• Title/Summary/Keyword: pore analysis

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Finite Difference Method on Consolidation under Time Dependent Loading (점증하중에 의한 압밀의 유한차분해석)

  • Lee, Seung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.4
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    • pp.1895-1899
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    • 2012
  • Formulation of finite difference method for analyzing consolidation were carried out. It can be seen that the differences in settlement with time obtained by FDM and Terzaghi method are diminished by fine discretization of time increment. Excess pore pressures predicted by the derived finite difference equation were same as those calculated by Olson's method. Predicted time-settlement behavior from the derived finite difference method were almost same as those calculated by Terzaghi's method and Olson's method. Analysis results obtained from the assumed multi-step time dependent loading are thought to be reasonable.

Properties of the $\beta$-SiC-$ZrB_2$ Composites with $Al_{2}O_{3}+Y_{2}O_{3}$ additives ($Al_{2}O_{3}+Y_{2}O_{3}$를 첨가한 $\beta$-SiC-$ZrB_2$ 복합체의 특성)

  • Shin, Yong-Deok;Ju, Jin-Young
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.853-855
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    • 1998
  • The electrical resistivity and mechanical properties of the hot-pressed and annealed ${\beta}$-SiC+39vol.%$ZrB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of $Al_{2}O_{3}+Y_{2}O_{3}$(6:4wt%). In this microstructures. no reactions were observed between $\beta$-SiC and $ZrB_2$, and the relative density is over 97.6% of the theoretical density. Phase analysis of composites by XRD revealed mostly of a $\alpha$-SiC(6H, 4H), $ZrB_2$ and weakly $\beta$-SiC(15R) phase. The fracture toughness decreased with increased $Al_{2}O_{3}+Y_{2}O_{3}$ contents and showed the highest for composite added with 4wt% $Al_{2}O_{3}+Y_{2}O_{3}$ additives. The electrical resistivity increased with increased $Al_{2}O_{3}+Y_{2}O_{3}$ contents because of the increasing tendency of pore formation according to amount of liquid forming additives $Al_{2}O_{3}+Y_{2}O_{3}$. The electrical resistivity of composites is all positive temperature coefficient resistance(PTCR) against temperature up to $700^{\circ}C$.

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Development of Objectives in Nursing Clinical Education based on the Nursing Core Competencies (핵심간호능력 중심 간호학실습교육목표 개발)

  • Kim, Mi-Won
    • Journal of Korean Academy of Nursing
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    • v.36 no.2
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    • pp.389-402
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    • 2006
  • Purpose: The purpose of this study was to set up a Nursing Core Competencies required for staff nurses and to set up Objectives for Nursing Clinical Education based on the Nursing Core Competencies. The objectives in this study are to be achieved ultimately through clinical practice because it is a common avenue of work and the basic objective regardless of the education system and curriculum. Method: A nursing Core Competencies were established by literature review and verified by 15 experts. Nursing Clinical Education Objectives were established by literature review and analysis, and a survey for validity using a five point Likert scale was given to 257 nursing professors, 503 head-nurses, 509 staff nurses who had less than 3 years clinical experience in 34 general hospitals and 738 senior student nurses from 81 nursing colleges. Result: Nine nursing core competencies were set up. In addition 39 Objectives for each of the nursing clinical core competencies were set up. Conclusion: In conclusion, this study will contribute to professional nursing education to provide comprehensive nursing care by applying knowledge to nursing practice to achieve the Nursing Pore Competency as a professional nurse.

Synthesis, Characterization and Catalytic Evaluation of Zinc Fluorides for Biodiesel Production

  • Indrayanah, Sus;Marsih, I Nyoman;Murwani, Irmina Kris
    • Journal of the Korean Chemical Society
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    • v.62 no.1
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    • pp.7-13
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    • 2018
  • The potential of zinc fluorides with different molar ratios of Zn/F was applied as a solid catalyst in the simultaneous reaction of transesterification and esterification of crude palm oil (CPO) for biodiesel production. These materials were prepared by the fluorolytic sol-gel technique with different fluorine contents. The resulting samples were investigated using elemental analysis, XRD, FT-IR, TG/DTG, $N_2$ physisorption measurements and SEM. The results exhibited that the presence of fluorine strongly affected the catalytic activity in the biodiesel production. The catalysts with smaller fluorine contents (${\leq}1$) showed the best performance in all of the observed samples, yields from 92.94 to 89.95, 87.38 and 85.21% with increasing fluorine contents, respectively. The yield toward the formation of biodiesel depended on the phase and particle sizes of catalysts, but it was not influenced by surface area, pore size, and volume of the samples. The recovered catalyst showed a gradual decrease in activity over three cycles of same reactions.

