• Title/Summary/Keyword: positions

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Cr(III)-Tetraaza Macrocyclic Complexes Containing Auxiliary Ligands (Part IV); Synthesis and Characterization of Cr(III)-Acetylacetonato, -Malonato and -Oxalato Macrocyclic Complexes

  • Byun, Jong-Chul;Han, Chung-Hun
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1395-1402
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    • 2005
  • The reaction of cis-[Cr([14]-decane)$(OH)_2]^+$ ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) with auxiliary ligands {$L_a$ = acetylacetonate (acac), oxalate (ox) or malonate (mal)} leads to a new cis-[Cr([14]-decane)(acac)]$(ClO_4)_2{\cdot}(1/2)H_2O\;(1),\;cis-[Cr([14]-decane)(ox)]ClO_4{\cdot}(1/2)H_2O\;(2)\;or\;cis-[Cr([14]-decane)(mal)]ClO_4{\cdot}(1/4)H_2O\;(3)$. These complexes have been characterized by a combination of elemental analysis, conductivity, IR and Vis spectroscopy, mass spectrometry, and X-ray crystallography. Analysis of the crystal structure of cis-[Cr([14]-decane)(acac)]$(ClO_4)_2{\cdot}(1/2)H_2O$ reveals that central chromium(III) has a distorted octahedral coordination environment and two acetylacetonate-oxygen atoms are bonded to the chromium(III) ion in the cis positions. The angle $N_{axial}-Cr-N_{axial}$ deviates by $11^{\circ}$ from the ideal value of $180^{\circ}$ for a perfect octahedron. The bond angle O-Cr-O between the chromium(III) ion and the two acetylacetonate-oxygen atoms is close to $90^{\circ}$. The bond lengths of Cr-O between the chromium and the acetylacetonate-oxygen atoms are 1.950(3) and 1.954(2) $\AA$. They are shorter than those between chromium and nitrogen atoms of the macrocycle. The IR spectra of 1, 2 and 3 display bands at 1560 {ν (C=O)}, 1710 {${\nu}_{as}$(OCO)} and 1660 $cm^{-1}$ {${\nu}_{as}$(OCO)} attributed to the acac, ox and mal auxiliary ligands stretching vibrations, respectively.

Effect of Changing positions on aged circulation (체위 변화가 노인들의 순환에 미치는 영향에 관한 연구)

  • Hong K.P.;Lee S.H.;Eun Y.;Kang H.Y.
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.2 no.2
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    • pp.239-251
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    • 1995
  • The prevalence of postural hypotension among over 65 year old men is 10-30%. The postural hypotension commonly causes the discomfort such as dizziness, irritability or fainting spell, and for the result it diminishes the quality of the life of aged. Therefore the assessment and intervention of postural hypotension during changing position is very important. The purpose of this study is to investigate the effect of changing position from supine to standing upright, from supine through left lateral to standing upright, from supine through sitting to standing upright of aged. The results obtained are as follows : 1. The average systolic blood pressure of normotension group is $132.68{\pm}16.04mmHg$ at supine position. The average diastolic blood pressure of normotension group is $80.72{\pm}9.82mmHg$ at supine position. The average systolic blood pressure of hypertension group is $153.92{\pm}20.12mmHg$ at supine position. The average diastolic blood pressure of hypertension group is $93.74{\pm}15.53mmHg$ at supine position. 2. There is no significant difference of blood pressure after three different procedures as mentioned above from supine to standing upright. 3. The prevalence of postural hypotension at standing upright is 13.5% which is 18.8% of the hypertension group and 9.4% of the normotension group. There is statistical difference of the prevalence of postural hypotension between hypertension group and normotension group.

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Molecular Phylogeny of Veneroidea (Bivalvia: Heteroconchia) on the Basis of Partial Sequences of 28S rRNA Gene (일부 28S rRNA 염기서열을 이용한 백합 상과 패류의 계통분류)

  • Kim, Sei-Chang;Kim, Jae-Jin;Hong, Hyun-Chul
    • The Korean Journal of Malacology
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    • v.21 no.2 s.34
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    • pp.147-161
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    • 2005
  • To elucidate the phylogenetic relation of the superfamily Veneroidea, we obtained partial 28S rRNA sequences of 14 heterodonts and three pteriomorphs which were collected from Korea and the sequence data of related taxa from GenBank, and analyzed maximum parsimony with PAUP program 750 of the nucleotide positions were variable, 560 of which were informative under conditions of parsimony. Total tree length was 2,765, and consistency index, homoplasy index (HI), and Retention index was 0.4843, 0.5157, and 0.6291, respectively. Intraspecific variation of 28 rRNA of Corbicula fluminea and Sinonovacula constricta was 3.1% and 1.3%, respectively. Pitarinae-Cyclininae-Meretrinae group had a clade and Samaranginae, Chioninae, and Dorsininae were clustered.

