• Title/Summary/Keyword: porous foam

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Electrochemical Properties of 3D Cu-Sn Foam as Anode for Rechargeable Lithium-Ion Battery (3D-foam 구조의 구리-주석 합금 도금층을 음극재로 사용한 리튬이온배터리의 전기화학적 특성 평가)

  • Jung, Minkyeong;Lee, Gibaek;Choi, Jinsub
    • Journal of Surface Science and Engineering
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    • v.51 no.1
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    • pp.47-53
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    • 2018
  • Sn-based lithium-ion batteries have low cost and high theoretical specific capacity. However, one of major problem is the capacity fading caused by volume expansion during lithiation/delithiation. In this study, 3-dimensional foam structure of Cu-Sn alloy is prepared by co-electrodeposition including large free space to accommodate the volume expansion of Sn. The Cu-Sn foam structure exhibits highly porous and numerous small grains. The result of EDX mapping and XPS spectrum analysis confirm that Cu-Sn foam consists of $SnO_2$ with a small quantity of CuO. The Cu-Sn foam structure electrode shows high reversible redox peaks in cyclic voltammograms. The galvanostatic cell cycling performances show that Cu-Sn foam electrode has high specific capacity of 687 mAh/g at a current rate of 50 mA/g. Through SEM observation after the charge/discharge processes, the morphology of Cu-Sn foam structure is mostly maintained despite large volume expansion during the repeated lithiation/delithiation reactions.

The Effects of Cell Sizes on Compression and Bending Strength of Aluminum Material (알루미늄 소재의 미세 기공 크기가 압축 및 굽힘 강도에 미치는 영향)

  • 전용필;강충길
    • Transactions of Materials Processing
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    • v.11 no.8
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    • pp.701-709
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    • 2002
  • Aluminium foam material is highly porous material, which has the complicated cellular structure defined by randomly distributed pores in metallic matrix. This structure gives the characteristic properties which cannot be achieved by any other conventional processes. As the properties of aluminium foam material significantly depend on its porosity, a desired profile of properties can be tailored by changing the foam density. But various defects lead to undesirable effects on the mechanical properties. Mechanical properties are dependent on cell sizes and aspect ratios. Therefore, this paper presents the effects of various processing parameters of various parameters on the mechanical properties. For the sake of this, combined stirring was used to fabricate aluminum foam materials by the parameters. Compression and bending tests were performed to investigate the effects of cell sizes and aspect ratios on the mechanical properties.

Bubble breakup dynamics and flow behaviors of a surface-functionalized nanocellulose based nanofluid stabilized foam in constricted microfluidic devices

  • Wei, Bing;Wang, Yuanyuan;Wen, Yangbing;Xu, Xingguang;Wood, Colin;Sun, Lin
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.24-32
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    • 2018
  • Nanocellulose was surface-functionalized toward the applications in enhanced oil recovery (EOR) as a green alternative. The focus of this paper is on the effect of this material based nanofluid (NF) on foam lamella stabilization through studying its bubble breakup dynamics and flow behaviors in constricted mircofluidic devices. The NF stabilized foam produced an improved flow resistance across the capillary largely due to the capillary trapped bubbles at the contraction. The "snap-off" caused the NF stabilized foam to produce finer textured bubbles, which can migrate readily forward to the deep porous media, as revealed by the pressure profiles.

The Simulation about the Air Flow and Pressure Drop inside the Metal Foam (발포 금속 내 공기 유동 및 압력강하에 관한 시뮬레이션)

  • Kim, Pil-Hwan;Jin, Mei-Hua;Jang, Seok-Jun;Chung, Han-Shik;Jeong, Hyo-Min
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1053-1058
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    • 2008
  • Porous medium was considered in the present study for the heat transfer enhancement. This was attributed to its high surface area to volume ratio as well as intensive flow mixing by tortuous flow passages. But when the air or water flow through in the porous medium, it is occurred the pressure drop between inlet and outlet. So in the present study investigated simulation result about the pressure drop in the porous medium before apply to heat exchanger. In this simulation, the thickness of the solid inside the porous medium region was varied 0.2 mm to 0.4 mm. And then the simulation result were compared the pressure drop in the same unit cell ($0.5\;mm{\times}0.5\;mm{\times}0.5\;mm$). To make the analysis model, it was assumed the 14-sided tetrakaidecahedron cell which has long been considered the optimal packing cell first proposed by the Lord Kelvin in 1887. And then the simulation is carried out using by STAR-CCM+ which is commercial software. The simulation result can be showed quantified pressure drop by solid effect in the porous medium.

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Synthesis of ZSM-5 on the Surface of Foam Type Porous SiC Support (폼 형태의 다공성 탄화규소 지지체 표면 위에 ZSM-5 합성)

  • Jung, Eunjin;Lee, Yoon Joo;Won, Ji Yeon;Kim, Younghee;Kim, Soo Ryong;Shin, Dong-Geun;Lee, Hyun Jae;Kwon, Woo Teck
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.425-430
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    • 2015
  • ZSM-5 crystals grew by hydrothermal synthesis method on the surface of foam type porous silicon carbide ceramics which fabricated by polymer replica method. Oxide layer was developed on the surface of the porous silicon carbide ceramics to induce growth of ZSM-5 from the surface. In this study, hydrothermal synthesis was carried out for 7 h at $150^{\circ}C$ using TEOS, $Al(NO_3){\cdot}9H_2O$ and TPAOH as raw materials in the presence of the porous silicon carbide ceramics. X-ray Powder Diffraction (XRD) and Scanning Electron Microscope (SEM) analyses were confirmed $1{\sim}3{\mu}m$ sized ZSM-5 crystals have grown on the surface of porous silicon carbide ceramics. BET data shows that small pores about $10{\AA}$ size drastically enhanced and surface area increased from $0.83m^2/g$ to $30.75m^2/g$ after ZSM-5 synthesis on the surface of foam type porous silicon carbide ceramics.

