100 bbl/day) and the SOR(stream-to-oil ratio)=3.5 was derived using Stokes' law. For modularization, optimization of the design of the inlet head configuration was performed with parallel-connected dual FWKO vessels. The feed condition of bitumen emulsion was API=17, $T_{in}=150^{\circ}C$ and $P_{in}=50bar$. A mean residence time was determined the time when 95% of the oil and water in FWKO vessel was separated. The combination between the volume of fluid (VOF) and the discrete phase model (DPM) was used to simulate the phase separation phenomenon in a multi-phase separator. Furthermore, in order to calculate multi-phase flow the pseudo-transient method was adopted.