• Title/Summary/Keyword: pore-size

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Preparation of Porous Glasses by the Phase-separation of the Silicate Glass Containing $TiO_2$ ($TiO_2$를 함유한 규산염 유리의 상분리를 이용한 다공질 유리의 제조)

  • 김병훈;최석진;박태철
    • Journal of the Korean Ceramic Society
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    • v.28 no.1
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    • pp.29-36
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    • 1991
  • Microporous glasses in the system TiO2-SiO2-Al2O3-B2O3-CaO-Na2O were prepared by the phase-separation technique. Morphology and distribution of pore and specific surface area of glasses heated and leached out at various conditions were investigated by SEM and Porosimeter. Crystallization of glasses heated above transition temperature was also inspected by X-ray diffraction method. When the heating temperature and time increased, the pore size and volume increased, but the specific surface area decreased above the critical temperature. The phase-separation, specific surface area and pore size showed more sensitive change on the variation of heating temperature than of heating time. The specific surface area and micropore volume of porous glasses prepared in this study were about 120-330$m^2$/g and 0.001-0.01cc/g, respectively. Mean pore size of porous glasses were about 20-90$\AA$. Anatase phases was deposited when the parent glass was heat-treated at 75$0^{\circ}C$ for 6hrs.

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APPLICATIONS OF PORE AND GRAIN-SIZE DISTRIBUTIONIN RECOVERY OF LNAPLS IN SOILS (토양속의 LAPLs 제거기슬에서의 Pore와 입도분포의 응용에 관한 연구)

  • Lee, Kwang-Y.
    • Proceedings of the Korean Geotechical Society Conference
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    • 1992.12a
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    • pp.19-32
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    • 1992
  • Objectives of this study are : 1) to utilize capillary theory and obtain pore-size distribution profiles from moisture-suction relationships using Laplace theory. 2) to investigate the behavior of Light Non-Aqueous Phase Liquids(LNAPLs) in the subsurface environment and to develop several predictive relationships which can be used to assess the effectiveness of various LNAPLs remediation technologies. The relationship to predict pore-size distribution function expressed in differencial equation is found by using capillary theory. Also, experiments are conducted to : the various LNAPLs subjected to vadose zone drainage, groundwater table drainage, waterflooding with surfactants. The experiments are performed with #2 heating oil, jet fuel. and kerosene. Several relationships have been derived describing the effect of various properties and process parameters on the LNAPL residual saturation.

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Effect of Hollow Composite Yarn Characteristics to the Comfort Property of Fabrics for High Emotional Garment (중공 복합사 특성이 고감성 의류용 직물의 쾌적성에 미치는 영향)

  • Kim, Hyun-Ah
    • Science of Emotion and Sensibility
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    • v.17 no.4
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    • pp.71-78
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    • 2014
  • Composite draw textured yarns(DTY) and air jet textured yarns(ATY) with hollow PET filament have been used for making high emotional fabrics including light weight sports wear garments. This study investigated effect of hollow composite yarns and fabric structural parameters to the comfort properties related to the moisture and thermal transport phenomena for the composite fabrics made of DTY and ATY with hollow PET filament. Wicking property of hollow composite fabric was superior at the high pore size fabric and was not influenced by fabric cover factor. Wicking property of the fabric with ATY was better than that of the fabric with DTY. On the other hand, drying rate of fine pore sized fabric was shorter than that of large pore sized fabric and drying rate of high multi yarn fabric with low cover factor and small pore size was superior than that of hollow composite fabric. The pore size of the fabric was dominant factor in the air permeability and thermal conductivity of hollow composite fabric. High pore sized fabric showed high air permeability and thermal conductivity of hollow composite fabric was nonlinearly inversely proportional to pore size of the fabric.

A study on selective hybrid-structure film fabricated by 355nm UV-pulsed laser processing (355nm UV 레이저를 이용한 선택적 하이브리드 구조 필름의 제작에 관한 연구)

  • Kim, Myung-Ju;Lee, Sang-Jun;Shin, Bo-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.5
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    • pp.2979-2984
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    • 2015
  • This paper has presented a new foaming technology of selective hybrid-structured polymer film with expanded pores. The porous structure of closed pore was firstly fabricated by applying the 355nm UV-pulsed laser to 0.1mm thick film that was uniformly mixed with PP pellets, copper powder, and CBA (Chemical Blowing Agent). In order to expand pore size of closed-cell shape, LAMO(Laser Aided Micro pore Opening) processing was conducted to heat the copper powder, and then the bigger pore size of closed-cell more than existing pore size was successfully formed because of rapid conduction of heated metal powder. From the experimental results, various process parameters such as laser fluence, intensity, scan rate, spot size and density of powder and CBA were considerably considered to reveal the correlation among the pore characteristics. In the future, a function experiment will be carried out to use the hybrid film of industrial applications.