Nanowire-Like Copper Oxide Grown on Porous Copper, a Promising Anode Material for Lithium-Ion Battery

  • Park, Hyeji;Lee, Sukyung;Jo, Minsang;Park, Sanghyuk;Kwon, Kyungjung;Shobana, M.K.;Choe, Heeman
    • Journal of the Korean Ceramic Society
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    • v.54 no.5
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    • pp.438-442
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    • 2017
  • This paper reports the facile synthesis of microlamella-structured porous copper (Cu)-oxide-based electrode and its potential application as an advanced anode material for lithium-ion batteries (LIBs). Nanowire-like Cu oxide, which is created by a simple thermal oxidation process, is radially and uniformly formed on the entire surface of Cu foam that has been fabricated using a combination of water-based slurry freezing and sintering (freeze casting). Compared to the Cu foil with a Cu oxide layer grown under the same processing conditions, the Cu foam anode with 63% porosity exhibits over twice as much capacity as the Cu foil (264.2 vs. 131.1 mAh/g at 0.2 C), confirming its potential for use as an anode electrode for LIBs.

Nonlocal strain gradient thermal vibration analysis of double-coupled metal foam plate system with uniform and non-uniform porosities

  • Fenjan, Raad M.;Ahmed, Ridha A.;Alasadi, Abbas A.;Faleh, Nadhim M.
    • Coupled systems mechanics
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    • v.8 no.3
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    • pp.247-257
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    • 2019
  • Fee vibrational characteristics of porous steel double-coupled nanoplate system in thermo-elastic medium is studied via a refined plate model. Different pore dispersions called uniform, symmetric and asymmetric have been defined. Nonlocal strain gradient theory (NSGT) containing two scale parameters has been adopted to stablish size-dependent modeling of the system. Hamilton's principle has been adopted to stablish the governing equations. Obtained results from Galerkin's method are verified with those provided in the literature. The effects of nonlocal parameter, strain gradient, foundation parameters, porosity distributions and porosity coefficient on vibration frequencies of metal foam nanoscale plates have been examined.

A new absorbing foam concrete: preparation and microwave absorbing properties

  • Xingjun, Lv;Mingli, Cao;Yan, Li;Xin, Li;Qian, Li;Rong, Tang;Qi, Wang;Yuping, Duan
    • Advances in concrete construction
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    • v.3 no.2
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    • pp.103-111
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    • 2015
  • The foam concrete was fabricated by adding the foaming agent which composite ordinary Portland cement with plant and animal protein into cement paste, and the electromagnetic wave absorption properties were studied for the first time as well. The studies showed that the electromagnetic waves can be absorbed by multiple reflections and scattering within the porous material. Thickness and filling ratio have a great influence on the electromagnetic wave absorbing properties in 2-18 GHz of the foam concrete, the greater the thickness, the better the performance of absorption; filling ratio was about 52 vol.%, the absorbing properties achieved the best.

Cooling Effect of a Heated Porous Plate by Droplets Impingement - A Preliminary Study (가열 상태의 다공성 판에 충돌하는 액적의 냉각 성능에 대한 기초 연구)

  • Ryu, S.U.;Kim, W.S.;Lee, S.Y.
    • Journal of ILASS-Korea
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    • v.14 no.1
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    • pp.20-27
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    • 2009
  • In the present work, effects of spray characteristics (droplet size and velocity) on the temperature variation of a heated porous plate (Melamine foam) have been investigated through a series of experiments. Based on the measured data, time required to cool down the hot porous material turned out to be shorten by doing with the smaller droplet size and/or smaller impinging velocity. In particular, the droplet size effect is more prominent than the impinging velocity. The cooling performance in the porous material is directly proportional to the penetration velocity.

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The Performance Characteristics of the Open Celled Aluminum Foam Applied for Heat Dissipation (다공성 알루미늄 방열핀의 성능특성 연구)

  • Kim, Jong-Soo;Lee, Hyo-Jin
    • Journal of the Korean Solar Energy Society
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    • v.23 no.2
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    • pp.91-98
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    • 2003
  • Experimental study for a porous aluminum heat dissipator/or heat sink made by casting method is conducted to evaluate the performance of the porous aluminum heat sinks. The parameters applied for the present study are the manufacturing method. various bonding materials for the bottom plate of heat sink, and their different material, pore size, etc.. The casting method for porous aluminum heat sink is suggested for the best performance of heat dissipation in this experiment. The bottom plate applied by melting aluminum is introduced and proved their excellent characteristics compared with brazing, soldering, and bonding methods. In the present experiment, aluminum with different conductivities, such as AC8A and pure aluminum, are tested and the pure aluminums with the higher conductivity than AC8A shows their improvement of the performance. And the proper dimensions related to the pore size and the height of porous aluminum heat sinks are proposed in the present study.