• Title/Summary/Keyword: property ($D_2$)

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Non-gaseous Plasma Immersion Ion Implantation and Its Applications

  • Han, Seung-Hee;Kim, En-Kyeom;Park, Won-Woong;Moon, Sun-Woo;Kim, Kyung-Hun;Kim, Sung-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.151-151
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    • 2012
  • A new plasma process, i.e., the combination of PIII&D and HIPIMS, was developed to implant non-gaseous ions into materials surface. HIPIMS is a special mode of operation of pulsed-DC magnetron sputtering, in which high pulsed DC power exceeding ~1 kW/$cm^2$ of its peak power density is applied to the magnetron sputtering target while the average power density remains manageable to the cooling capacity of the equipment by using a very small duty ratio of operation. Due to the high peak power density applied to the sputtering target, a large fraction of sputtered atoms is ionized. If the negative high voltage pulse applied to the sample stage in PIII&D system is synchronized with the pulsed plasma of sputtered target material by HIPIMS operation, the implantation of non-gaseous ions can be successfully accomplished. The new process has great advantage that thin film deposition and non-gaseous ion implantation along with in-situ film modification can be achieved in a single plasma chamber. Even broader application areas of PIII&D technology are believed to be envisaged by this newly developed process. In one application of non-gaseous plasma immersion ion implantation, Ge ions were implanted into SiO2 thin film at 60 keV to form Ge quantum dots embedded in SiO2 dielectric material. The crystalline Ge quantum dots were shown to be 5~10 nm in size and well dispersed in SiO2 matrix. In another application, Ag ions were implanted into SS-304 substrate to endow the anti-microbial property of the surface. Yet another bio-application was Mg ion implantation into Ti to improve its osteointegration property for bone implants. Catalyst is another promising application field of nongaseous plasma immersion ion implantation because ion implantation results in atomically dispersed catalytic agents with high surface to volume ratio. Pt ions were implanted into the surface of Al2O3 catalytic supporter and its H2 generation property was measured for DME reforming catalyst. In this talk, a newly developed, non-gaseous plasma immersion ion implantation technique and its applications would be shown and discussed.

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The Film Property and Deposition Process of TSV Inside for 3D Interconnection (3D Interconnection을 위한 실리콘 관통 전극 내부의 절연막 증착 공정과 그 막의 특성에 관한 연구)

  • Seo, Sang-Woon;Kim, Gu-Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.3
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    • pp.47-52
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    • 2008
  • This investigation was performed in order to study the properties of deposition and layers by Silicon Dioxide, SiO2, as dielectric onto Via and Trench which have high Aspect Ratio (AR). Thus, in order to confirm these properties, three types of CVD, which were PECVD, PETEOS, and ALD, were selected. On the experiment each of the property sections was estimated that step overage of PECVD: <30%, PETEOS: 45%, ALD: 75% and the RSM of PECVD: 27.8 nm, PETEOS: 2.1 nm, ALD: <2.0 nm. As a result of this experiment for the property of electric film, ALD was valuated to be the most favorable outcome. However, ALD was valuated to have the least quality for the deposition rate. ALD deposition rate, $10\;\AA/min$ by $1\;\AA$/1cycle, was prominently lower than PETEOS, which had the deposition rate of $5000\;\AA$/min. Since electric film requires at least $1000\;\AA$ thicknesses, ALD was not suitable for the deposition rate. which is the most important component in a practical use. Therefore, in this particular study, PETEOS was evaluated to be the most suitable recipe.

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Effect of Bath Compositions and Plating Conditions for Decorative Properties of Chromium Deposits using Oxalic Acid (수산을 사용한 크롬도금의 광택성에 미치는 도금액의 조성과 도금조건의 영향)

  • Oh, I.S.;Park, J.D.
    • Journal of Power System Engineering
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    • v.5 no.3
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    • pp.80-87
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    • 2001
  • Decorative properties of chromium depositions from oxalic acid bath containing chromium oxide and ammonium sulfate have been examined over a wide range of bath compositions and plating conditions. The obtained results from this experiment are summarized as follow: The followings were determined as a optimum conditions, bath compositions; $CrO_3\;200{\sim}250\;g/{\ell},\;H_2C_2O_4{\cdot}2H_2O\;500{\sim}700\;g/{\ell},\;(NH_4)_2SO_4\;40{\sim}120\;g/{\ell}$, and operation conditions; pH $2.0{\sim}2.5$, current density $15{\sim}250\;A/dm^2$ at bath temperature range of $30{\sim}80^{\circ}C$. Bright chromium deposits were obtained over a wide range of ammonium sulfate concentration and bath temperature. Decorative property for chromium deposition was adopted to apply stoichiometric ratio of $CrO_3$ concentration and $H_2C_2O_4{\cdot}2H_2O$.

