• Title/Summary/Keyword: pore analysis

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Distribution of Calcium Hydroxide at the ITZ between Steel and Concrete

  • Ann Ki-Yong;Kim Hong-Sam;Kim Yang-Bae;Moon Han-Young
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.481-485
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    • 2005
  • The present study examines the distribution of calcium hydroxide, unhydrated cement grain and porosity at the steel-concrete interface. The formation of calcium hydroxide has been confirmed by microscopic analysis using BSE images containing the ITZ between the steel and concrete. It was found that calcium hydroxide does not form a layer on the steel surface, different from the hypothesis that has been available in investigating the corrosion of steel in concrete, ranging from 5 to $10\%$ within the steel surface. Moreover, the high level of porosity at the ITZ was observed, accounting for $30\%$, which may reduce the buffering capacity of cement hydration products against a local fall in the pH. These findings may imply that the mole of ($Cl^-$) :($OH^-$) in pore solution as chloride threshold level lead to wrong judgement or to a wide range of values.

Application of electromagnetic methods to the investigation of seawater intrusion into coastal aquifer - A case study in the Hasunuma area, Chiba Prefecture, Japan

  • Mitsuhata Yuji;Uchida Toshihiro
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.335-339
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    • 2003
  • The estimation of seawater intrusion into deep aquifers has been becoming an important subject in terms of site characterization for geological disposal of radioactive waste. Conventional direct-current resistivity methods have been used for ground water explorations and recently have been applied to environmental problems. However, electromagnetic methods are more practical and useful for such a deep investigation. We consider audio-frequency magnetotelluric (AMT) and surface-to-borehole electromagnetic (EM) tomography methods as promising tools for the investigation of deep aquifer. These methods were tested in the Hasunuma area, Chiba Prefecture, Japan. Although the study area is in an urban area, high-quality AMT data were acquired, which was mainly accomplished by night-time data recording and remote-reference data processing. One-dimensional inversion results of the AMT data revealed two extremely conductive zones, which is consistent with the electrical conductivity profile of pore water in core samples. It can be interpreted as the seawater intrusions into both zones. However, the chemical analysis of the groundwater sampled in the deep zone suggests that this groundwater must be fossil seawater that had been confined during sedimentation processes. In addition, the permeability coefficient of the deep layer is very low. Thus the deep conductive zone corresponds to the fossil seawater regarded as being difficult to flow.

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Effect of Sodium Aluminate Concentration in Electrolyte on the Properties of Anodic Films Formed on AZ31 Mg Alloy by Plasma Electrolytic Oxidation (AZ31 마그네슘 합금의 플라즈마 전해 산화에서 Sodium Aluminate 농도가 산화막 특성에 미치는 영향)

  • Lee, Jong-Seok;Baek, Hong-Gu;Kim, Sung-Wan
    • Journal of the Korean Society for Heat Treatment
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    • v.25 no.5
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    • pp.227-232
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    • 2012
  • Magnesium alloy have good physical properties such as good castability, good vibration absorption, high strength/weight ratios. Despite the desirable properties, the poor resistance of Mg alloy impedes their use in many various applications. Therefore, magnesium alloy require surface treatment to improve hardness, corrosion and wear resistance. Plasma Electrolytic Oxidation (PEO) is one the surface treatment methods to form oxide layer on Mg alloy in alkali electrolyte. In comparison with Anodizing, there is environmental process having higher hardness and faster deposition rate. In this study, the characteristics of oxide film were examined after coating the AZ31 Mg alloy through the PEO process. We changed concentration of sodium aluminate into $K_2ZrF_6$, KF base electrolyte. The morphologies of the coating layer were characterized by using scanning electron microscopy (SEM). Corrosion resistance also investigated by potentiodynamic polarization analysis. As a result, propertiy of oxide layer were changed by concentration of sodium aluminate. Increasing with concentration of sodium aluminate in electrolyte, the oxidation layer was denser and the pore size was smaller on the surface.