Development of $YSZ/La_0.85S_r0.15MnO_3$ Composite Electrodes for Solid Oxide Fuel Cells (고체산화물 연료전지용 $YSZ/La_0.85S_r0.15MnO_3$계 복합전극의 개발)

  • 윤성필;현상훈;김승구;남석우;홍성안
    • Journal of the Korean Ceramic Society
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    • v.36 no.9
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    • pp.982-990
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    • 1999
  • YSZ/LSM composite cathode was fabricated by dip-coating of YSZ sol on the internal pore surface of a LSM cathode followed by sintering at low temperature (800-100$0^{\circ}C$) The YSZ coating significantly increased the TPB(Triple Phase Boundary) where the gas the electrode and the electrolyte were in contact with each other. Sinter the formation of resistive materials such as La2Zr2O7 or SrZrO3 was prevented due to the low processing temperature and TPB was increased due to the YSZ film coating the electrode resistance (Rel) was reduced about 100 times compared to non-modified cathode. From the analysis of a.c impedance it was shown that microstructural change of the cathode caused by YSZ film coating affected the oxygen reduction reaction. In the case of non-modified cathode the RDS (rate determining step) was electrode reactions rather than mass transfer or the oxygen gas diffusion in the experimental conditions employed in this study ($600^{\circ}C$-100$0^{\circ}C$ and 0,01-1 atm of Po2) for the YSZ film coated cathode however the RDS involved the oxygen diffusion through micropores of YSZ film at high temperature of 950-100$0^{\circ}C$ and low oxygen partial pressure of 0.01-0.03 atm.

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Effect of Inherent Anatomy of Plant Fibers on the Morphology of Carbon Synthesized from Them and Their Hydrogen Absorption Capacity

  • Sharon, Madhuri;Sharon, Maheshwar
    • Carbon letters
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    • v.13 no.3
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    • pp.161-166
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    • 2012
  • Carbon materials were synthesized by pyrolysis from fibers of Corn-straw (Zea mays), Rice-straw (Oryza sativa), Jute-straw (Corchorus capsularis) Bamboo (Bombax bambusa), Bagass (Saccharum officinarum), Cotton (Bombax malabaricum), and Coconut (Cocos nucifera); these materials were characterized by scanning electron microscope, X-ray diffraction (XRD), and Raman spectra. All carbon materials are micro sized with large pores or channel like morphology. The unique complex spongy, porous and channel like structure of Carbon shows a lot of similarity with the original anatomy of the plant fibers used as precursor. Waxy contents like tyloses and pits present on fiber tracheids that were seen in the inherent anatomy disappear after pyrolysis and only the carbon skeleton remained; XRD analysis shows that carbon shows the development of a (002) plane, with the exception of carbon obtained from bamboo, which shows a very crystalline character. Raman studies of all carbon materials showed the presence of G- and D-bands of almost equal intensities, suggesting the presence of graphitic carbon as well as a disordered graphitic structure. Carbon materials possessing lesser density, larger surface area, more graphitic with less of an $sp^3$ carbon contribution, and having pore sizes around $10{\mu}m$ favor hydrogen adsorption. Carbon materials synthesized from bagass meet these requirements most effectively, followed by cotton fiber, which was more effective than the carbon synthesized from the other plant fibers.

