• Title/Summary/Keyword: property ($B_2$)

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Studies on the Properties of Thexylboronic Acid and Its Derivatives

  • Cha, Jin-Soon;Brown, Herbert C.
    • Bulletin of the Korean Chemical Society
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    • v.26 no.2
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    • pp.292-296
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    • 2005
  • Physical and chemical properties of thexylboronic acid and its derivatives such as thexylboroxine and ethylene glycol or diethanolamine thexylboronic ester have been studied. Thexylboronic acid can be extracted from an organic solution with an aqueous sodium hydroxide solution as an “te”complex. It is readily converted into thexylboroxine in the presence of anhydrous magnesium sulfate in pentane. It reacts with simple alcohols only slowly; however, it reacts readily with excess diethanolamine in the presence of anhydrous magnesium sulfate to give the corresponding ester.

PROPER RATIONAL MAP IN THE PLANE

  • Jeong, Moon-Ja
    • The Pure and Applied Mathematics
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    • v.2 no.2
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    • pp.97-101
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    • 1995
  • In [6], the author studied the property of the Szeg kernel and had a result that if $\Omega$ is a smoothly bounded domain in C and the Szeg kernel associated with $\Omega$ is rational, then any proper holomorphic map from $\Omega$ to the unit disc U is rational. It leads to the study of the proper rational map of $\Omega$ to U. In this note, first we simplify the proof of the above result and prove an existence theorem of a proper rational map. Before we proceed to state our result, we must recall some preliminary facts.(omitted)

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On the Characteristics of Probability and Periodicity for the Daily Precipitaty Occureonce in Korea (우리나라 일별 강수발생의 확률과 주기성의 특성)

  • Moon, Sung-Euii;Kim, Baek-Jo;Ha, Chang-Hwan
    • Journal of Environmental Science International
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    • v.6 no.2
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    • pp.95-106
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    • 1997
  • The characteristics on the transtion probabilities and periodicity for the daily precipitation occurrence in Korean peninsula are investigated by applying the Markov chain properties to daily precipitation occurrence. In order to examine the responses of Markov Chain properties to the applied period and their magnitudes, three cases (Case A: 1956~ 1985 at 14 stations, Case B: 1965~ 1994 at 14 stations, and Case C: 1985~ 1994 at 63 stations) are considered In this study. The transition probabilities from wet day to wet day for all cases are about 0.50 and in summer, especially July, are higher. In addition, considering them in each station we can find that they are the highest at Ullung-do and lowest at Inchon for all cases. The annual equilibrium probabilities of a wet day appear 0.31 In Case A, 0.30 Case B, and 0. 29 Case C, respectively. This may explain that as the data-period used becomes shorter, the higher the equilibrium probability is. The seasonal distributions of equilibrium probabilities are appeared the lowest(0.23~0.28) in winter and the highest(more than 0.39) in spring and monthly in .truly and in October, repectively. The annual mean wet duration for all cases is 2.04 days in Case A, 1.99 Case B, and 1.89 Case C, repectively. The weather cycle obtained from the annual mean wet and dry duration is 6.54~6.59 days, which are closely associated with the movement of synoptic systems. And the statistical tests show that the transitions of daily precipitation occurrence for all cases may have two-state first Markov chain property, being the stationarity in time and heterogeneity in space.

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Effect of Added B4C on the Mechanical Properties of WC/Ni-Si Hardmetal (WC/Ni-Si 초경합금의 기계적 성질에 미치는 B4C의 영향)

  • Lee, Gil-Geun;Ha, Gook-Hyun
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.366-370
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    • 2013
  • The effects of $B_4C$ on the mechanical properties of WC/Ni-Si hardmetal were analyzed using sintered bodies comprising WC(70-x wt.%), Ni (28.5 wt.%), Si (1.5 wt.%), and $B_4C$ (x wt.%), where $$0{\leq_-}x{\leq_-}1.2$$ wt.%. Samples were prepared by a combination of mechanical milling and liquid-phase sintering. Phase and microstructure characterizations were conducted using X-ray diffractometry, scanning electron microscopy, and electron probe X-ray micro analysis. The mechanical properties of the sintered bodies were evaluated by measuring their hardness and transverse rupture strength. The addition of $B_4C$ improved the sinterability of the hardmetals. With increasing $B_4C$ content, their hardness increased, but their transverse rupture strength decreased. The changes of sinterability and mechanical properties were attributed to the alloying reaction between $B_4C$ and the binder metal (Ni, Si).

