• Title/Summary/Keyword: potassium sulfate

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Synthesis of Inorganic/Organic Core-Shell Polymer Using Polyoxyethylene Alkylether Sulfate as a Surfactant (Polyoxyethylene Alkylether Sulfate 계면활성제를 사용한 무기/유기 코어-셀의 합성)

  • Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.1
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    • pp.93-97
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    • 2010
  • Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S75D) surfactant was prepared. The core-shell composite of inorganic/organic were polymerized by using styrene(St) as a shell monomer and potassium persulfate(KPS) as an initiator. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene in the presence of an anionic surfactant lauryl sulfate(SLS). The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer(TGA) and morphology of latex by scanning electron microscope(SEM).

Effect of Anionic Surfactants in Synthesizing Silicone Dioxide/Styrene Core-Shell Polymer (이산화규소/스티렌의 코어-셀 합성에서 음이온 계면활성제의 영향)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.3
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    • pp.404-409
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    • 2008
  • The core-shell composite particles of inorganic/organic were polymerized by using styrene(St) as a shell monomer and potassium persulfate (KPS) as an initiator. We studied the effect of core-shell structure of silicone dioxide/styrene in the presence of an anionic surfactant sodium lauryl sulfate (SLS) and polyoxyethylene alky lether sulfate (EU-S133D). We found that when $SiO_2$ core/PSt shell polymerization was prepared on the surface $SiO_2$ particle, to minimize the coagulation during the shell polymerization, the optimum conditions were at concentration of $2.56{\times}10^{-2}mole/L$ SLS. The structure of core-shell polymer was confirmed by measuring the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of core-shell polymer particles by transmission electron microscope (TEM).

The Effect of Anionic Surfactants in Synthesizing Calcium Carbonate/Acrylate Core-Shell Polymer (탄산칼슘/아크릴계 유기물의 코어-셀 합성에서 음이온 계면활성제의 영향)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.1
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    • pp.83-90
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    • 2008
  • The core-shell latex particles were prepared by sequential emulsion polymerization using alkyl methacrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We study the effects of core-shell structure of calcium carbonate/alkyl methacrlyate in the presence of an anionic surfactant sodium lauryl sulfate (SLS) and polyoxyethylene alkyl ether sulfate (EU-S133D)). The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by transmission electron microscope (TEM).

Electrokinetic Restoration of Saline Soil Accumulated with Nitrate and Sulfate (질산염 및 황산염 집적 염류 토양의 전기역학적 개량)

  • Cho, Jung-Min;Jo, Sung-Ung;Kim, Do-Hyung;Yang, Jung-Seok;Baek, Ki-Tae
    • Journal of Soil and Groundwater Environment
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    • v.16 no.5
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    • pp.18-23
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    • 2011
  • The electrokinetic transport characteristics of salts were investigated using nitrate and sulfate accumulated saline greenhouse soil. Within 8 days, 95% of nitrate was removed from the soil, while sulfate removal was 19% for 8 days. The low removal of sulfate came from adsorption reaction on the soil particles or organic matter and precipitation with calcium. Divalent cations such as calcium and magnesium were transported toward cathode via electromigration, and most monovalent cation such as potassium was removed. The pattern of residual electrical conductivity was similar with that of sulfate. Based on the results, electrokinetic technique is effective to restore nitrate-accumulated saline soil, but is not effective to restore sulfate-accumulated soil.

Changes of Allylisothiocyanate Content by Foliar Application of Fertilizer in Wasabia japonica Mastum (엽면시비(葉面施肥)에 따른 고추냉이 근경(根莖)의 행미성분함양(幸味成分含量) 변화(變化))

  • Lee, Sung-Woo;Choi, Kyong-Gu;Park, Jang-Whan;Kim, Seok-Dong
    • Korean Journal of Medicinal Crop Science
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    • v.6 no.1
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    • pp.1-5
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    • 1998
  • We studied about the changes of Allylisothiocyanate (allyINCS) content in rhizome by growth period or season and the effect of foliar application of fertilizer on allylNCS content in Wasabia japonica. AllylNCS content in rhizome of Wasabia japonica was changed according to growth period or season and it was decreased suddenly in May, the last stage of flowering. Foliar application of 1 % urea increased rhizome weight, but had no effect on allylNCS content in rhizome. Total three times foliar applications of 1 % potassium sulfate from Feb. to April increased rhizome weight by 44% and allylNCS content by 38% compared with control and potassium sulfate was more effective than ammonium sulfate. Even though the use of 1 % urea and 1 % ammonium sulfate caused growth disorder due to high concentration, rhizome weight was similar to the control and allylNCS content of rhizome increased by 47% more than control.

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Hydrochemical Characteristics of Spring Water in Cheju Island (제주도 용천수의 수리화학적 특성)

