• Title/Summary/Keyword: porosity reduction

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Effect of Freeze Drying Condition of WO3/Tert-Butyl Alcohol Slurry on the Microstructural Characteristics of Porous Body (WO3/tert-butyl alcohol 슬러리의 동결건조 조건이 다공체의 미세구조 특성에 미치는 영향)

  • Lee, Eui Seon;Heo, Youn Ji;Suk, Myung-Jin;Oh, Sung-Tag
    • Journal of Powder Materials
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    • v.28 no.4
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    • pp.331-335
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    • 2021
  • The effects of drying temperature on the microstructure of porous W fabricated by the freeze-casting process of tert-butyl alcohol slurry with WO3 powder was investigated. Green bodies were hydrogen-reduced at 800℃ for 1 h and sintered at 1000℃ for 6 h. X-ray diffraction analysis revealed that WO3 powders were completely converted to W without any reaction phases by hydrogen reduction. The sintered body showed pores aligned in the direction of tert-butyl alcohol growth, and the porosity and pore size decreased as the amount of WO3 increased from 5 to 10vol%. As the drying temperature of the frozen body increased from -25℃ to -10℃, the pore size and thickness of the struts increased. The change in microstructural characteristics based on the amount of powder added and the drying temperature was explained by the growth behavior of the freezing agent and the degree of rearrangement of the solid powder during the solidification of the slurry.

Effective study of operating parameters on the membrane distillation processes using various materials for seawater desalination

  • Sandid, Abdelfatah Marni;Neharia, Driss;Nehari, Taieb
    • Membrane and Water Treatment
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    • v.13 no.5
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    • pp.235-243
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    • 2022
  • The paper presents the effect of operating temperatures and flow rates on the distillate flux that can be obtained from a hydrophobic membrane having the characteristics: pore size of 0.15 ㎛; thickness of 130 ㎛; and 85% porosity. That membrane in the present investigation could be the direct contact (DCMD) or the air-gap membrane distillation (AGMD). To model numerically the membrane distillation processes, the two-dimensional computational fluid dynamic (CFD) is used for the DCMD and AGMD cases here. In this work, DCMD and AGMD models have been validated with the experimental data using different flows (Parallel and Counter-current flows) in non-steady-state situations. A good agreement is obtained between the present results and those of the experimental data in the literature. The new approach in the present numerical modeling has allowed examining effects of the nature of materials (Polyvinylidene fluoride (PVDF) polymers, copolymers, and blends) used on thermal properties. Moreover, the effect of the area surface of the membrane (0.021 to 3.15 ㎡) is investigated to explore both the laminar and the turbulent flow regimes. The obtained results found that copolymer P(VDF-TrFE) (80/20) is more effective than the other materials of membrane distillation (MD). The mass flux and thermal efficiency reach 193.5 (g/㎡s), and 83.29 % using turbulent flow and an effective area of 3.1 ㎡, respectively. The increase of feed inlet temperatures and its flow rate, with the reduction of cold temperatures and its flow rate are very effective for increasing distillate water flow in MD applications.

Fabrication of Ti-Mo Core-shell Powder and Sintering Properties for Application as a Sputtering Target (Ti-Mo 코어-쉘 분말 제조 및 소결 특성 연구)

  • Won Hee Lee;Chun Woong Park;Heeyeon Kim;Yuncheol Ha;Jongmin Byun;Young Do Kim
    • Journal of Powder Materials
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    • v.31 no.1
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    • pp.43-49
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    • 2024
  • In this study, a core-shell powder and sintered specimens using a mechanically alloyed (MAed) Ti-Mo powder fabricated through high-energy ball-milling are prepared. Analysis of sintering, microstructure, and mechanical properties confirms the applicability of the powder as a sputtering target material. To optimize the MAed Ti-Mo powder milling process, phase and elemental analyses of the powders are performed according to milling time. The results reveal that 20 h of milling time is the most suitable for the manufacturing process. Subsequently, the MAed Ti-Mo powder and MoO3 powder are milled using a 3-D mixer and heat-treated for hydrogen reduction to manufacture the core-shell powder. The reduced core-shell powder is transformed to sintered specimens through molding and sintering at 1300 and 1400℃. The sintering properties are analyzed through X-ray diffraction and scanning electron microscopy for phase and porosity analyses. Moreover, the microstructure of the powder is investigated through optical microscopy and electron probe microstructure analysis. The Ti-Mo core-shell sintered specimen is found to possess high density, uniform microstructure, and excellent hardness properties. These results indicate that the Ti-Mo core-shell sintered specimen has excellent sintering properties and is suitable as a sputtering target material.