Development of Oxo-biodegradable Bio Film by Using Biodegradable Catalyst (생분해 촉매제를 이용한 산화생분해 바이오 필름 개발)

  • Rhee, Jin-Kyu;Jung, Dong Seok;You, Young-Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.22 no.3
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    • pp.127-134
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    • 2016
  • In this study, Biodegradable masterbatch (M/B) was prepared by different kinds and content of biodegradable catalysts added to oxo biodegradable plastics. The bio film was prepared by adding biodegradable M/B to the polyethylene pellet, and the change of physical properties by UV and heat treatment and the stability as food packaging material were confirmed. As a result of the physical property change, Fe salt and Al salt bio film was superior to Ni salt bio film about a decrease in physical property. However, considering the raw material cost and industrial availability, M/B containing Fe salt was selected and additional experiments were conducted by concentration. The bio films prepared with Fe salt M/B 1.0, 1.5 and 2.0 wt% showed excellent physical properties.

Antimicrobial and Biogenic Amine-Degrading Activity of Bacillus licheniformis SCK B11 Isolated from Traditionally Fermented Red Pepper Paste (전통고추장에서 유해균 억제 및 Biogenic Amines 분해 능력을 가지는 Bacillus licheniformis SCK B11의 분리)

  • Kim, Yong-Sang;Jeong, Jin-Oh;Cho, Sung-Ho;Jeong, Do-Yeon;Uhm, Tai-Boong
    • Korean Journal of Microbiology
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    • v.48 no.2
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    • pp.163-170
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    • 2012
  • In order to inhibit the growth of pathogens and degrade biogenic amines during the fermentation of soybean products, an isolate with antimicrobial activity against pathogens and biogenic amine-degrading property was obtained from 83 traditionally fermented soybean products. The morphological and biochemical tests and the phylogenetic relationship among 16S rRNA gene sequences indicated that the isolate named as the strain SCK B11 was most closely related to Bacillus licheniformis. The cell-free supernatant of two day cultures was active against several pathogens including Enterococcus faecalis, Listeria monocytosis, Micrococcus luteus, Pseudomonas aeruginosa, Bacillus cereus, and Staphylococcus aureus. PCR analysis was conducted to determine relatedness to antimicrobial lantibiotics and biosurfactants produced by Bacillus spp., but showed negative for the genes encoding surfactin, lichenysin, and lichenicidine. Electron microscopic observation indicated that the antimicrobial agent seemed to attack the membrane of the pathogens, leaving the ghost or shrunken cells. The strain was found to degrade histamine by 72% and tyramine by 66% in the cooked soybean containing 5.3% of biogenic amine over 10 days of fermentation time. The use of selected strain would be a potential control measure in manufacturing traditionally fermented soybean products that are difficult to control pathogens and biogenic amine levels.

Composition-property Relationships of Enamel Glass for Low Carbon Steel

  • Kang, Eun-Tae;Kim, Jong-Po;Cho, Yong-Hyun;Park, Seon-Mi
    • Journal of the Korean Ceramic Society
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    • v.50 no.3
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    • pp.186-194
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    • 2013
  • The relationship between composition and properties of enamel glass was investigated by introducing a mixture design. The enamel glass was manufactured by mixing various components under the following constraints: $45{\leq}SiO_2{\leq}55$, $10{\leq}B_2O_3{\leq}18$, $6{\leq}Na_2O{\leq}15$, $1{\leq}Li_2O{\leq}6$, $5{\leq}K_2O{\leq}10$, $0{\leq}TiO_2{\leq}8$, $0{\leq}ZrO_2{\leq}8$, 13.3MO (mol %). A mathematical model for the calculation of some properties of enamel glasses as a function of their composition was developed by the experimental statistical method. The results showed that the proposed model with the experimental measurement were in good agreement and the mixture experimental design was an effective method for optimizing the composition of the enamel glass with respect to its properties.

Design and Synthesis of Novel Rhodamine-based Chemosensor Probe Toward Cu2+ Cation

  • Son, Young-A
    • Textile Coloration and Finishing
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    • v.26 no.1
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    • pp.7-12
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    • 2014
  • Nowdays, fluorescent rhodamine chemosensors have attracted a worldwide interest due to its ability to selectively detect heavy and transition metal cations. Due to the importance in environmental and biological toxic effects, the developments of fluorescent chemosensors have been received considerable attention in recent. Especially, a rhodamine-based chemosensor probes have been proved to be useful by exhibiting the efficient "off-on" fluorescence switching toward selected metal cations. This fluorophore can undergo the transformation from non-fluorescent and colorless spirolactam derivative to fluorescent ring-open form. In this study, a new fluorescent chemosensor was synthesized using rhodamine B through two-step procedures, and its selectivity and related optical property were characterized. Selectivity and sensitivity was found toward $Cu^{2+}$ guest molecules and then related optical properties of rhodamine B based fluorescent chemosensor compound were characterized using discussed. In addition, computational calculation was used to determine the HOMO/LUMO values.