• Title/Summary/Keyword: pore analysis

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Analysis on Permittivity of Soil to Evaluate Pore Water Contamination

  • Oh Myoung-Hak;Kim Yong-Sung;Yoo Dong-Ju;Park Jun-Boum
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.249-252
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    • 2005
  • 저주파수에서 유전상수 측정시 100kHz 이하의 주파수 영역에서는 전극분극효과가 발생하므로 100kHz이상의 주파수에서 유전상수가 평가되어야 한다. 유전상수는 쌍극자모멘트의 수에 비례하기 때문에 흙의 유전상수는 체적함수비에 따른 선형적인 증가경향을 나타내었다. 용액에 이온성분이 존재하는 경우에는 수화작용에 의한 물분자의 배향분극 발현의 감소로 인하여 유전상수가 감소한다. 흙과 중금속 혼합시료의 경우 함수비가 큰 시료에서는 용액의 유전특성이 발현되지만, 함수비가 작은 경우에는 공간전하분극의 영향으로 유전상수가 10-20%정도 증가하는 경향을 나타내었다. 현장에서의 정확한 오염도 평가를 위해서는 토양의 함수비에 대한 평가가 반드시 수행되어야 한다.

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An analysis of rainfall infiltration characteristics on a natural slope from in-situ monitoring data (현장 계측을 통한 자연사면에서의 강우 침투 특성 분석)

  • Kim, Woong-Ku;Chang, Pyoung-Wuck;Cha, Kyung-Seob
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.375-380
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    • 2005
  • In Korea, most landslides are occurred during the rainy season from June to September and have a shallow failure plane parallel to the slope. For these types of rainfall-induced failures, the most important factors triggering slope unstability is not the increase of pore water pressure but the decrease of the matric suction of unsaturated soils by rainfall infiltration. So it is essential to landslide hazard assessment that defines the characteristics of infiltration in natural slopes. In this study, field measurements have been carried out in order to monitor in-situ volumetric water contents and ground water table, at several depths and locations on a natural slope. The results show that rainfall infiltration is correlated with antecedent water contents, rainfall intensity and total rainfall. The ground water table was varied sensitively by every rainfall event.

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Effect of Manufacturing Conditions on the Properties of Oil-absorbable Melt Blown Nonwoven (멜트블로운 부직포 제조공정이 유흡착포의 특성에 미치는 영향)

  • Shin, Hyun-Sae;Jin, Lu;Yoo, Joo-Hwan
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.22-28
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    • 2009
  • Oil-absorbable nonwovens were produced by melt-blown processing of polypropylene chips. The melt-blown processing conditions, such as air pressure, and gear pump speed, DCD. In this study, these three factors were chosen to produce samples. Experimental array and variance analysis of the design of experiment were used to increase the field repeatability and universality. The effect of the factors on oil absorption properties of melt-blown nonwoven fabric such as oil absorbency were evaluated. As a result, the fiber diameter decreased as gearpump speed decreased or air pressure increased. The oil absorbency increased as air pressure increased or gearpump speed decreased and with the DCD increasing the oil absorbency significantly increased.

Adsorption of Cu(II) Ions onto Myristica Fragrans Shell-based Activated Carbon: Isotherm, Kinetic and Thermodynamic Studies

  • Syahiddin, D.S.;Muslim, A.
    • Journal of the Korean Chemical Society
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    • v.62 no.2
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    • pp.79-86
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    • 2018
  • This study reported the adsorption of Cu(II) ions onto activated carbon prepared from Myristica Fragrans shell (MFS AC) over independent variables of contact time, activating chemical (NaOH) concentration, initial adsorbate concentration, initial pH of adsorbate solution and adsorption temperature. The MFS AC structure, morphology and total surface area were characterized by FTIR, SEM and BET techniques, respectively. The Cu(II) ions adsorption on the MFS AC (activated using 0.5 M NaOH) fitted best to Freundlich adsorption isotherm (FAI), and the FAI constant obtained was 0.845 L/g at $30^{\circ}C$ and pH 4.5. It followed the pseudo first order of adsorption kinetic (PFOAK) model, and the PFOAK based adsorption capacity was 107.65 mg/g. Thermodynamic study confirmed the Cu(II) ions adsorption should be exothermic and non-spontaneous process, physical adsorption should be taken place. The total surface area and pore volume based on BET analysis was $99.85m^2/g$ and 0.086 cc/g, respectively.

