• Title/Summary/Keyword: property change

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Structure and Property Modification of Bimodal Molecular Weight Distribution Polyethylene by Electron Beam Irradiation

  • Lee, Sang-Man;Jeon, Hye-Jin;Choi, Sun-Woong;Song, Hyun-Hoon;Nho, Young-Chang;Cho, Kyu-Cheol
    • Macromolecular Research
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    • v.14 no.6
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    • pp.640-645
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    • 2006
  • Polyethylene of bimodal molecular weight distribution was irradiated with an electron beam. The thermal and mechanical properties were examined by DSC, small and wide angle X-ray scattering and static tensile test according to the crystal morphology of the irradiated samples. The crystal morphology change upon irradiation, as revealed by wide angle X-ray scattering, correlated well with the changes in melting enthalpy, whereas the lamellar thickness and the amorphous gap thickness remained virtually unchanged at irradiation doses up to 500 kGy. Crosslinks in the crystal domains became evident at an energy level of 250 kGy, resulting in reduced crystallinity and crystal size of the (110) and (200) planes. The samples became stiff and brittle with increased irradiation dose, which seem to be more relevant to the amount of cross links than the crystal morphology changes.

Time of Fight Resonace Investigation of Amorphous Selenium Films (비정질 셀레늄 필름의 공명 비행시간 조사)

  • Park, J.K.;Park, S.K.;Lee, D.G.;Choi, J.Y.;Ahn, S.H.;Eun, C.K.;Nam, S.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.501-504
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    • 2001
  • We used time-of-flight method to analyze transport properties of charge carrier which is produced by X-ray exposure. It is the research of charge transport and specific property of trap that is performed in direct digital x-ray image receptor. But the results shows us different measurement value of electron and charge drift mobility and it is difficult to precise analysis about charge transport properties and trap mechanism. We measured transit time and drift mobility of charge carriers using time-of-flight method to evaluate the correlation of a-Se thickness change and electric field. We made a testing glass with a-Se of 400 ${\mu}m$ thickness on coming glass using thermoevaporation method and built Au electrode with 300nm, $2{\varphi}$ on both sides of a-Se, As a result of this experiment, electron and hole transit time was each $229.17{\mu}s$ and $8.73{\mu}s$ at $10V/{\mu}m$ electric field and Drift mobility was each $0.00174 cm^{2}/V{\cdot}s$, $0.04584cm^{2}/V{\cdot}s$.

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The Annealing Effect of Diamond-like Carbon Films for RF MEMS Switch

  • Hwang, Hyun-Suk;Choi, Won-Seok;Cha, Jae-Sang
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.35 no.11A
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    • pp.1091-1096
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    • 2010
  • Stiction in microelectromechanical systems (MEMS) has been a major failure mechanism. Especially, in RF MEMS switches, moving parts often suffered in-use and release related stiction problems. Some materials and methods have been used to prevent this problem. Diamond-like carbon (DLC) has not only been used as a protective material owing to its good mechanical properties but also has been used as a hydrophobic material. Its properties could be controlled by post annealing treatment in various conditions. We synthesized DLC films using a radio frequency plasma enhanced chemical vapor deposition (RF PECVD) method on silicon substrates using methane ($CH_4$) and hydrogen ($H_2$) gas. Then, the change of the hydrophobic property of the films was investigated undervarious annealing temperatures in nitrogen and in oxygen ambient. The films, that were annealed above $700^{\circ}C$ in nitrogen ambient, showed a high contact angle of water (> $90^{\circ}$) even though their mechanical property was sacrificed to some degree. The structural variation and the changes of the hydrophobic and mechanical properties of the DLC films were analyzed by Raman spectrum, contact angle measurement, surface profiler, and a nanoindentation test.