Analysis of 3D Geometry and Compressive Behavior of Aluminum Open Cell Foam Using X-ray Micro CT (마이크로 X-ray CT를 활용한 알루미늄 개방형 폼의 형상 및 압축 거동 분석)

  • Kim, Y.I.;Kim, J.H.;Lee, J.K.;Kim, D.
    • Transactions of Materials Processing
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    • v.20 no.7
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    • pp.518-523
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    • 2011
  • The three dimensional geometries of an aluminum open cell foam before and after uniaxial compressive loading were investigated using the X-ray micro CT(computed tomography). Aluminum 6101-T6 open cell foams of 10, 20, 40 ppi (pore per inch) were considered in this work. After the serial sectioning CT images of aluminum foams were obtained from non-destructive X-ray images, the exact 3D structure were reproduced and visualized with commercial image processing program. The relative density ratio was around the 7.0 to 9.0 range, the unit cells showed anisotropic shapes having the different dimensional ratios of 1.1 to 1.3 between the rise and the transverse directions. The yield stress increased with the relative density ratio and the volumetric strain increased proportionally with compressive strain. The plateau stress in the compressive stress-strain curve was caused by the buckling of ligaments.

Multi-scale simulation of drying process for porous materials using molecular dynamics (part 2: material properties) (분자동역학을 이용한 다공성 물질 건조공정 멀티스케일 시뮬레이션(2부: 미시 물성))

  • Baik S.M.;Keum Y.T.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.4
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    • pp.162-167
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    • 2005
  • As the properties of porous materials during the drying process relate to the atomistic defects of heterogeneous materials such as dislocation, grain, grain boundary, pore, etc., the knowledge of nano-scale analysis is needed in order to accurately analyze the drying process for porous materials. In this study, the atomic behavior of porous materials Is statically predicted by using the molecular dynamics simulation and the nano-scale material properties are computed. The elastic modulus, thermal expansion coefficient, and volumetric heat capacity numerically found from the molecular dynamics simulation are compared with those of experiment and theory and proved the accuracy.

Effect of Specific Surface Area on the Reaction of Silicon Monoxide with Porous Carbon Fiber Composites

  • Park, Min-Jin;Lee, Jae-Chun
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.245-248
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    • 1998
  • Porous carbon fiber composites (CFCs) having variable specific surface area ranging 35~1150 $\m^2$/g were reacted to produce silicon carbide fiber composites with SiO vapor generated from a mixture of Si and $SiO_2$ at 1673 K for 2 h under vacuum. Part of SiO vapor generated during conversion process condensed on to the converted fiber surface as amorphous silica. Chemical analysis of the converted CFCs resulting from reaction showed that the products contained 27~90% silicon carbide, 7~18% amorphous silica and 3~63% unreacted carbon, and the composition depended on the specific carbide, 7~18% amorphous silica and 3~63% unreacted carbon, and the composition depended on the specific surface area of CFCs. CFC of higher specific surface area yielded higher degree of conversion of carbon to silicon and conversion products of lower mechanical strength due to occurrence of cracks in the converted caron fiber. As the conversion of carbon to silicon carbide proceeded, pore size of converted CFCs increased as a result of growth of silicon carbide crystallites, which is also linked to the crack formation in the converted fiber.

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Soft computing-based slope stability assessment: A comparative study

  • Kaveh, A.;Hamze-Ziabari, S.M.;Bakhshpoori, T.
    • Geomechanics and Engineering
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    • v.14 no.3
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    • pp.257-269
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    • 2018
  • Analysis of slope stability failures, as one of the complex natural hazards, is one of the important research issues in the field of civil engineering. Present paper adopts and investigates four soft computing-based techniques for this problem: Patient Rule-Induction Method (PRIM), M5' algorithm, Group Method of data Handling (GMDH) and Multivariate Adaptive Regression Splines (MARS). A comprehensive database consisting of 168 case histories is used to calibrate and test the developed models. Six predictive variables including slope height, slope angle, bulk density, cohesion, angle of internal friction, and pore water pressure ratio were considered to generate new models. The results of test studies are used for feasibility, effectiveness and practicality comparison of techniques with each other, and with the other available well-known methods in the literature. Results show that all methods not only are feasible but also result in better performance than previously developed soft computing based predictive models and tools. It is shown that M5' and PRIM algorithms are the most effective and practical prediction models.

