• Title/Summary/Keyword: pore scale

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Removal of Benzene in Solution by using the Bio-carrier with Dead Bacillus drentensis sp. and Polysulfone (Bacillus drentensis sp. 사균과 polysulfone으로 이루어진 미생물담체를 이용한 수용액 내 벤젠 제거)

  • Park, Sanghee;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.18 no.1
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    • pp.46-56
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    • 2013
  • Laboratory scale experiments to remove benzene in solution by using the bio-carrier composed of dead biomass have been performed. The immobilized bio-carrier with dead Bacillus drentensis sp. and polysulfone was manufactured as the biosorbent. Batch sorption experiments were performed with bio-carriers having various quantities of biomass and then, their removal efficiencies and uptake capacities were calculated. From results of batch experiments, 98.0% of the initial benzene (1 mg/L) in 1 liter of solution was removed by using 40 g of immobilized bio-carrier containing 5% biomass within 1 hour and the biosorption reaction reached in equilibrium within 2 hours. Benzene removal efficiency slightly increased (99.0 to $99.4%{\pm}0.05$) as the temperature increased from 15 to $35^{\circ}C$, suggesting that the temperature rarely affects on the removal efficiency of the bio-carrier. The removal efficiency changed under the different initial benzene concentration in solution and benzene removal efficiency of the bio-carrier increased with the increase of the initial benzene concentration (0.001 to 10 mg/L). More than 99.0% of benzene was removed from solution when the initial benzene concentration ranged from 1 to 10 mg/L. From results of fitting process for batch experimental data to Langmuir and Freundlich isotherms, the removal isotherms of benzene were more well fitted to Freundlich model ($r^2$=0.9242) rather than Langmuir model ($r^2$=0.7453). From the column experiment, the benzene removal efficiency maintained over 99.0% until 420 pore volumes of benzene solution (initial benzene concentration: 1 mg/L) were injected in the column packed with bio-carriers, investigating that the immobilized carrier containing Bacillus drentensis sp. and polysulfone is the outstanding biosorbent to remove benzene in solution.

$C_a/C_c$ for Marine Clay at Southern Part of Korea by Laboratory Consolidation Tests (실내압밀시험에 의한 남해안 해성점토의 $C_a/C_c$)

  • 김규선;임형덕;이우진
    • Journal of the Korean Geotechnical Society
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    • v.15 no.6
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    • pp.87-98
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    • 1999
  • Consolidation settlements on soft clay are often greatly and potentially damaging to structures. Currently, large-scale projects are in planning or progressing in Korea. These structures will be constructed on both thick and soft clay layers, and so the accurate evaluation of magnitude of settlement is required at every step in design and construction. Especially, secondary compression may play an important role in consolidation settlements of soft clay. Generally, the magnitudes of secondary compression are evaluated by laboratory and in-situ consolidation tests. The empirical $C_a/C_c$ may be economical, fast and powerful tool in estimating secondary consolidation settlement. However, the databases of the $C_a/C_c$ at construction site in Korea are insufficient. The purpose of this study is to investigate the relationship of $C_a/C_c$ on marine clay near the southern sea in Korea. A series of incremental loading consolidation tests (measuring base pore water pressure) is peformed. It was found that the $C_a/C_c$ on undisturbed marine clay is 0.0397.

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Evaluation of the Numerical Liquefaction Model Behavior with Drainage Condition (배수조건에 따른 액상화 수치모델의 거동평가)

  • Lee, Jin-Sun;Kim, Seong-Nam;Kim, Dong-Soo
    • Journal of the Korean Geotechnical Society
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    • v.35 no.11
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    • pp.63-74
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    • 2019
  • Numerical liquefaction model and response history analysis procedure are verified based on dynamic centrifuge test results. The test was a part of the Liquefaction Experiments Analysis Project (LEAP). The model ground was formed inside of rigid box by using the submerged Ottawa F65 sand with a relative density of 55% and 5° of surface inclination. A tapered sinusoidal wave with a frequency of 1 Hz was applied to the base of the model box. Numerical analyses were performed by two dimensional finite difference method in prototype scale. The soil is modeled to show hysteretic behavior before shear failure, and Mohr-Coulomb model is applied for shear failure criterion. Byrne's liquefaction model was applied to track the changes in pore pressure due to cyclic loading after static equilibrium. In order to find an appropriate flow condition for the liquefaction analysis, numerical analyses were performed both in drained and undrained condition. The numerical analyses performed under the undrained condition showed good agreement with the centrifuge test results.