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Multi-sensor Fusion Based Guidance and Navigation System Design of Autonomous Mine Disposal System Using Finite State Machine (유한 상태 기계를 이용한 자율무인기뢰처리기의 다중센서융합기반 수중유도항법시스템 설계)

  • Kim, Ki-Hun;Choi, Hyun-Taek;Lee, Chong-Moo
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.47 no.6
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    • pp.33-42
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    • 2010
  • This research propose a practical guidance system considering ocean currents in real sea operation. Optimality of generated path is not an issue in this paper. Way-points from start point to possible goal positions are selected by experienced human supervisors considering major ocean current axis. This paper also describes the implementation of a precise underwater navigation solution using multi-sensor fusion technique based on USBL, GPS, DVL and AHRS measurements in detail. To implement the precise, accurate and frequent underwater navigation solution, three strategies are chosen. The first one is the heading alignment angle identification to enhance the performance of standalone dead-reckoning algorithm. The second one is that absolute position is fused timely to prevent accumulation of integration error, where the absolute position can be selected between USBL and GPS considering sensor status. The third one is introduction of effective outlier rejection algorithm. The performance of the developed algorithm is verified with experimental data of mine disposal vehicle and deep-sea ROV.

Development of Simulator for Weight-Variable Type Drone Base on Kinetics (무게-가변형 드론을 위한 동역학 기반 시뮬레이터 개발)

  • Bai, Jin Feng;Kim, Jung Hwan;Kim, Shik
    • IEMEK Journal of Embedded Systems and Applications
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    • v.15 no.3
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    • pp.149-157
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    • 2020
  • Regarding previously-developed drone simulators, it was easy to check their flight stability or controlling functions based on the condition that their weight was fixed from the design. However, the drone is largely classified into two types that is the one with the fixed weight whose purpose is recording video with camera and racing and another is whole weight-variable during flight with loading the articles for delivery and spraying pesticide though the weight of airframe is fixed. The purpose of this thesis is to analyze the structure of drone and its flight principle, suggest dynamics-model-based simulator that is capable of simulating weight-variable drone and develop the simulator that can be used for designing main control board, motor and transmission along the application of weight-variable drone. Weight-variable simulator was developed by using various calculation to apply flying method of drone to the simulator. First, ground coordinate system and airframe-fixing coordinate system were established and switching matrix of those two coordinates were made. Then, dynamics model of drone was established using the law of Newton and moment balance principle. Dynamics model was established in Simulink platform and simulation experiment was carried out by changing the weight of drone. In order to evaluate the validity of developed weight-variable simulator, it was compared to the results of clean flight public simulator against existing weight-fixed drone. Lastly, simulation test was performed with the developed weight-variable simulation by changing the weight of drone. It was found out that dynamics model controlled various flying positions of drone well from simulation and the possibility of securing the optimum condition of weight-variable drone that has flying stability and easiness of controlling.

A Novel Method for Estimating Representative Section Travel Times Using Individual Vehicle Trajectory Data (개별차량 주행정보를 이용한 차로별 구간대표통행시간 산출기법)

  • Rim, Hee-Sub;Oh, Cheol;Kang, Kyeong-Pyo
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.8 no.6
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    • pp.23-35
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    • 2009
  • This study proposes a methodology for estimating representative section travel times using individual vehicle travel information under the ubiquitous transportation environment (UTE). A novel approach is to substantialize a concept of dynamic node-links in processing trajectory data. Also, grouping vehicles was conducted to obtain more reliable travel times representing characteristics of individual vehicle travels. Since the UTE allows us to obtain higher accuracy of vehicle positions, travel times for each lane can be estimated based on the proposed methodology. Evaluation results show that less than 10% of mean absolute percentage error was achievable with 20% of probe vehicle rate. It is expected that outcome of this study is useful for providing more accurate and reliable traffic information services.

