한국응용과학기술학회지 (Journal of the Korean Applied Science and Technology)

  • 제27권1호
  • /
  • Pages.93-97
  • /
  • 2010
  • /
  • 1225-9098(pISSN)
  • /
  • 2288-1069(eISSN)
한국응용과학기술학회 (The Korean Society of Applied Science and Technology)
권호 표지
DOI QR코드

DOI QR Code

Polyoxyethylene Alkylether Sulfate 계면활성제를 사용한 무기/유기 코어-셀의 합성

Synthesis of Inorganic/Organic Core-Shell Polymer Using Polyoxyethylene Alkylether Sulfate as a Surfactant

  • 김덕술 (동명대학교 의용공학과) ;
  • 박근호 (창원대학교 화공시스템공학과)
  • Kim, Duck-Sool (Dept. of Biomedical Engineering, Tongmyong University) ;
  • Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University)
  • 투고 : 2010.03.12
  • 심사 : 2010.03.24
  • 발행 : 2010.03.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S75D) surfactant was prepared. The core-shell composite of inorganic/organic were polymerized by using styrene(St) as a shell monomer and potassium persulfate(KPS) as an initiator. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene in the presence of an anionic surfactant lauryl sulfate(SLS). The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer(TGA) and morphology of latex by scanning electron microscope(SEM).

키워드

참고문헌

  1. K. H. Park, Effect of Anionic Surfactants in Synthesizing Silicone Dioxide/Styrene Core-Shell Polymer (2), J. Kor. Oil Chem. Soc., 26(1), 66 (2009).
  2. S. E. Shim and S. J. Choe, Synthesis of Core-Shell Type Polymer/Metal Composite Nanoparticles and Their Applications, J. Kor. Ind. Eng. Chem., 14(2), 131 (2003).
  3. M. Devon, and J. Gardon, Effects of Core-Shell Latex Morphology on Film Forming Behavior, J. Appl. Polym. Sci, 39, 2119 (1990). https://doi.org/10.1002/app.1990.070391007
  4. J. M. Lim and S. D. Seol, Preparation and Characterization of Encapsulation by PMMA Core-Shell Latex, Elastomer, 38(4), 303 (2003).
  5. N. S. Kim, D. S. Kim, and K. H. Park, Synthesis of Inorganic/Organic Core-Shell Polymer, J. Kor. Oil Chem. Soc., 19(4), 265 (2002).
  6. K. P. Velikov and A. Blaaderen, Synthesis and Characterization of Monodisperse Core - shell Colloidal Spheres of Zinc Sulfide. and Silica, Langmuir, 17(16), 4779 (2001). https://doi.org/10.1021/la0101548
  7. P. Mulvaney, L. M. Liz-Marzan, M. Glersig, and T. Ung, Silica Encapsulation of Quantwn Dots and Metal Clusters, J. Mater. Chem., 10, 1259 (2000). https://doi.org/10.1039/b000136h
  8. T. Ung, L. M. Liz-Marzan, and P. Mulvaney, Controlled Method for Silica Coating of Silver Colloids. Influence of Coating on the Rate of Chemical Reactions, Langmuir, 14, 3740 (1998). https://doi.org/10.1021/la980047m
  9. S. Chang, L. Liu, and S. A. Asher, Preparation and Properties of Tailored Morphology, Monodisperse Colloidal Silica-cadmium Sulfide Nanocomposites, J. Am. Chem. Soc., 116, 6739 (1994) https://doi.org/10.1021/ja00094a032
  10. J. Wagner, T. Autenrieth, and R. Hempelmann, Core - shell Particles Consisting of Cobalt Ferrite and Silica as Model Ferrofluids CoFe204-SiO2 Coreshell Particles, J. Mag. and Mag. Mater., 252. 4 (2002). https://doi.org/10.1016/S0304-8853(02)00729-1
  11. F. G. Aliev, M. A. Correa-Duarte, A. Mamedov, J. W. Ostrander, M. Giersig, L. M. Liz-Marzan, and N. A. Kotov, Layer-by-layer Assembly of Core-shell Magnetite Nano Particles : Effect of Silica Coating on Interparticle Inter actions and Magnetic Properties, Adv. Mater., 11 (12) 1006 (1999). https://doi.org/10.1002/(SICI)1521-4095(199908)11:12<1006::AID-ADMA1006>3.0.CO;2-2
  12. K. G. Lee and K. H. Park, Preparation and Physical Properties of Poly(Styrene/Acrylate) Core-Shell Latex Particles, J. Kor. Oil Chem. Soc., 20(2), 27 (2003).
  13. J. B. Kwon, N. W. Lee, and S. D. Seul, A Consideration on Thermal Stability of the PVAc Latex Adhesive, J. Kor. Soc. of Safety, 18(3), 81 (2003).
  14. S. D. Seul, S. R. Lee, and N. W. Lee, A Development of Nontoxic Composite Latex Using $CaCO_{3}$/ PEMA, J. Kor. Soc. of Safety, 17(4), 133 (2002).
  15. D. S. Kim and K. H. Park, Effect of Anionic Surfactants in Synthesizing Silicone Dioxide/Styrene Core-Shell Polymer, J. Kor. Oil Chem. Soc., 26(2), 199 (2009).