Surface Characterization of NF membranes for Hardness Removal and Its Implications to Fouling Mechanisms (경도제거용 나노여과막의 표면 특성 분석 및 막오염기작 연구)

  • Ham, Sangwoo;Kim, Youngjin;Kim, Chunghwan;Shon, Hokyong;Hong, Seungkwan
    • Journal of Korean Society on Water Environment
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    • v.29 no.4
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    • pp.559-567
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    • 2013
  • In recent years, NF (nanofiltration) membrane has been receiving great attention for hardness removal and has begun to replace traditional lime soda ash softening process, particularly in Florida, USA, mainly due to less sludge production and easy operation. This study aimed to provide detailed surface characteristics of various commercial NF membranes by performing sophisticated surface analysis, which would help more fundamentally understand the performance of NF membranes. More specifically, a total of 7 NF membranes from top NF/RO manufacturers in the world were examined for basic performance tests, surface analysis, and fouling potential assessment. The results demonstrated that NF membranes are classified into two groups in terms of surface zeta potential; they are highly negatively charged ones, and neutral and/or less negatively charged ones. Their hydrophobicities, measured by contact angle, varied from hydrophilic to slightly hydrophobic ones. The AFM measurements showed various surface roughness, ranging from 23 nm (smooth) to 162 nm (rough) of average peak height. Lab-scale fouling experiments were performed using feedwater obtained from conventional water treatment plants in the province of Korea, and their results attempted to correlate to surface characteristics of NF membranes. However, unlike typical RO membranes, no clear correlation was found in this study, indicating that fouling mechanisms of NF membrane may be different from those of typical RO membranes, and both cake deposition and pore blocking mechanisms should be considered simultaneously.

Preparation of Silica Particles by Emulsion-Gel Process Using Membrane Emulsification (막유화 에멀젼-겔 공정에 의한 실리카 입자의 제조)

  • Yeon, Song-Hee;Youm, Kyung-Ho
    • Membrane Journal
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    • v.20 no.2
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    • pp.87-96
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    • 2010
  • We prepared spherical silica particles by controlling various conditions of emulsion-gel procedure using a lab-scale membrane emulsification system equipped with SPG (Shirasu porous glass) membrane having pore size of 2.6 ${\mu}m$. We determined the effects of process parameters of membrane emulsification (dispersed phase pressure, stabilizer and emulsifier concentration in continuous phase, $H_2O$/TEOS ratio, ratio of dispersed phase to continuous phase) on the mean size and size distribution of silica particles. The increase of the dispersed phase pressure and ratio of dispersed phase to continuous phase led to the increase in the mean size of silica particles. On the contrary, the increase in stabilizer and emulsifier concentration and $H_2O$/TEOS ratio caused the reduction of the mean size of particles. Through controlling these parameters, monodisperse spherical silica particles with about 3 ${\mu}m$ of the mean size were finally prepared.

Fabrication of Nanoporous Alumina Mask and its Applications (나노다공성 알루미나 마스크의 제조 및 응용)

  • Jung, Mi;Choi, Jeong-Woo;Kim, Young-Kee;Oh, Byung-Ken
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.465-472
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    • 2008
  • Fabrication of nanostructured materials and synthesis of nanomaterials have intensively studied to realize electronic devices for nanotechnology. By using nanoporous alumina mask, nanostructured material can be fabricated in the form of uniform array. The size and the density of the nanostructured materials can be controllable by changing the pore diameter and the density of the alumina mask. This method is possible low cost and on large scale process, and feasible to contribute the fusion technology consisting of information technology, nanotechnology, and biotechnology. Therefore, these techniques provide alternative approaches for development of new electronic applications. In this paper, the fabrication technique and its applications of nanoporous alumina mask are described and nanostructured materials such as quantum dots, nanoholes, and nanorods are introduced.

A Study on the Improvement Effects of Soft Ground through In-Situ Construction of Quick Lime Pile (생석회파일 현장시험시공 통한 연약지반 개량효과에 관한 연구)

  • 천병식;고갑수;이용한
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.11a
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    • pp.41-48
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    • 2000
  • Most land development projects and large scale civil works require a great amount of sand. And sand is also the most favorable material for soft ground improvement. The demand for sand is soaring rapidly due to increased number of projects regardless of its limited supply. Therefore, it is not difficult to predict that sand may become depleted and no longer be available as ground improvement material in the near future. Against this backdrop, developing an inexpensive sand-substitution material with an efficient accessibility will be necessary and urgently called for. So quick lime could be recommended as the substitutional material for sand. Quick lime is now preferred by forward developed nations. If Korea is able to take advantage of its abundant supply, economical efficiency could be achieved through massive production as well as being able to take advantage of utilization of natural resources. In this respect the purpose of this paper was to estimate improvement effect of soft ground though in-situ construction of quick lime pile. In-situ construction was peformed in road construction site of soft clay and in this study quick lime from Dan-yang that was estimated prominently in aspect of engineering characteristics was used. Quick lime piles were installed by 1.5m, 2.0m, 3.0m spacing to confirm improvement effect according to spacing and installed piles are 0.4m in diameter, up to 5m in length and the density of quick piles installed is 1.4 t/㎥. Vibrating wire pore water pressure cell was installed to confirm consolidation characteristics in surrounding of quick lime piles and both laboratory test and field test were carried out to confirm strength increase. In conclusion, soft ground improvement by quick lime piles was confirmed.