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A Study of Mechanical Properties and Microstructure of ZrO2-Ag Depending on the Composite Route (ZrO2-Ag의 복합화 공정에 따른 기계적 특성 및 미세조직 평가)

  • Yeo, In-Chul;Han, Jae-Kil;Kang, In-Cheol
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.416-423
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    • 2012
  • This paper introduces an effect of a preparing $ZrO_2$-Ag composite on its mechanical properties and microstructure. In present study, $ZrO_2$-Ag was prepared by reduction-deposition route and wetting dispersive milling method, respectively. Two type of Ag powders (nano Ag and micron Ag size, respectively) were dispersed into $ZrO_2$ powder during wetting dispersive milling in D.I. water. Each sample was sintered at $1450^{\circ}C$ for 2hr in atmosphere, and then several mechanical tests and analysis of microstructure were carried out by bending test, hardness, fracture toughness and fracture surface microstructure. As for microstructure, the Ag coated $ZrO_2$ showed homogeneously dispersed Ag in $ZrO_2$ in where pore defect did not appear. However, $ZrO_2$-nano Ag and $ZrO_2$-micro Ag composite appeared Ag aggregation and its pore defect, which carried out low mechanical property and wide error function value.

Correlation Analysis between Rut Resistance and Deformation Strength for Superpave Mixtures (수퍼페이브 혼합물의 소신변형저항성과 변형강도와의 상관성분석)

  • Kim, K.W.;Kim, S.T.;Kwon, O.S.;Doh, Y.S.
    • International Journal of Highway Engineering
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    • v.6 no.4 s.22
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    • pp.45-53
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    • 2004
  • This study dealt with correlation analysis between deformation strength and rut resistance of asphalt concretes based on binder grade in Superpave specification with changing submerging time. Currently, Mashall mix design is known to have little correlation with rutting related performance. Therefore, some agencies started to use the Superpave method for asphalt mix design. But this method has a weak point in that it can not distinct mechanical property of the asphalt mixtures designed. For solution of these problem, this study used deformation strength, $S_D$, of Kim test which is a new approach under development for finding property which represents rut resistance characteristics of asphalt mixtures under static loading. This study used two aggregates from two regions and five PG asphalt binders. Final rut depth (DR) and dynamic stability (DS) from wheel tracking (WT) test were obtained. and $S_D$ value of the same mixture specimen which was made by gyratory compactor was obtained using loading head [4(1.0)]. Three submerging times 30min, 40min, 50min were used as a test variable at $60^{\circ}C$. Correlation analysis of DR and DS with $S_D$ were performed based on PG grade. It was found out that the $S_D$ has a high correlation with DR and DS of superpave mixtures. The highest $R^2$ was found from the $S_D$ values of 30min. submerged specimen.

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The Effects of the Science and Technology Environment on Technology Transfer (과학기술 환경이 기술이전에 미치는 영향: OECD 34개 국가를 중심으로)

  • Back, Seunghee;Park, Young-Il
    • Journal of Technology Innovation
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    • v.22 no.2
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    • pp.131-156
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    • 2014
  • Nowadays, the R&D policy has gradually emphasized the creation of economic values added through technology transfer of R&D performance. Technology transfer plays an important role in making a profit on commercialization of technology, but the performance of technology transfer is a great difference between countries. Therefore, this study analyzes the effects of the science and technology environment on technology transfer from a national point of view. In this study, the science and technology environment largely consists of openness, ease of firms, protection of intellectual property, emphasis of science in schools. We select OECD 34 countries as the subject of this study and collect the data from IMD between 2002 and 2011. The results show that all hypotheses are supported. Openness and ease of firms are related to technology transfer as they help to improve the understanding and willingness about technology transfer nationally. Protection of intellectual property also influences the spread of R&D performance positively, and the environment that is emphasized science in school actively promotes both creation and technology transfer of R&D performance. Although prior studies have focused on technical capabilities to improve the performance of technology transfer, we consider the influence of the science and technology environment from an institutional perspective. This study will do much for formulate the R&D policy.