  • 윤정수;박상운
    • Journal of the Korean Society of Groundwater Environment
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    • v.5 no.2
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    • pp.66-79
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    • 1998
  • This study purposes to elucidate the characteristics of local water quality and the evolutional process of the spring water have been studied with the samples from 55 selected springs, from the coast region to the Baegrogdam, a caldera lake of Halla mountain in Cheju Island. Results of hydrochemical analyses in the 55 spring water show that Gwaneumsa is pollued with high hydrogen concentration, and spring waters from Yusuarmchun, Jangsumul, Dukjisemmul, Sinch'onk'nmul, Youngchunsa, Woonyangchun, Harwontongmul, Dongheamul, Seakdalsengsu, Andukkyekok, Dotimul, Kinmul, Harkangmul and Jungkeummul are polluted by the pollution sources from the surface surrounding ground. Spring waters of Samyang3suwon, Meungbusa, Sernurungmul, Tosanmul, Jungkeummul, Kwakgimul, Aewolharmul, Konemul and Nokgomul are also polluted from the sea water intrusion. The electrical conductivity, pH and the concentration of nitrate nitrogen and bicarbonate increase when the precipitation increases, but the concentration of sodium, chloride and sulphate decrease when the precipitation increases. The concentrations of potassium, magnessium and calcium are nearly independent of the precipitaion. Quality characteristics of spring water show complicated group of spring water through piper's trilinear diagram. The high mountain region consists of groups of sodium or potassium type and bicarbonate type; the middle mountain region consists of groups of sodium or potassium type and no dominant type; the low mountain consists of groups of no dominant type and sulfate or nitrate type; the coast region consists of groups of sodium or potassium type and chloride type or no dominant type. These characteristics indicate that the spring waters are changed from bicarbonate type in the high and middle mountain regions into non-bicarbonate type in the coastal region, as the precipitated waters flow downslope.

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Influence of Potassium on the Cement Clinker Formation I. Unstable Free Alkali in Clinker (시멘트 클린커 생성과정에 미치는 Potassium의 영향 I. 불안정 상태의 알칼리)

  • 서일영;최상홀
    • Journal of the Korean Ceramic Society
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    • v.22 no.1
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    • pp.25-34
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    • 1985
  • The states of alkali occuring in Portland cement clinker were studied. Potassium was added to raw mixture by there kinds ; $K_2SO_4$, $K_2CO_3$ and KOH. In case of $K_2CO_3$ and KOH addition the new state of unstable alkali was found when alkakli content is high and $SO_3$ content is low in the clinker. Unstable state of highly basic free 4K_2O$ causes lowering burnability much more than alkali sulfate especially at the early stage of burning. Lowered burnability by 4K_2O$ became more serious with higher LSF. Unstable free-4K_2O$ which is readily soluble with water reacts with gypsum to form $Ca(OH)_2$ and syngenite as soon as water is added. As a results the liberation rate of heat of hydration at the early hydration process(1st peak) was increased.

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Characteristics of $PM_{2.5}$ in Kanghwa (강화에서의 $PM_{2.5}$ 특성)

  • 최민규;여현구;임종억;조기철;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.6
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    • pp.573-583
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    • 2000
  • In order to investigate the characteristics of PM(sub)2.5 in the background area, the following pollutant were measured from February 1996 to June 1999 in Kanghwa: PM(sub)2.5 mass, sulfate, nitrate, chloride, ammonium, sodium, calcium, magnesium and potassium. The mean concentration of PM(sub)2.5 mass was 25.8$\pm$1.2$\mu\textrm{g}$/㎥(range 5.18~85.74). This value was higher than the annual PM(sub)2.5 US NAAQS(15$\mu\textrm{g}$/㎥) and the total number of samples higher than the 24-h PM(sub)2.5 US NAAQS(65$\mu\textrm{g}$/㎥) was seven. PM(sub)2.5 masses also showed temporal variations both yearly and seasonally. Total water soluble ions constituted about 45% of PM(sub)2.5 miss, and sulfate, nitrate and ammonium were main components in water soluble ions. Compared with the literature data from other areas, the measured PM(sub)2.5 concentrations were relatively high.

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Immunogenicity of a Gamma-irradiat d Brucella Vaccine (Gamma선 조사로 만든 Brucella Vaccine의 생쥐에 대한 면역력)

  • Ahn, Tai-Hew
    • The Journal of the Korean Society for Microbiology
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    • v.6 no.1
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    • pp.15-20
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    • 1971
  • A vaccine was prepared by $10^6$ r cobalt-60 irradiation of lyophilized virulent Brucella melitensis and tested in mice for immunogenic activity against a lethal challenge dose of the homologous strain. The vaccine(GIV) produced a high degree of immunity in mice, and comparative studies demonstrated it to be superior to vaccines prepared by heat or by chemical(ether, formalin, or phenol) treatment. Living vaccines, Brucella abortus. strain 19 and an R-form of Brucella melitensis were lethal for mice in larger doses. A comparison of seven adjuvant mixtures for use with the GIV showed no statistically significant difference, but. Freund's complete adjuvant and a mixture of aluminum-potassium sulfate and pectin appeared to enhance the activity of the GIV.

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Service-life Prediction of Reinforced Concrete Structures in Subsurface Environment (지중 환경하에서의 철근콘크리트 구조물의 열화인자별 한계수명 평가)

  • Kwon, Ki-jung;Jung, Haeryong;Park, Joo-Wan
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.1
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    • pp.11-19
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    • 2016
  • This paper focuses on the estimation of durability and service-life of reinforced concrete structures in Wolsong Low- and intermediate-level wastes Disposal Center (WLDC) in Korea. There are six disposal silos located in the saturated environment. The silo concrete is degraded due to reactions with groundwater and chemical attacks, and finally it will lose its properties as a transport barrier. The infiltration of sulfate and magnesium, leaching of potassium hydroxide, and chlorine induced corrosion are the most significant factors for degradation of reinforced concrete structure in underground environment. From the result of evaluation of the degradation time for each factor, the degradation rate of the reinforced concrete due to sulfate and magnesium is $1.308{\times}10^{-3}cm/yr$, and it is estimated to take 48,000 years for full degradation while potassium hydroxide is leached in depth of less than 1.5 cm at 1,000 years after the initiation of degradation. In case of chlorine induced corrosion, it takes 1,648 years to initiate corrosion in the main reinforced bar and 2,288 years to reach the lifetime limit of the structural integrity, and thus it is evaluated as the most significant factor.