Novel high performanced and fouling resistant PSf/ZnO membranes for water treatment

  • Sarihan, Adem;Eren, Erdal
    • Membrane and Water Treatment
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    • v.8 no.6
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    • pp.563-574
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    • 2017
  • Antibacterial effective, high performanced, novel ZnO embedded composite membranes were obtained by blendig ZnO nanoparticles with polysulfone. IR, TG/DTG, XRD and SEM analysis were performed to characterize structure and morphology of ZnO nanoparticles and composite membranes. Contact angle, EWC, porosity and pore structure properties of composite membranes were investigated. Cross-flow filtration studies were performed to investigation of performances of prepared membranes. It was found from the cross section SEM images that ZnO nanoparticles dispersed homogenously up to additive amount of 2% and the membrane skin layer thicknesses increased in the presence of ZnO. Contact angle of pure PSf membranes were reduced from $70^{\circ}$ to $55^{\circ}$ after addition of 4% ZnO. Porosity of composite membrane contains 1% ZnO was higher about 22% than pure PSf membrane. BSA rejection ratio and PWF of 0.5% ZnO embedded composite membrane became 2.2 and 2.3 times higher than pure PSf membrane. It was determined from flux recovery ratios that ZnO additive increased the fouling resistance of composite membranes. Also, the bacterial killing ability of ZnO is well known and there are many researches related to this in the literature. Therefore, it is expected that prepared composite membranes will show antibacterial effect.

Stability Analysis and Design of Reinforced Masonry Walls (보강석축의 안정해석 및 설계)

  • Kim, Hong Taek;Kang, In Kyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.2
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    • pp.239-253
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    • 1992
  • The masonry walls, having the characters of cheap construction materials and relatively easy construction, have been widely used in supporting slopes. However, the necessity of reinforcing methods to improve the stability of masonry walls has been continuously required due to the collapses taken place quite often. In the present study, a new method to improve the stability of masonry walls was developed based on the soil nailing system proven effective in strengthening the surrounding soils. The developed method could be used in reinforcing the old masonry walls structually unsafe as well as in constructing new masonry walls. The effects of pore water pressures due to heavy rainfalls were included in the developed method and also the chart practically applicable to design was presented, together with a design example.

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Fabrication of 3D Bioceramic Scaffolds using Laser Sintering Deposition System and Design of Experiment (레이저 소결 적층 시스템과 실험 계획법을 이용한 3차원 바이오 세라믹 인공지지체의 제작)

  • Lee, Chang-Hee;Sa, Min-Woo;Kim, Jong Young
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.12
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    • pp.59-66
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    • 2019
  • In this study, we developed a novel laser sintering deposition system (LSDS) based on solid free-form fabrication (SFF) technology as it has the potential to fabricate complex geometries with controllable architecture for bone tissue engineering applications. The 3D biphasic calcium phosphate (BCP) scaffolds were fabricated with a pore size of 800㎛, a line width and height of 1000㎛, and an overall size of 8.2×8.2×8.0 mm3 according to the design of experiment (DOE) results. Additionally, an optimized manufacturing process using response surface analysis was established to fabricate 3D BCP scaffolds. The fabricated 3D BCP scaffolds were sintered at 950℃, 1050℃, 1150℃, and 1250℃ according to sintering processes with a furnace. As the sintering temperature increased, the porosity increased. Through the compressive strength test, the 3D BCP scaffolds sintered at 1050℃ presented good results of about 0.76 MPa. These results suggest that fabrication methods for 3D bioceramic scaffolds using LSDS may meet the basic requirements for bone tissue engineering.