A Study on Residual Stress Reduction Effect of Cold Spray Coating to Improve Stress Corrosion Cracking of Stainless Steel 304L and 316L Welds (STS304L 및 STS316L 용접부의 응력 부식 균열 개선을 위한 저온 분사 코팅의 잔류 응력 감소 효과에 대한 연구)

  • Kwang Yong Park;Deog Nam Shim;Jong Moon Ha;Sang Dong Lee;Sung Woo Cho
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.19 no.2
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    • pp.102-108
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    • 2023
  • A Chloride-induced stress corrosion cracking (CISCC) of austenite stainless steel in dry cask storage system (DCSS) can occur with extending service time than originally designed. Cold spray coating (CSC) not only form a very dense microstructure that can protect from corrosive environments, but also can generate compressive stress on the surface. This characteristic of CSC process is very helpful to increase the resistance for CISCC. CSC with several powders, such as 304L, 316L and Ni can be optimized to form very dense coating layer. In addition, the impact energy generated as the CSC powder collides with the surface of base metal at a speed of Mach 2 or more can remove the residual tensile stress of welding area and serve the compress stress. CSC layers include no oxidation and no contamination with under 0.2% porosity, which is enough to protect from the penetration of corrosive chloride. Therefore, the CSC coating layer can be accompanied by a function that can be disconnected from the corrosive environment and an effect of improving the residual stress that causes CISCC, so the canister's CISCC resistance can be increased.

Assessment of CO2 Geological Storage Capacity for Basalt Flow Structure around PZ-1 Exploration Well in the Southern Continental Shelf of Korea (남해 대륙붕 PZ-1 시추공 주변 현무암 대지 구조의 CO2 지중저장용량 평가)

  • Shin, Seung Yong;Kang, Moohee;Shinn, Young Jae;Cheong, Snons
    • Economic and Environmental Geology
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    • v.53 no.1
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    • pp.33-43
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    • 2020
  • CO2 geological storage is currently considered as the most stable and effective technology for greenhouse gas reduction. The saline formations for CO2 geological storage are generally located at a depth of more than 800 m where CO2 can be stored in a supercritical state, and an extensive impermeable cap rock that prevents CO2 leakage to the surface should be distributed above the saline formations. Trough analysis of seismic and well data, we identified the basalt flow structure for potential CO2 storage where saline formation is overlain by basalt cap rock around PZ-1 exploration well in the Southern Continental Shelf of Korea. To evaluate CO2 storage capacity of the saline formation, total porosity and CO2 density are calculated based on well logging data of PZ-1 well. We constructed a 3D geological grid model with a certain size in the x, y and z axis directions for volume estimates of the saline formation, and performed a property modeling to assign total porosity to the geological grid. The estimated average CO2 geological storage capacity evaluated by the U.S. DOE method for the saline formation covered by the basalt cap rock is 84.17 Mt of CO2(ranges from 42.07 to 143.79 Mt of CO2).

