• Bulletin of the Korean Chemical Society
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• v.25 no.9
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• pp.1346-1350
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• 2004

Pseudo-first order rate constants $(k_{obs})$ are reported for the following solvolyses in approximately isodielectric mixtures: 3- and 4-methoxybenzyl chloride, bromo- and chlorodiphenylmethane, and 4-chloro-, 4,4'-dichloro and 4-methyl-chlorodiphenylmethane in 0-80% v/v nitromethane-methanol mixtures; and bromo- and chlorodiphenylmethane and 4-methyl-chlorodiphenylmethane in various acetonitrile-methanol mixtures (in the range 0-50% v/v) at$25^{\circ}C.$ These data, and literature data for t-butyl halides (Cl, Br, and I), and for p-methoxybenzoyl chloride, show rate maxima in solvent compositions of ca. 30% aprotic cosolvent, explained by a stoichiometric solvent effect on electrophilic solvation. Linear relationships are observed between $(k_{obs})/[MeOH]^2$ and [AP]/[MeOH], where [AP] refers to the molar concentration of aprotic cosolvent. The results are consistent with competing third order contributions to $k_{obs}$, $k_{MM}[MeOH]^2$ with hydrogen-bonded methanol as electrophile, and $k_{MAP}[MeOH][AP]$ with hydrogen-bonding disrupted by the aprotic solvent.

• The Transactions of the Korean Institute of Electrical Engineers D
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• v.55 no.1
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• pp.20-23
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• 2006

This paper presents a new approach to the problem of designing a cascaded three-parameters controller for a given linear time invariant (LTI) plant in unity feedback system. We consider a proportional-integral-derivative (PID) and a first-order controller with the specified overshoot and settling time. This problem is difficult to solve because there may be no analytical solution due to the use of low-order controller. Furthermore, the zeros of controller just appear in the zeros of feedback system. The key idea of our method is to impose a constraint on the controller parameters so that the zeros of resulting controller are distant from the dominant pole of closed-loop system to the left as far as the given interval. Two methods realizing the idea are suggested. We have employed the characteristic ratio assignment (CRA) in order to deal with the time response specifications. It is noted that the proposed methods are accomplished only in parameter space. Several illustrative examples are given.

• The Transactions of the Korea Information Processing Society
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• v.6 no.3
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• pp.781-791
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• 1999

DD(Decision Diagrams) is an efficient operational data structure for an optimal expression of boolean functions. In a graph-based synthesis using DD, the goal of optimization decreases representation space for boolean functions. This paper represents boolean functions using OPKFDD(Ordered Pseudo-Kronecker Functional Decision Diagrams) for a graph-based synthesis and is based on the number of nodes as the criterion of DD size. For a property of OPKFDD that is able to select one of different decomposition types for each node, OPKFDD is variable in its size by the decomposition types selection of each node and input variable order. This paper proposes a method for generating OPKFDD efficiently from the current BDD(Binary Decision Diagram) Data structure and an algorithm for minimizing one. In the multiple output functions, the relations of each function affect the number of nodes of OPKFDD. Therefore this paper proposes a method to decide the input variable order considering the above cases. Experimental results of comparing with the current representation methods and the reordering methods for deciding input variable order are shown.

• Bulletin of the Korean Chemical Society
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• v.22 no.7
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• pp.669-672
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• 2001

Pseudo-first-order rate constants have been measured spectrophotometrically for the title reactions. The plot of kobs vs the concentration of alkali metal ethoxides is linear for the reactions performed in the presence of complexing age nt, 18-crown-6 ether, but curved upwardly for the corresponding reactions performed in the absence of the complexing agent, indicating that the alkali metal ions studied in this study behave as a catalyst. The catalytic effect was found to increase in the order Li+ << K+ ${\leq}$ Na+. Second-order rate constants were determined for the reactions with dissociated free ethoxide (kEtO-) and with ion paired alkali metal ethoxides (kEtO-M+ ) from ion pairing treatments. The magnitude of catalytic effect (kEtO-M+/kEtO-) was found to be 2.3, 9.5 and 8.7 for the reaction of 8-(5-nitroquinolyl) 2-furoate, while 1.4, 3.6 and 4.2 for that of 4-nitrophenyl 2-furoate, indicating that the catalytic effect is larger in the reaction of the former substrate than in that of the latter one. The larger catalytic effect was attributed to two possible complexing sites with alkali metal ions in the former substrate.

• Applied Chemistry for Engineering
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• v.29 no.3
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• pp.356-361
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• 2018

It is common to analyze volatile organic compound (VOC) or semi-VOC (SVOC) in a sample composed of a complex matrix consisting of multiple components such as bloods through a separation process. Adsorption is a physical phenomenon in which certain components accumulate on the surface of other phases. In order to overcome difficulties in the pretreatment process, an adsorption is frequently used. Solid phase microextraction (SPME) equipment with porous carbon carboxen (CAR) is an example of adsorption application. In this study, the adsorption of 4-octylphenol to carboxen was examined. To do so, the extraction efficiency for such solvents as dichloromethane ($CH_2Cl_2$, DCM), ethylacetate ($CH_3COOC_2H_5$, EA) and diethylether ($C_2H_5OC_2H_5$, $Et_2O$) was studied and also the derivatization reaction for 4-octylphenol with reagents of bistrimethylsilyltrifluoroacetamide (BSTFA), methylchloroformate (MCF) and pentafluorobenzylbromide (PFBBr) was compared. The combination of DCM and BSTFA showed good performance thus they were adopted for this study. Thermodynamic adsorption experiments showed that the adsorption process was endothermic and Freundlich isotherm equation was more suitable than Langmuir isotherm. It was also found that the adsorption followed a pseudo-$2^{nd}$ order kinetic model.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.6
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• pp.642-650
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• 2005