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Model Test to Predict the Runout Distance of Landslide according to Hourly Rainfall (강우강도에 따른 산사태 확산범위 예측을 위한 모형실험)

  • Song, Young-Suk;Chae, Byung-Gon;Kim, Won-Young;Seo, Yong-Seok
    • Proceedings of the Korean Geotechical Society Conference
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    • 2006.03a
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    • pp.12-19
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    • 2006
  • Landslide model experiments considering hourly rainfall were performed to investigate and predict the run out distance induced by landslides. The model flume and the rainfall simulator were designed and produced. The model flume was designed in consideration of the landslide characteristics of Korea. The landslides in Korea were mainly occurred in the interface between soil layer and rock layer. The rainfall simulator was produced for controlling hourly rainfall ranged from 100mm/hr to 1,000mm/hr. Jumnunjin standard sand as slope soils was placed on the model flume. The model experiments were performed with changing the hourly rainfall ranged from 150mm/hr to 250mm/hr. In this experiments, the inclination of slope was 25o and the relative density of slope soils was 35%. As a result of experiments, the pore water pressure is rapidly increased at landslide occurring time, and the scale of landslide is increased with increasing in hourly rainfall. The spreading range of run out distance is occurred with pan type, and the spreading width and length are rapidly increased in its early stage and slowly increased after early stage. Also, The increasing velocity of run out distance of debris is influenced by hourly rainfall.

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Anodizing of pure Al foil for AAO as a Nanowire Template (Al 양극산화에 의한 나노선재용 AAO template제조)

  • Lee Kwan Hyi;Lee Hwa Young;Jeung Won Young
    • Journal of the Korean Electrochemical Society
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    • v.4 no.2
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    • pp.47-52
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    • 2001
  • AAO template having nano scale pores of high aspect ratio has been prepared through anodizing of aluminum foil in sulfuric acid electrolyte. The effect of anodizing parameters on the pore size and distribution was also examined to obtain the proper AAO as a template material of nanowire. The surface of AAO template prepared was observed by SEM to examine the mean size and distribution of pores generated by the anodizing and Fe nanowires obtained by AC electroforming using AAO template were also observed with TEM to determine the length and shape of them. From the results of work, it was found that the mean size or distribution of pores was influenced significantly by the anodizing parameters such as voltage and temperature of electrolyte. Mean length and aspect ratio of Fe nanowires prepared in the work were found to be $10{\mu}m\;and\;300\;to\;1,000$, respectively.

Removal Characteristics of NOx Using a Mixed Soil-Biofilter (토양 혼합여재를 이용한 질소산화물 제거특성)

  • Cho, Ki-Chul;Sin, Eun-Sang;Hwang, Gyeong-Cheol;Cho, Il-Hyoung;Lee, Nae-Hyun;Yeo, Hyun-Gu
    • Journal of environmental and Sanitary engineering
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    • v.21 no.3 s.61
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    • pp.15-26
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    • 2006
  • As traffic in city-centre around the world continues to increase, so levels of atmospheric pollutants continue to rise. High concentrations of NOx can have negative effects on human health, and we must find new ways to reduce their levels in the air we breathe. Nitrogen oxide gas (NOx), consisting of nitrogen monoxide (NO) and nitrogen dioxide $(NO_2)$ produced using $O_3$ oxidation, at a low concentration corresponding to that on roads as a result of exhaust from automobiles, was carried out to evaluate the removal characteristics of NOx through a laboratory-scale biofilter packed with soil as a packing material. A mixture media (yellow soil (30%): soil (40%): compost (10%): a used briquet (20%)) was applied. After about 1day of operation, the removal efficiency for $NO_2$ in all experiments with a constant condition ($25^{\circ}C$ and water humidity (60%)) was over 98%. The retention times of the section between phase I and phase II for formation and reduction of $NO_3$ NO and $NO_2$ on the initial $NO_3$ concentration was 50min $(O_3:195\;ppb),\;55min\;(O_3:925\;ppb),\;65min\;(O_3:1743\;ppb),\;70min\;(O_3:2616\;ppb),\;75min\;(O_3:3500\;ppb)$, respectively The soil biofilter system is a unique technology that purifies urban air by utilizing the natural processes that take place in the soil. Although some of the processes are quite complex, they can broadly be summarized as adsorption onto soil particles, dissolution into soil pore water, and biochemical.