• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.3B
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• pp.211-220
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• 2011

In this study a conceptual soil water model is proposed to simulate water balance at catchment scale. The model is based on the sequential separation of daily precipitation into surface runoff, wetting, vaporization, and percolation. The proposed model is calibrated by using three observation sets: empirically estimated annual vaporization, monthly wetting estimated by NRCS-CN method, and both of them. The model performance is evaluated to understand which hydrologic components for calibrating the model are needed. It is shown that both of annual vaporization and monthly wetting are indispensable hydrologic components to simulate reasonably precipitation partitioning.

• Journal of the Korean association of regional geographers
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• v.14 no.3
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• pp.212-223
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• 2008

The rainfall partitioning in a monogenetic volcano has been analysed using the hydrological data of a small catchment on Eoseungsaeng-oreum of Mount Halla and the meterological data of Eorimok Automated Weather System. The experimental catchment extends from 965 m to 1,169 m in altitude, and has an catchment area of $51,000\;m^2$ Eoseungsaeng-oreum is the scoria cone predominantly covered with Carpinus laxiflora and Quercus serrata. The analyzed periods are April 30 to September 12 and October 7 to November 19, 2007. The experimental catchment exhibits the total precipitation of 2,296.5 mm. Surface runoff amounts to 465 mm that is equivalent to 20.2% of the precipitation. By contrast, evapotranspiration accounts for 25.9% of the precipitation, and the remnant of 1,236.5 mm deep1y percolates underground through a basement. The rainy summer season, in particular, shows the highest deep percolation ratio of 62.2%. The deep percolation ratio of the experimental catchment is at 1east more two times than the ratio of a gneiss basin in Korea Peninsular. It has suggested that the experimental catchment is characterized by the higher portion of deep percolation in rainfall partitioning which reflects the highly permeable lithology in Jeju Island.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.409-412
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• 2003

Total extraction of stream sediments in the Kwangyang mine area shows their significant pollution with most trace metals such as Cr, Co, Fe, Pb, Cu, Ni, Zn and Cd, due to sulfide oxidation in waste dumps. Calculations of enrichment factor shows that Chonam-ri creek sediments are more severely contaminated than Sagok-ri sediments. Using the weak acid (0.1N HCl) extraction and sequential extraction techniques, the transport and sediment-water partitioning of heavy metals in mine drainage were examined for contaminated sediments in the Chonam-ri and Sagok-ri creeks of the Kwangyang Au-Ag mine area. Calculated distribution coefficient (Kd) generally decreases in the order of Pb $\geq$Al > Cu > Mn > Zn > Co > Ni $\geq$ Cd. Sequential extraction of Chonam-ri creek sediments shows that among non-residual fractions the Fe-Mn oxide fraction is most abundant for most of the metals. This indicates that precipitation of Fe hydroxides plays an important role in regulating heavy metal concentrations in water, as shown by field observations.

• The Journal of the Korea institute of electronic communication sciences
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• v.14 no.1
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• pp.61-68
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• 2019

In addition to non-meteorological echoes, meteorological echoes with large scattering effects, such as precipitation, cause errors in wind data measured by wind profiler. In the rainfall situation, the Doppler spectrum of wind profiler shows both the rainfall signal and the atmospheric signal as two peaks. The vertical radial velocity is very large due to the falling rain drop. The radial velocity contaminated by rainfall decreases the accuracy of the horizontal wind vector and leads to inaccurate weather analysis. In this study, we developed an algorithm to process raw data of wind profiler and distinguished rainfall signal and wind signal by partitioning bimodal peak for Doppler spectrum in rainfall environment.

• Proceedings of the KSRS Conference
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• 2002.10a
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• pp.721-727
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• 2002

Precipitation evapotranspiration and runoff are three key parameters of regional water balance. Problems exist in the traditional methods for calculating such factors , such as explaining of the geographic rationality of spatial interpolating methods and lacking of enough observation stations in many important area for bad natural conditions. With the development of modern spatial info-techniques, new efficient shifts arose for traditional studies. Guided by theories on energy flow and materials exchange within Soil-Atmosphere-Plant Continuant (SPAC), retrieval models of key hydrological parameters were established in the Yellow River basin using CMS-5 and FengYun-2 meteorological satellite data. Precipitation and evapotranspiration were then estimated: (1) Estimating tile amount of solar energy that is absorbed by the ground with surface reflectivity, which is measured in the visible wavelength band (VIS): (2) Assessing the partitioning of the absorbed energy between sensible and latent heat with the surface temperature, which was measured in the thermal infrared band (TIR), the latent heat representing the evapotranspiration of water; (3) Clouds are identified and cloud top levels are classified using both VIS and TIR data. Hereafter precipitation will be calculated pixel by pixel with retrieval model. Daily results are first obtained, which are then processed to decade, monthly and yearly products. Precipitation model has been has been and tested with ground truth data; meanwhile, the evapotranspiration result has been verified with Large Aperture Scintillometry (LAS) presented by Wageningen University of the Netherlands. Further studies may concentrate on the application of models, i.e., establish a hydrological model of the Yellow river basin to make the accurate estimation of river volume and even monitor the whole hydrological progress.