A Two-Stage Power Amplifier with a Latch-Structured Pre-Amplifier (래치구조의 드라이브 증폭단을 이용한 2단 전력 증폭기)

  • Choi Young-Shig;Choi Heyk-Hwan
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.9 no.2
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    • pp.295-300
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    • 2005
  • In this paper we have designed a two-stage Class I power amplifier operated at 2.4CHz for Class-1 Bluetooth application. The power amplifier employs class-I topology to exploit its soft-switching property for high efficiency. The latch-structured pre-amplifier with amplifiers makes its output signal as sharp as possible for soft switching of the next power amplifier. It improves the overall efficiency of the proposed power amplifier. It shows 65.8$\%$ PAE, 20dB power gain and 20dBm output power.

Nano Dispersion of Aggregated Y2O3:Eu Red Phosphor and Photoluminescent Properties of Its Nanosol (응집된 Y2O3:Eu Red 형광체의 나노분산 및 나노졸의 형광특성)

  • Lee, Hyun Jin;Ban, Se Min;Jung, Kyeong-Youl;Choi, Byung-Ki;Kang, Kwang-Jung;Kim, Dae Sung
    • Korean Journal of Materials Research
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    • v.27 no.2
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    • pp.100-106
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    • 2017
  • Nanosized and aggregated $Y_2O_3:Eu$ Red phosphors were prepared by template method from metal salt impregnated into crystalline cellulose. The particle size and photoluminescent property of $Y_2O_3:Eu$ red phosphors were controlled by variation of the calcination temperature and time. Dispersed nanosol was also obtained from the aggregated $Y_2O_3:Eu$ Red phosphor under bead mill wet process. The dispersion property of the $Y_2O_3:Eu$ nanosol was optimized by controlling the bead size, bead content ratio and milling time. The median particle size ($D_{50}$) of $Y_2O_3:Eu$ nanosol was found to be around 100 nm, and to be below 90 nm after centrifuging. In spite of the low photoluminescent properties of $Y_2O_3:Eu$ nanosol, it was observed that the photoluminescent property recovered after re-calcination. The dispersion and photoluminescent properties of $Y_2O_3:Eu$ nanosol were investigated using a particle size analyzer, FE-SEM, and a fluorescence spectrometer.

Design of Transdermal Delivery System Using New Film-Forming Agents (신규 필름형성제를 이용한 경피흡수제제의 설계)

  • Choi, Yang-Gyu;Kim, Young-So;Kim, Jung-Ju;Sim, Young-Chul
    • Journal of Pharmaceutical Investigation
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    • v.33 no.3
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    • pp.163-169
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    • 2003
  • In order to develop a film-forming transdermal drug delivery system, polyurethane (PU) based on poly(ethylene glycol) and poly(tetramethylene oxide) was synthesized and characterized. The synthesized PU was blended with Gantrez ES 225 (GT) to improve the adhesion property of film-forming agent to the skin. When film-forming gel formulation containing 3% ketoprofen (KP) was applied, transparent thin film was obtained within 5 minutes and adhered to the skin for 8 hours. In vitro percutaneous absortion studies were performed to determine the rate of ketoprofen absorption through guinea pig skin. A prominent effect of limonene on the skin permeability of ketoprofen was observed among the various skin permeation enhancers investigated. Considering mechanica properties of film and skin permeability of ketoprofen, 2% of limonene was optimal content in the film forming transdermal formulation.

The Synthesis and Charge/discharge Properties of $LiNiO_2$ according to heat treatment condition (열처리 조건에 따른 $LiNiO_2$의 합성과 충방전 특성)

  • Lee, H.N.;Chun, D.G.;Choi, H.K.;Kim, K.S.;Gu, H.B.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1603-1605
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    • 1997
  • $LiNiO_2$ is prepared by heating LiOH $H_2O$ and $Ni(OH)_2$ (mole ratio 1:1). In this study, we investigated X-ray diffraction, and charge/discharge property heat treatment condition and conductive agent sort and volume of $LiNiO_2$ prepared at various temperature and time. All $LiNiO_2$ prepared at this study showed hexagonal structure. In charge/discharge capacities, heated at $O_2$ than air and $750^{\circ}C$ than $700^{\circ}C$, specific capacity is higher. Therefore, when preliminary heat at $650^{\circ}C$ $O_2$ and heat at $750^{\circ}C$ carried out, charge/discharge property is best.

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