A Study on Measurement of Mechanical Properties of Polyther Polyol Base Polyurethane Dispersion by 1,4-butanediol Chain Extension (Polyether Polyol을 이용한 수분산 폴리우레탄의 1,4-butanediol 사슬연장에 의한 물성변화)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.711-718
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    • 2014
  • In this paper, the mechanical property change was investigated by adding 1,4-butanediol as chain extender of polyurethane dispersion for leather coating. Reagents for the synthesis were polypropylene glycol(PPG), isoporon diisocyanate(IPDI), dimethylolpropionic acid(DMPA) and 1,4-BD. All samples showed good solvent resistance and flexibility by different content of the 1,4-BD. As results, samples which contains a lot of 1,4-BD showed good properties whth strength of $1.80kg_f/mm^2$ and abrasion test measurement of 49.54 mg.loss. According to elongation test, the sample which contains low amount of 1,4-BD was good property as 364 %.

Development of Heat-treatment Furnace with Maximum Uniform Zone using Gas-phase Condensing Heat Exchange (기상응축 열교환을 이용한 고정밀 등온 가열로 개발)

  • Hong, Hyun-Seon;Kong, Man-Seek;Kang, Hwan-Kook
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.3
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    • pp.162-168
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    • 2009
  • A horizontal tube furnace with a wide uniform-temperature zone was developed using isothermal characteristics of a heat pipe. The heat pipe heating system consists of a concentric annular shaped stainless-steel container, sodium as a working fluid and a screen mesh wick structure. The performance test of the heat pipe revealed that temperature changes along seven consecutive positions of the heat pipe outer wall were less than${\pm}0.1^{\circ}C$, thereby ensuring the high isothermal property. The isothermal property of the heat pipe-adapted tube fumace was investigated and compared to a conventional non-heat pipe type tube furnace. The temperature distribution measurement showed that the uniform temperature zone, in which temperature change is less than${\pm}$1$^{\circ}$C, of the heat pipe employed tube furnace system was about three times longer compared to the conventional tube furnace system.

Effects of Spinning Speed and Heat Treatment on the Mechanical Property and Biodegradability of Polylactic Acid Fibers (제사속도와 열처리에 따른 polylactic acid 섬유의 물성 및 생분해성 변화)

  • Park Chung-Hee;Hong Eun-Young
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.4 s.152
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    • pp.607-614
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    • 2006
  • This study was carried out to suggest the optimal spinning process condition which provides a proper range of tenacity and biodegradability as textile fibers. The effects of the melt spinning speed and heat treatment on the mechanical property and biodegradability of polylactic acid fiber were investigated. Polylactic acid(PLA) was spun in a high spinning speed of $2000{\sim}4000m/min$. Each specimen was heat-treated at $100^{\circ}C$ during 30min. Mechanical properties such as breaking stress and the degree of crystallinity were evaluated using WAXS. Biodegradability was estimated from the decrease of breaking stress, weight loss, and the degree of crystallinity after soil burial. Experimental results revealed that heat treated specimens showed higher breaking stress than untreated specimens, but the increase was not so high as was expected from the remarkable change of crystallinity by heat treatment. It was concluded that breaking stress was more influenced by spinning speed than heat treatment. In the soil burial test, however biodegradability calculated from weight loss was more influenced by heat treatment than spinning speed.

The Effect of Intermediate Thermo-Mechanical Treatment on the Microstructure and Mechanical Property of 7175 Al Alloy (7175 합금 단조재의 미세조직과 기계적 성질에 미치는 중간가공열처리 영향)

  • Lee, Y.Y.;Song, Y.B.;Im, S.T.;Son, Y.I.;Lee, K.H.;Eun, I.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.3
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    • pp.172-180
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    • 1997
  • The microstructure, tensile and impact properties of forgings of 7175 aluminium alloy have been studied as a function of intermediate thermo-mechanical treatment(ITMT) process. The ITMT process is consisted of warm working and recrystallization. In the case that the billet was warm-worked above 60% below $250^{\circ}C$ and recrystallized at $475^{\circ}C$, the grain size revealed about $17{\mu}m$ which corresponds to one third of that of conventional process. The refinement of grain size leaded to the improved ductility and impact energy without sacrifice of tensile strength. It was found that the ITMT processed specimen behaved isotropically due to the near equiaxed grains. It was observed that the ITMT processed specimen showed the mixed fracture mode of transgranular and intergranular, instead of intergranular mode. This change of fracture mode contributed to the improved ductility and impact property.