• Corrosion Science and Technology
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• v.13 no.2
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• pp.48-55
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• 2014

Influence of annealing temperature on the microstructure and resistance to pitting corrosion of the hyper duplex stainless steel was investigated in acid and neutral chloride environments. The pitting corrosion resistance is strongly dependent on the microstructure, especially the presence of chromium nitrides ($Cr_2N$), elemental partitioning behavior and volume fraction of ferrite phase and austenite phase. Precipitation of deleterious chromium nitrides reduces the resistance to pitting corrosion due to the formation of Cr-depleted zone. The difference of PREN (Pitting Resistance Equivalent Number) values between the ferrite and austenite phases was the smallest when solution heat-treated at $1060^{\circ}C$. Based on the results of electrochemical tests and critical crevice temperature tests, the optimal annealing temperature is determined as $1060^{\circ}C$.

• Applied Microscopy
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• v.46 no.3
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• pp.127-133
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• 2016

Atom probe tomography is a time-of-flight mass spectrometry-based microanalysis technique based on the field evaporation of surface atoms of a tip-shaped specimen under an extremely high surface electric field. It enables three-dimensional characterization for deeper understanding of chemical nature in conductive materials at nanometer/atomic level, because of its high depth and spatial resolutions and ppm-level sensitivity. Indeed, the technique has been widely used to investigate the elemental partitioning in the complex microstructures, the segregation of solute atoms to the boundaries, interfaces, and dislocations as well as following of the evolution of precipitation staring from the early stage of cluster formation to the final stage of the equilibrium precipitates. The current review article aims at giving a comment to first atom probe users regarding the limitation of the techniques, providing a brief perspective on how we correctly interprets atom probe data for targeted applications.

• Bulletin of the Korean Chemical Society
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• v.33 no.5
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• pp.1681-1685
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• 2012

A sensitive liquid chromatography-tandem mass spectrometric (LC-MS/MS) method was developed to determine valproic acid in human red blood cell (RBC). It is important to measure the drug concentration of the RBC as well as that of the plasma because of drug partitioning for pharmacokinetic and pharmacodynamic study. The method was linear over the dynamic range of 1-100 ${\mu}g$/mL with a correlation coefficient $r$ = 0.9997. The linearity of this method was established from 1 to 100 ${\mu}g$/mL for valproic acid in red blood cell with accuracy and precision within 15% at all concentrations. The intra-run and inter-run assay accuracy and coefficient of variations are all within 15% for all QC samples prepared in plasma and red blood human samples. Then, valproic acid amount by protein precipitation in plasma was quantified by LC-MS/MS mass spectrometry. The distribution ratio of VPA in RBC and plasma was analyzed by clinical samples. Based on measurement of the valproic acid in human red blood cell, this method has been applied to clinical research for study of distribution ratio of valproic acid in blood.

• Journal of Microbiology
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• v.39 no.1
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• pp.67-73
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• 2001

A validation study was conducted to evaluate the efficacy and mechanism of the cryo-precipitation, monoclonal anti-FVIIIc antibody (mAb) chromatography, Q-Sepharose chromatography, and lyophilization steps involved in the manufacture of high purity factor VIII (GreenMono) from human plasma, in the removal and/or inactivation of hepatitis A virus (HAV). Samples from the relevant stages of the production process were spiked with HAV and subjected to scale-down processes mimicking the manufacture of the high purity factor VIII concentrate. Samples were collected at each step and immediately titrated using a 50% tissue culture infectious dose (TCID$\_$50/) and then the virus reduction factors were evaluated. HAV was effectively partitioned from factor VⅢ during cryo-precipitation with the log reduction factor of 3.2. The mAb chromatography was the most effective step far removal of HAV with the log reduction factor of $\geq$4.3. HAV infectivity was not detected in the fraction of factor VⅢ, while most of HAV infectivity was recovered in the fractions of flow through and wash during mAb chromatography. Q-Sepharose chromatography showed the lowest efficacy for partitioning HAV with the log reduction factor of 0.7. Lyophilization was an effective step in inactivating HAV with the log reduction factor of 2.3. The cumulative lag reduction factor, $\geq$10.5, achieved for tile entire manufacturing process was several magnitudes greater than the potential HAV load of current plasma pools.

• Corrosion Science and Technology
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• v.18 no.6
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• pp.267-276
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• 2019

The purpose of this study was to examine the influence of conditions for quenching and/or tempering on the corrosion and hydrogen diffusion behavior of ultra-strong automotive steel in terms of the localized plastic strain related to the dislocation density, and the precipitation of iron carbide. In this study, a range of analytical and experimental methods were deployed, such as field emission-scanning electron microscopy, electron back scatter diffraction, electrochemical permeation technique, slow-strain rate test (SSRT), and electrochemical polarization test. The results showed that the hydrogen diffusion parameters involving the diffusion kinetics and hydrogen solubility, obtained from the permeation experiment, could not be directly indicative of the resistance to hydrogen embrittlement (HE) occurring under the condition with low hydrogen concentration. The SSRT results showed that the partitioning process, leading to decrease in localized plastic strain and dislocation density in the sample, results in a high resistance to HE-induced by aqueous corrosion. Conversely, coarse iron carbide, precipitated during heat treatment, weakened the long-term corrosion resistance. This can also be a controlling factor for the development of ultra-strong steel with superior corrosion and HE resistance.