Experimental Study on Consolidation Characteristics of Soft Marine Deposit by Piezocone Dissipation Test (피에조콘 소산시험을 통한 해성연악지반의 압밀특성에 대한 실험적 연구)

  • 박찬국;송정락;김수일
    • Journal of the Korean Geotechnical Society
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    • v.18 no.2
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    • pp.137-146
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    • 2002
  • Field piezocone dissipation tests are performed, and the results are compared to the Rowe cell consolidation tests results to investigate the consolidation characteristics of soft marine deposit at the same location in Korea. From these results, statistical formula fur the relation between the coefficients of horizontal consolidation$(c_r)$ from Rowe cell consolidation tests and $t_{50}$ from pore pressure dissipation tests by Piezocone is suggested through the regression analysis. The results are also compared to the existing theoretical formula. It is also shown that suggested formula is similar to Torstensson's(1977) formula based on cylindrical cavity expansion theory and Houlsby and Teh's(1988) formula based on strain path method.

Stability analyses of railroad cut-off soil slopes considering rainfall infiltration (강우에 의한 침투를 고려한 철도 절개 토사 사면의 안정해석)

  • Lee, Su-Hyung;Hwang, Seon-Keun;Kim, Hyun-Ki;SaGong, Myung
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.811-818
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    • 2005
  • Stability analyses on the 17 railroad cut-off soil slopes were carried out. The influences of rainfall infiltration on the slope stabilities were taken into account by seepage analyses using finite element method and by assuming ground water tables to be located adjacent to soil surface. The validity of those analyses were evaluated by comparing the slope failure characteristics between analysis results and the past failure records. The analyses were not appropriate to estimate the failure surface and the method considering only the increase of pore-water pressure (reduction of matric suction) as the influence of rainfall cannot appropriately estimate the surficial failures that occurred most of the cut-off soil slopes. For the better estimation of the surficial failure, the influence of water flows over slope surface which erode soil mass and/or increase driving force, should be evaluated and considered.

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Electrochemical Properties and Estimation on Active Material LiMnO2 Synthesis for Secondary

  • Wee, Sung-Dong;Kim, Jong-Uk;Gu, Hal-Bon
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.2
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    • pp.35-39
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    • 2003
  • This paper is contents on the orthorhombic crystalline calcined by the solid phase method with LiMnO$_2$ thin film structured as the result which an average pore diameter of power was 132.3${\AA}$ in porosity analysis. Voltage ranges are able to get the properties of charge and discharge for experimental results of LiMnO$_2$ thin film were 2.2V 4.3V. The current density and scan speed were 0. 1㎃/$\textrm{cm}^2$ and 0.2㎷/sec respectively. Properties of the charge and discharge are obtained by optimum experiment condition parameters. Li dense ratio of the LiMnO$_2$ thin film that discharged capacities were 87㎃h/g have been 96.9[ppm] at 670.784[nm] wavelength. The dense ratio of Mn analyzed to 837[ppm] at 257.610[nm] wavelength. It can be estimated the quality of the LiMnO$_2$ thin film as that the wrong LiMnO$_2$ thin film pulled up from cell of electrolyte and became dry it at 800$^{\circ}C$. The results of SEM and XRD were the same as that of original researchers.

Effect of Two-step Surface Modification of Activated Carbon on the Adsorption Characteristics of Metal Ions in Wastewater I. Equilibrium and Batch Adsorptions

  • Park, Geun-Il;Lee, Jae-Kwang;Ryu, Seung-Kon;Kim, Joon-Hyung
    • Carbon letters
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    • v.3 no.4
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    • pp.219-225
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    • 2002
  • The two-step surface modifications of activated carbon was carried out to improve the adsorption capacity of toxic heavy metal ions in liquid phase. Physical and chemical properties of the as-received activated carbon (AC) and two kinds of surface-modified activated carbons ($1^{st}AC$ and $2^{nd}AC$) were evaluated through the BET analysis, surface acidity, and oxides measurements. Specific surface area and pore volume did not significantly change, but surface oxide-group remarkably increased by the surface modification. Equilibrium and batch adsorptions of the various metals, such as Pb, Cd, and Cr, using AC, $1^{st}AC$, and $2^{nd}AC$ were performed at initial pH 5. The adsorption capacity and rate of $2^{nd}AC$ were higher than those of AC and $1^{st}AC$. The carboxylic/sodium carboxylate complex groups were developed from the two-step surface modification of activated carbon, which strongly affected the adsorption of metal ions.

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