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An Adaptive Buffering Scheme for P2P Live Streaming Systems (P2P 라이브 스트리밍 시스템을 위한 적응적 버퍼링 기법)

  • Kim, Taeyoung;Kim, Eunsam
    • Journal of Digital Contents Society
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    • v.13 no.4
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    • pp.567-574
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    • 2012
  • In this paper, we propose a buffering scheme to improve the performance by adaptively adjusting the length of the buffering period according to the degree of data duplication among peers that belong to each specific playback period in P2P live streaming systems. To do so, we first assign all the peers into many groups depending on their playback time positions. We then determine the length of their buffering periods according to the number of peers belonging to each group. That is, we increase the length of the buffering periods when much buffered data are duplicated among peers within a group while we decrease it when few buffered data are duplicated. By simulation experiments, we show that our proposed buffering scheme can improve the performance significantly compared to the fixed length buffering scheme that have been employed in the existing mesh-based P2P systems.

Smart monitoring system with multi-criteria decision using a feature based computer vision technique

  • Lin, Chih-Wei;Hsu, Wen-Ko;Chiou, Dung-Jiang;Chen, Cheng-Wu;Chiang, Wei-Ling
    • Smart Structures and Systems
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    • v.15 no.6
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    • pp.1583-1600
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    • 2015
  • When natural disasters occur, including earthquakes, tsunamis, and debris flows, they are often accompanied by various types of damages such as the collapse of buildings, broken bridges and roads, and the destruction of natural scenery. Natural disaster detection and warning is an important issue which could help to reduce the incidence of serious damage to life and property as well as provide information for search and rescue afterwards. In this study, we propose a novel computer vision technique for debris flow detection which is feature-based that can be used to construct a debris flow event warning system. The landscape is composed of various elements, including trees, rocks, and buildings which are characterized by their features, shapes, positions, and colors. Unlike the traditional methods, our analysis relies on changes in the natural scenery which influence changes to the features. The "background module" and "monitoring module" procedures are designed and used to detect debris flows and construct an event warning system. The multi-criteria decision-making method used to construct an event warring system includes gradient information and the percentage of variation of the features. To prove the feasibility of the proposed method for detecting debris flows, some real cases of debris flows are analyzed. The natural environment is simulated and an event warning system is constructed to warn of debris flows. Debris flows are successfully detected using these two procedures, by analyzing the variation in the detected features and the matched feature. The feasibility of the event warning system is proven using the simulation method. Therefore, the feature based method is found to be useful for detecting debris flows and the event warning system is triggered when debris flows occur.

Effects of Earth's Atmosphere on Terrestrial Reference Frame : A Review (지구 대기가 지구 기준계에 미치는 영향 : 기존 모델 분석)

  • Na, Sung-Ho;Cho, Jungho
    • Geophysics and Geophysical Exploration
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    • v.18 no.3
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    • pp.133-142
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    • 2015
  • Displacement of the Earth's surface due to atmospheric loading has been recognized since a century years ago, and its accurate estimation is required in present day geodesy and surveying, particularly in space geodesy. Atmospheric load deformation in continental region can readily be calculated with the given atmospheric pressure field and the load Green's function, and, in near coastal area, approximate model is used for the calculation. The changes in the Earth's atmospheric circulation and the seasonal variation of atmospheric pressure on two hemispheres of the Earth are the each main causes of variation of the Earth's spin angular velocity and polar motion respectively. Wind and atmospheric pressure do the major role in other periodic and non-periodic perturbations of the positions in the Earth's reference frame and variations in the Earth's spin rotational state. In this reviewing study, the developments of related theories and models are summarized along with brief description of phenomena, and the geodetic perturbing effects of a hypothetical typhoon passing Korea are shown as an example. Finally related existing problems and further necessary studies are discussed in general.

The Advance Study of Human Resource Development Program Object for Community Peoples In information Society. (정보화사회에서 지역주민을 위한 진보적 인간자원개발의 방향성 연구)

  • 정종기
    • Journal of the Korea Society of Computer and Information
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    • v.3 no.2
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    • pp.217-227
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    • 1998
  • This study "The advance Study of human resource development Program Object for community Peoples in Information Society." that is too much important in Information society and IMF times. Human resource development is the process by which a community insures that it has the right number and kinds of peoples, in the right places at the right time, doing the things for which they are economically most useful. In the IMF season, an ever increasing number of cooperations are appointing executive level positions responsible for the re-enpoloyment, advancement, development of teaching, and growth of human resources. As a result, the field is being viewed as an important strategic approach to improved productivity efficiency and profitability in information society. Also, human resource development is a dynamic and evolving field in the world business. Industrial society organizations consist of three types of resources that machines, financial and human but, today have resource of organization that Knowledge, information and idea all include human. Human resource development factors will be consisted of that individual development, career development, motivation, Image making, Orignal idea development orientation and education and management time.ment time.

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