Development of Selective Adsorption Process with Various Pore Size A-type Zeolite on Removal of Acetylenes for Isoprene Purification (제올라이트 A를 이용하여 이소프렌에서 아세틸렌 제거를 위한 선택적 흡착공정 개발)

  • Jun, Kyung-Jin;Ahn, Byoung-Sung;Yoo, Kye-Sang
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.548-552
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    • 2010
  • This study focused on the development of effective adsorbent to remove acetylenes for the purification of isoprene. The adsorbents with various pore sizes from $4{\AA}$ to $5{\AA}$ were prepared to investigate the effect of pore size on selective adsorption of acetylene as an impurity. The pore size of zeolite A was adjusted by ion-exchange between Na and Ca ions. The pore size of adsorbents has affected the removal of acetylenes selectively because of the kinetic diameter of acetylenes, such as 2-methyl-1-butyne-3-yen (IPA) and 2-butyne. In a batch adsorption experiment, 5A zeolite with pore size of $5{\AA}$ showed the highest removal capacity of 2-butyne. However, IPA was hardly removed from isoprene by the A-type zeolites. For the adsorption isotherm, modified Langmuir model was well fitted with 2-butyne adsorption. Moreover, the regeneration of adsorbent was carried out to determine optimum method. The adsorbent heated for 12 h at $300^{\circ}C$ was regenerated significantly.

Analysis of Pore Structure for Porous Body with Coal Fly ash and Clay (석탄회-점토계 다공체의 기공구조 분석)

  • 이기강;박천주
    • Korean Journal of Crystallography
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    • v.9 no.1
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    • pp.64-70
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    • 1998
  • Porous body was prepared from coal fly ash 70 wt%0clay 30 wt% slip using DCC(Direct Coagulated Casting) method. Effect of the specific gravity of the slip on the pore size and distribution of the sintered body was examined by the SEM observation of microstructure and mercury porosimetry measurement of the pore size distribution. Average pore size of the porous sintered body was about 2.5μm for all slips with specific gravity of 1.55, 1.60 and 1.65g/cm3, respectively. Sintered body prepared from the slip of specific gravity of 1.60g/cm3 have the narrowest pore size distribution. slip of specific gravity of 1.55g/cm3 shows broader pore size distribution due to slow gellation process. Slip of specific gravity of 1.65g/cm3 required large amount of deflocculant and showed large variation of the viscosity with addition of coagulant which resulted in very unstable slip properties.

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Microstructural Change of Doped-Alumina Membrane (도핑된 알루미나 여과막의 미세구조 변화)

  • 이진하;최성철;한경섭
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1040-1047
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    • 1999
  • After alumina sol was prepared by Yoldas process supported membranes were fabricated by adding ce and Re solution and SiO2 sol into alumina sol. The particle size of alumina sol was 11 nm and it was monodispersed transparent and stable for long time. The pore size of un-doped membrane started to increase to about 7,5nm at 1000$^{\circ}C$ and it was grown to twice (about 15nm) at 1100$^{\circ}C$ However the pore size of doped alumina was uniform to 1100$^{\circ}C$. The effect of retardation of grain growth was superior in SiO2 addition to that of Ce and Ru Because SiO2 doped samples transformed to needed-like phase and densified at 1200$^{\circ}C$ their application in membranes was limited. Ce and Ru doped sample showed vermicular structure identical to the un-doped ones at 1200$^{\circ}C$ But the particle size was smaller than that of un-doped ones.

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Manufacture of SiC matrix for PAFC (인산형 연료전지용 SiC MATRIX 제조)

  • 김영우;이주성
    • Journal of Energy Engineering
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    • v.2 no.2
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    • pp.187-193
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    • 1993
  • Porous matrices to contain and support phosphoric acid were prepared with PTFE as binder and SiC whisker or SiC powders of various particle size for phosphoric acid fuel cell(PAFC). Among the matrix characteristics the most important factors in stack performances were thought to be the bubble pressure and electrolyte wettability And then matrix was constructed to have pore size smaller than that of electrode. The bubble pressures and wettabilities of matrices manufactured with various size of SiC and different PTFE contents were investigated and related with the porosities measured by porosimeter, and then the optimum manufacturing condition of matrix for PAFC was determined.

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Effects of Raw Materials for Papermaking and Physical Treatment on the Pore Structure and Paper Properties (제지 원료의 특성 및 물리적 처리가 종이의 기공 구조 및 물성에 미치는 영향)

  • Won, Jong-Myoung;Nam, Ki-Young;Chung, Soon-Ki
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.4
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    • pp.7-13
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    • 2007
  • Effects of pulp type, refining and filler type on the pore characteristics and physical properties of paper were investigated. HwBKP, SwBKP and BCTMP are used to study the effect of pulp type in this study. The effects of each filler (PCC, GCC and talc) and the combination of PCC/GCC were also studied. Highest bulk, pore volume and light scattering are obtained from BCTMP and PCC. It was found that the pore size and pore volume are important in light scattering in paper structure. It was found that PCC was the most effective filler for the improvement of the bulk and light scattering because of the increase in pore volume which can scatter light, but the increase of PCC content was not so effective in the improvement of bulk.

The Effect of Sintering Condition On Tribological Behavior in the Cu-Base Sintered Friction Materials (동계 소결마찰재의 소결조건에 따른 마찰특성 고찰)

  • 김상호;김기열;정진현;이범주;정동윤
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1997.04a
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    • pp.53-61
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    • 1997
  • The effect of sintering condition on tribological behavior in the Cu-base sintered friction materials was studied through pin-on-disk type wear tester. Especially, the experiment was focused on making a comparative study between presstwed sintering and pressureless sintering. Pressureless sintering process showes more stable friction coefficient and lower wear rate than pressure sintering process. This result is related to pore size and density of pore in the sintered materials.

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