Effects of Absorbent Polymer on the Moisture Resistance and Hydration Characteristics of Cement Pastes (시멘트 페이스트의 특성에 미치는 흡수성폴리머의 영향)

  • 나종균;김창은;이승규
    • Journal of the Korean Ceramic Society
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    • v.36 no.5
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    • pp.539-546
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    • 1999
  • Absorbent polymer-cement composites were fabricated by the semi-powder mixing OPC(ordinary Portland cement) with an absorbent polymer. The effects of absorbent polymer on the mechanical properties and the hydration characteristics were observed and the polymer-cement interaction also discussed. Absorbent polymer-cement composites showed the value of total porosity of 8vol% the value of 28 days flexural strength was up to 280 Kgf/cm2 in the case of absorbent polymer-cement composite at 1 wt% absorbent polymer content and microstructure of absorbent polymer-cement composite has been observed more dense than that of OPC paste. Accordingly the permeability of compositewas improved and so the moisture resistance was also increased. Adding polymer did not retard the hydration of OPC. It was considered from the results of IR(infrared) analysis that the functional group of absorbent polymer would be changed from unidentate to bidentate during by the hydration of cement minerals.

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Non-Covalent Immobilization of Chiral (Salen) Complexes on HF-treated Mesoporous MFI-type Zeolite for Asymmetric Catalysis

  • Lee, Kwang-Yeon;Lee, Choong-Young;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.389-396
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    • 2009
  • MFI structural zeolite (ZSM-5 or Sililcalite) was treated with HF solution to introduce mesoporous channels in the microporous crystals. Inner mesopore size could be controlled from 2.5 to 3.5 nm by changing the concentration of HF solution. The pore structure of HF-treated MFI zeolite was studied by instrumental analysis. The active Co (III) salen complex monomers were successfully anchored non-covalently on the surfaces of mesoporous MFI-type zeolite. These heterogeneous catalysts could be applied in asymmetric ring opening of terminal epoxides by phenol derivatives. It showed very high enantioselectivity and yield up to 95% in the catalytic synthesis of optically active $\alpha$-aryloxy alcohol compounds.

Geotechnical Characteristics of Major Earth and Rockfill Dams in Korea (우리나라 주요 록휠 댐의 지반공학적 특성)

  • 유태성
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.10a
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    • pp.3.2-27
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    • 2002
  • This paper presents the status of dam construction in Korea, along with a brief assessment of the dam design and construction practice. The assessment is based on publically available design and construction records of the major existing rockfill dams which have been constructed since early 1970's, and focussed in identifying geotechnical characteristics of design and construction parameters of the dams. Though the assessment, two representative dams, having unique geotechnical characteristics, are selected for comprehensive comparison of their geotechnical engineering behavior during construction and operation. The comparison yields very interesting findings on the effects of various design and construction parameters on dam behavior.

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Consolidated Undrained Triaxial on Cubical Compression and Plane Clay Specimen (입방체 점토시료에 대한 압밀 비배수 삼축압축 및 평면변헝률 시험)

  • 박경기;이강일
    • Geotechnical Engineering
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    • v.10 no.3
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    • pp.41-54
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    • 1994
  • This study aims at investigating the mechanism and operation of cubical triaxial test developed by Lade in order to obtain analysis on the clayey foundation deformation. A comparison on deviator stress, pore water pressure and stress path is made between test results of clay using the cubical consolidated undrained test as well as plane strain test.

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Analysis of Segregation Resistance by Admixture Replacement of Hardened System High Fluidity Concrete (경화된 분체계 고유동 콘크리트의 혼화재 치환 변화에 따른 재료분리 저항성 분석)

  • Lee, Hyuk-Ju;Choi, Yoon-Ho;Han, Jun-Hui;Han, In-Deok;Han, Dong-Yeop;Han, Min-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.101-102
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    • 2019
  • The use of high fluidity concrete has been added in recent construction work. In this study, we analyzed segregation resistance due to admixture substitution of the system high fluidity concrete that was hardened. The research results show that the resistance to segregation at the time of admixture replacement is improved. The best results were shown with a ternary system mixed like FA and BS.

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Effect of Processing Time on the Microarc Oxidation Coatings Produced on Magnesium AZ61 Alloy at Constant Hybrid Voltage

  • Ur Rehman, Zeeshan;Jeong, Yeong Seung;Koo, Bon Heun
    • Korean Journal of Materials Research
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    • v.25 no.10
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    • pp.509-515
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    • 2015
  • MAO ceramic coatings were prepared on AZ61 magnesium alloy for various processing times ranging from 5 to 60 min, in an electrolyte solution based on silicate-fluoride. The mechanical, electrochemical and, microstructural properties and the phase compositions of the coating layers were investigated. In this work, unlike previous studies, coatings with high amounts of the $Mag_2SiO_4$ phase were formed which contained small amounts of MgO and $MgF_2$ at a processing condition of 30 min. A microstructural analysis revealed that the porosity of the coatings was reduced considerably with an increase in the processing time, together with a change in the pore geometry from an irregular to a spherical shape. Potentiodynamic polarization and mechanical testing results showed that the coatings acquired after a processing time of 30 min were superior to all of the others.