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Physical Performance of Metallic Jacquard Fabrics (메탈릭 자카드 직물 물리적 성능평가)

  • Kang, Duck-Hee;Lee, Jung-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.1
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    • pp.149-159
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    • 2009
  • The purposes of this study are to evaluate physical performance of metallic Jacquard fabrics, and to contribute to the research and development of the women's suit made of the metallic Jacquard fabrics. First, eight fabrics were woven with two kinds of warp yarns(nylon and rayon) and weft yarn blended with various contents(0, 7, 14, 21%) of metallic yarn. Second, the mechanical properties were measured by using the KES-FB system, and physical properties such as tensile strength, tearing strength, abrasion resistance, drape, pilling, snagging, degree of crease resistance, flexural stiffness, specular gloss, folding endurance and electrostatic propensity were measured. The results were as follows. As the metal fiber content increased, bending, shear, thickness and weight increased, which imply low recovery of wrinkles. It means that metallic Jacquard fabrics enable to use as a memory fabric. 7% metallic Jacquard fabric showed a low value at total hand value, but there was little change. As the metal fiber content increased, tensile strength, tearing strength, drape coefficient, specular gloss and flexural stiffness increased, however the degree of crease resistance, electrostatic propensity and folding endurance decreased. The metallic Jacquard fabrics were excellent in snagging, abrasion resistance and pilling.

Effect of Aging Treatment Temperature on Surface Modifications in Ni-Ti alloy (Ni-Ti합금의 표면개질에 미치는 시효처리 온도의 영향)

  • Park, J.M.;Kim, W.C.
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.6
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    • pp.368-374
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    • 2009
  • Nickel titanium shape memory alloys (NiTi) have been investigated for applications in the biomedical industry. However, little is known about the influences of surface modifications on the propertise of these alloys. The effect of electropolishing and heat treatments was found to exhibit significant surface roughness. Change of phase was B2, r-phase and B19' by heat treatments. In this study, effect of the electropolishing conditions on surface roughness is investigated in Ni-Ti alloys (Nitinol). Variation in phases with heat treatment temperature is investigated for a Ni-Ti alloy by X-ray diffraction and DSC. Characteristic of the microstructure have been observed by SEM. Surface roughness have been measured by AFM. The results clearly show that significant different in surface property to heat treated at $500^{\circ}C$ (R-phase). $TiO_2$ phases preciritated all of the specimens. It is not good effect of surface roughness because made to surface relief. The surface roughness appears to be important in the property of Ni-Ti alloys for biomedical applications.

Influence of Fast Neutron Irradiation on the Electrical and Optical Properties of Li Doped ZnSnO Thin Film Transistor (Li 도핑된 ZnSnO 박막 트랜지스터의 전기 및 광학적 특성에 대한 고속 중성자 조사의 영향)

  • Cho, In-Hwan;Kim, Chan-Joong;Jun, Byung-Hyuk
    • Korean Journal of Materials Research
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    • v.30 no.3
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    • pp.117-122
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    • 2020
  • The effects of fast neutron irradiation on the electrical and optical properties of Li (3 at%) doped ZnSnO (ZTO) thin films fabricated using a sol-gel process are investigated. From the results of Li-ZTO TFT characteristics according to change of neutron irradiation time, the saturation mobility is found to increase and threshold voltage values shift to a negative direction from 1,000 s neutron irradiation time. X-ray photoelectron spectroscopy analysis of the O 1s core level shows that the relative area of oxygen vacancies is almost unchanged with different irradiation times. From the results of band alignment, it is confirmed that, due to the increase of electron carrier concentration, the Fermi level (EF) of the sample irradiated for 1,000 s is located at the position closest to the conduction band minimum. The increase in electron concentration is considered by looking at the shallow band edge state under the conduction band edge formed by fast neutron irradiation of more than 1,000 s.