Experimental Investigation of the Drag Coefficient of Porous Road Signs (유공형 도로표지의 항력계수에 대한 실험적 연구)

  • Sung, Hongki;Chong, Kyusoo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.71-76
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    • 2018
  • Recently, various technologies have been developed for road facilities to reduce the load, some of which use technologies employing perforated plates for wind load reduction. Currently, there are no regulations concerning the drag coefficient of perforated plates for domestic road facilities. In the United States, the regulations regarding the drag coefficient of perforated plates in the 'Minimum design loads for buildings and other structures' were revised based on the studies of Letchford (2001) and Giannoulis (2012). In this study, a wind tunnel test was carried out to analyze the feasibility of applying regulations involving the perforated plates' drag coefficient. The results of the wind tunnel test and the drag coefficient used in the regulation were compared and analyzed. In addition, the reduction effect of the cross area of road signs calculated by applying the drag coefficient was analyzed. The results of the wind tunnel test and the value of the drag coefficient used in the regulation in the US were found to be very similar. Therefore, it was found that it is possible to apply the formula involving the drag coefficient of the perforated plate to the regulation and that the cross area of the perforated plate used for the post of the road sign is reduced by about 9.45% and that of the horizontal post by about 6.45%.

A Study on Influence of Firing Temperature and Temper Content on the Physical Properties of Earthenware Coffin (소성온도와 혼입물 함량이 옹관의 물성에 주는 영향에 관한 연구)

  • Kim, Kyu Been;Chung, Kwang Yong
    • Journal of Conservation Science
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    • v.30 no.4
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    • pp.373-381
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    • 2014
  • Adding temper into clay prevents to shrink and crack, or twist the clay during the dry process. The purpose of this study is to identify the role of temper and the physical property of earthenware coffin according to the clay state modification in the reduction firing based on earthenware coffins found in Naju which had been made in Three Kingdom Period. Clay from the Oryang-dong site in Naju was used as circle shaped samples. The samples were tempered with various proportions (0%, 20%, 40%) and fired in various temperature ($1000^{\circ}C$, $1100^{\circ}C$, $1200^{\circ}C$). Physical properties were identified by macroscopy, an optical microscope (x50), specific gravity and porosity. Chemical components and existence of specific minerals were identified by analysing XRF and XRD. As a result, the more firing temperature increase, clay volume expansion. To prevent the volume expansion, temper was added.

The Evaluation on the exiting greens of Hwasan Country Club by undisturbed Soil Core Analysis (토양 코아 분석을 통한 화산 골프장의 조성된 그린에 대한 평가)

  • 이상재;허근영;심경구
    • Journal of the Korean Institute of Landscape Architecture
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    • v.26 no.2
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    • pp.54-61
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    • 1998
  • The subsurface environment of the root zone area can set the stae for "do or die" of the turfgrass plant. The good condition of the greens is verified by their physical properties. Therefore, this study was carried to evaluate on the existing green of Hwasan C.C. by undisturbed soil Core Anaysis. We completed the ISTRC SYSTEM BenchMarking of the undisturbed core samples taken from Green #1, Green #5, Green #9-"Best" area, and Green #9-"Stressed" area for the Hwasan C.C.. It was also our understanding that the greens were in "good" to "very good" conditioni. THe exception might be Green #9-"Stress" area, which was the stressed area. The stressed area was confined to a ridge across Green #9. The organic content test results comfirmed the development of organic layering in depth 0-2.5cm. For the amount of compaction in the upper root zones and te development of the green's respective organic layers, the infiltration rates were high in Green #1, Green #5, and Green #9 "Stressed" area. The depicted aerificaton hole might be the probable cause of the relatively high infiltraton rate. Green #9-"Best" area had a tested infiltration rate of 18.75cm/hr. Either this area had not been aerified, or the undisturbed sample did not contain a aerification cavity. The water retention capacity of the undisturbed samples was good. When the greens were first constructed, the original root zone mix had been relatively low water retention properties. And the bulk density and the porosity of the undisturbed samples were good. In the result, all the greens were similar except for the infiltration. Thus, we supposed that Green #9-"Stressed" area might be ainly influenced by the amount of irrigation water and the configuration of the green's surface. There had been a reduction in the amount of irrigation water as the water retention capacity in the greens was promoted. Especially, it had gradually become more of a problem as the green had matured in Green #9-"Stressed" area. Because Green #9-"Stressed" area was a ridge area. The reduction in the amount of irrigation water might be the probable cause of the stress in Green #9-"Stressed" area. Our final observation related to the soil texture and the particle size distribution of the sand. Though and sand contant of all the tested greens were good, the gravel content of them exceeded ISTRC Guidelines. In particle size distribution of the sand, the very coarse and the coarse content of all the tested greens exceeded, but the rest was insufficient. The stability is a function of the material retained on the 0.25mm mesh screen. But, the content of all the tested greens was very insufficient. Though all the greens was serviceable, the coarse root zone sands, such as the sand in the tested greens, tended to be "unstable". Thus, we recommend using a topdressing/aerification sand which should be more in line with ISTRC/USGA Guidelines.;unstable". Thus, we recommend using a topdressing/aerification sand which should be more in line with ISTRC/USGA Guidelines.ines.