This research investigates the effects of adding oxidants such as $Fe^0$, $Fe^{2+}$, and ${S_2O_8}^{2-}$ in the sonolysis of 1,4-D. Results indicate that the degradation could be divided into two steps (initiation and acceleration) kinetically. The initial portion agreed with zero-order expression, while the second portion could be fitted with pseudo first-order expression. In the presence of ${HCO_3}^-$, as a radical scavenger, the degradations of 1,4-D and TOC were suppressed, indicating that OH radical is an important factor in the sonolysis. The overall degradation efficiency of 79.0% in the sonolysis was achieved within 200 minutes. While $Fe^0$, $Fe^{2+}$, and ${S_2O_8}^{2-}$ were individually combined with sonication, the degradation efficiency of 1,4-D increased 18.6%, 19.1%, and 16.5% after 200 min, respectively. The addition of oxidants not only changed the kinetic model from zero to pseudo first order at initiation step, but also increased the rate constants in the acceleration step. The addition of oxidants in the sonolysis of 1,4-D also improved the mineralization of 1,4-D, however, the effect of adding oxidants on the rate increase was similar regardless of the oxidants.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.6
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• pp.663-669
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• 2005

The aim of this study was to investigate the ozone decay pattern for the effective application of ozone in drinking water treatment. In order to measure the ozone decomposition in water, ozone measuring instrument was developed with flow injection analysis (FIA) method. From the result of continuous residual ozone concentration in water, it was confirmed that the ozone decay pattern was divided with instantaneous ozone demand(I.D) and pseudo first-order rate($k_c$) phases, which were influenced by the variation of ozone dose. The empirical model obtained from I.D and $k_c$ values enabled us to predict the residual ozone concentration according to the reaction time, showing the high correlation between model and experimental values. The concentration of OH radical and $R__{ct}$ could be indirectly measured by OH radical probe compound. In both I.D and $k_c$ phases, the production pattern of OH radical could be observed, which was also affected by the variation of ozone dose. Finally, it was confirmed that the ozone consumption rate was varied according to the each drinking water treatment process and seasoning. Therefore, the optimum position and dosage of ozone have to be selected by considering various factors.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.3
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• pp.195-203
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• 2012

In this study, The effects of three different biological activated carbon (BAC) materials (each coal, coconut and wood based activated carbons) and anthracite, empty bed contact time (EBCT) and water temperature on the removal of MK, HHCB and AHTN in BAC filters were investigated. Experiments were conducted at three water temperatures (5, 15 and $25^{\circ}C$) and four EBCTs (5, 10, 15 and 20 min). The results indicated that coal based BAC retained more attached bacterial biomass on the surface of the activated carbon than the other BAC, increasing EBCT or increasing water temperature increased the synthetic musk compounds (SMCs) removal in BAC columns. The kinetic analysis suggested a first-order reaction model for MK, HHCB and AHTN removal at various water temperatures (5, 15 and $25^{\circ}C$). The pseudo-first-order biodegradation rate constants and half-lives were also calculated for MK, HHCB and AHTN removal at 5, 15 and $25^{\circ}C$. The pseudo-first-order biodegradation rate constants and half-lives of MK, HHCB and AHTN ranging from 0.0082 $min^{-1}$ to 0.4452 $min^{-1}$ and from 1.56 min to 84.51 min could be used to assist water utilities in designing and operating BAC filters for SMCs removal.

• The Journal of the Acoustical Society of Korea
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• v.39 no.1
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• pp.8-15
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• 2020

In this paper, we propose a frame synchronization algorithm for robust to the combined effects of large Doppler fluctuations and extended, time-varying multipath in the underwater acoustic communication. From the algorithm, we can recover a high timing error which is occurred from an acoustic propagation delay and uncertainty of oscillator between transmitter and receiver. In order to verify the performance of the synchronization algorithm, the lake trial results are used. The lake experiments are performed in a Gyeongcheonho located in Mungyeong-si, Gyeongsangbuk-do. We can see that the start position of frame is adjusted after the frame synchronization while the receiver moving.

• Journal of Ocean Engineering and Technology
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• v.17 no.5 s.54
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• pp.66-75
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• 2003

Long cylinder, subjected to internal pressure, is important in the analysis and design of nuclear fuel rod structures. In many cases, long cylinder problems have been considered as a plane strain condition. However, strictly speaking, long cylinder problems are not plane strain problems, but rather a general plane strain (GPS) condition, which is a combination of a plane strain state and a uniform strain state. The magnitude of the uniform axial strain is required, in order to make the summation of the axial force zero. Although there has been the GPS element, this paper proposes a general technique to solve long cylinder problems, using several pseudo-general plane strain (PGPS) elements. The conventional GPS elements and PGPS elements employed are as follows: axisymmetric GPS element (GA3), axisymmetric PGPS element (PGA8/6), 2-D GPS element (GIO), 3-D PGPS element (PG20/16), and reduced PGPS elements (RPGA6, RPG20/16). In particular, PGPS elements (PGA8/6, PG20/16) can be applied in periodic structure problems. These finite elements are tested, using several kinds of examples, thereby confirming the validity of the proposed finite element models.