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Evaluation of the Performance of Woodchip-filled Infiltration Trench Treating Stormwater from Highway (고속도로 강우유출수 처리를 위한 우드칩 충진 침투도랑의 성능평가)

  • Park, Kisoo;Kang, Heeman;Kim, Youngchul
    • Journal of Wetlands Research
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    • v.18 no.2
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    • pp.183-193
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    • 2016
  • In this study, design and performance of infiltration trench using woodchip as media for treating stormwater from highway were examined through field monitoring. Average reduction efficiency for TSS, COD, BOD, TN, and TP was 88%, 94%, 85%, 80%, and 75% respectively, which is similar to values reported by other studies and design manuals even though direct comparison is not possible due to different monitoring and design conditions. Mean field infiltration rate estimated by measuring the change of water depth inside the observation well was about 40mm/hr, and the time taken for complete infiltration was about 0.83days, which corresponds well with design criteria recommended by MOE guidelines in Korea. In addition, according to analysis of infiltration rate and reduction efficiency, effective rainfall depth applied for determining water quality volume(WQv), 5mm was found to be properly established as design criteria. Woodchip must be considered and included as an alternative media together with crushed rock and gravel into the design guidelines because it has more advantages in terms of weight, porosity, cost, and easiness of management than other media materials.

Geomechanical properties of synthesised clayey rocks in process of high-pressure compression and consolidation

  • Liu, Taogen;Li, Ling;Liu, Zaobao;Xie, Shouyi;Shao, Jianfu
    • Geomechanics and Engineering
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    • v.20 no.6
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    • pp.537-546
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    • 2020
  • Oil and natural gas reserves have been recognised abundantly in clayey rich rock formations in deep costal reservoirs. It is necessary to understand the sedimentary history of those reservoir rocks to well explore these natural resources. This work designs a group of laboratory experiments to mimic the physical process of the sedimentary clay-rich rock formation. It presents characterisation results of the physical properties of the artificial clayey rocks synthesized from illite clay, quartz sand and brine water by high-pressure consolidation tests. Special focus is given on the effects of illite clay content and high-stress consolidation on the physical properties. Multi-step loaded consolidation experiments were carried out with stress up to 35 MPa on mixtures constituting of the illite clay, quartz sand and brine water with five initial illite clay contents (w=85%, 70%, 55%, 40% and 25%). Compressibility and void ratio were characterised throughout the physical compaction process of the mixtures constituting of five illite clay contents and their water permeability was measured as well. Results show that the applied stress induces a great reduction of clayey rock void ratio. Illite clay contents has a significant influence on the compressibility, void ratio and the permeability of the physically synthesized clayey rocks. There is a critical illite clay content w=70% that induces the minimum void ratio in the physically synthesised clayey rocks. The SEM study indicates, in the high-pressure synthesised clayey rocks with high illite clay contents, the illite clay minerals are located in layers and serve as the material matrix, and the quartz minerals fill in the inter-mineral pores or are embedded in the illite clay matrix. The arrangements of the minerals in microscale originate the structural anisotropy of the high-pressure synthesised clayey rock. The test findings can give an intuitive physical understanding of the deep-buried clayey rock basins in energy reservoirs.