• Proceedings of the KAIS Fall Conference
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• 2010.11a
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• pp.495-499
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• 2010

The biocatalytic capture of $CO_2$, and its precipitationas $CaCO_3$, over bovine carbonic anhydrase (BCA) immobilized on a pore-expanded SBA-15 support was investigated. SBA-15 was synthesized using TMB as a pore expander, and the resulting porous silica was characterized by XRD, BET, IR, and FE-SEM analysis. BCA was immobilized on SBA-15 through various approaches, including covalent attachment (BCA-CA), adsorption (BCA-ADS), and cross-linked enzyme aggregation (BCA-CLEA). The immobilization of BCA on SBA-15 was confirmed by the presence of zinc metal in the EDXS analysis. The effects of pH, temperature, storage stability, and reusability on the biocatalytic performance of BCA were characterized by examining para-nitrophenyl acetate (p-NPA) hydrolysis. The $K_{cat}/K_m$ values for p-NPA hydrolysis were 740.05, 660.62, and $680.11M^{-1}s^{-1}$, respectively, where as $K_{cat}/K_m$ for free BCA was $873.76M^{-1}s^{-1}$. The amount of $CaCO_3$ precipitate was measured quantitatively using anion-selective electrode and was found to be 12.41, 11.82, or 11.28 mg $CaCO_3$/mg for BCA-CLEA, BCA-ADS, or BCA-CA, respectively. The present results indicate that the immobilized BCA-CLEA, BCA-ADS, and BCA-CA are green materials, and are tunable, reusable, and promising biocatalysts for $CO_2$ sequestration.

• Economic and Environmental Geology
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• v.32 no.3
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• pp.293-306
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• 1999

The lower Permian jungseong Formation, Taebaegsan basin (Baegunsan Syncline), represents a coal-bearing siliciclastic succession which was later modified by the Songrim or Dabo orogeny. Sandstone perography and clay mineralogy were studied to understand the thermal history of the Jangseong Formation during basin evolution. Petrographic study indicates the Jangseong sandstones are composed of quartz, feldspar, lithic fragments (metamorphic and sedimetary), and varying proportions of matrix and cement. The dominance of quartz(<97%) over feldspar (<1%) and lithic fragments (<2%) classifies most Jangseong sandstones as quartz arenotes or quartzwackes, but lithic graywackes and sublithic arenite locally occur. The diagentic features of these sandstones include mechanical compaction, cemenation by quartz and clay minerals indentified in the Jangseong Formation by X-ray diffraction analysis are late-stage clay pore-filling. Clay minerals isdentified in the Jangseong Formation by X-ray diffaction analysis are illite, kaolinte, and pyrophyllite with a minor amount of chlorite and micas. The illite, kaolinite, and pyrophyllite appear to be largely autjigenic based on their well-crystallinity forms. There authigenic clay minerals form clay minerals form clay coats/rims and late-stage pore-filling cements, Illitecrystallinity shows that the Jangseong formation has been in late-diagenetic zone to early-epizone, which ranges in temperature from $200^{\circ}C$ to $300^{\circ}C$. In assition, kaolinite-pyrophyllite transition suggests that paleotemperature of the formation has reached at least $265^{\circ}C$. Such temperatureis likely to be consistent with homogenixation temperatures of fluid inclusions in quartz veins in the formation. Thus, the Jangseong Formation has been subjected to paleotemperature of about $265^{\circ}C$. The major heat source responsible for paleotemperature may be hydrothermal solutions. The passage of hydrothermal solutions was probably assisted by fractures created during the basin-modifying tectonism of the taebaegsan basin.

• Journal of the Korean Ceramic Society
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• v.36 no.2
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• pp.130-135
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• 1999

The enhanced slag fineness and the batch water of low water-to-cement ratio(W/C) were employed in order to improve the early strength of blast-furnace slag blended cement at low temperature. A grinding aid was used to grind the blast-furnace slag into the fineness of 6,280$\textrm{cm}^2$/g (Blaine), and this fine slag was then homogeneously mixed with the ordinary Portland cement to produce the blast-furnace slag blended cement containing 40% slag by weight composition. On the other hand, the batch water could be reduced from W/C=0.50 (KS L 5105) to W/C=0.33 through a commercial, naphthalene type superplasticizer. Through the method mentioned above, the early strength of the blast-furnace slag blended cement at low temperature could be enhanced even somewhat higher than the Portland cement strength. And the microsturcture of the cement was studied by both the pore structure analysis and the A.C. impedance measurement.

• Geomechanics and Engineering
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• v.15 no.3
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• pp.851-859
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• 2018

There are two primary causes of the ground movement due to tunnelling in urban areas; firstly the lost ground and secondly the groundwater depression during construction. The groundwater depression was usually not considered as a cause of settlement in previous research works. The main purpose of this study is to analyze the combined effect of these two phenomena on the transverse settlement trough. Centrifuge model tests and numerical analysis were primarily selected as the methodology. The characteristics of settlement trough were analyzed by performing centrifuge model tests where acceleration reached up to 80g condition. Two different types of tunnel models of 180 mm diameter were prepared in order to match the prototype of a large tunnel of 14.4 m diameter. A volume loss model was made to simulate the excavation procedure at different volume loss and a drainage tunnel model was made to simulate the reduction in pore pressure distribution. Numerical analysis was performed using FLAC 2D program in order to analyze the effects of various groundwater depression values on the settlement trough. Unconfined fluid flow condition was selected to develop the phreatic surface and groundwater level on the surface. The settlement troughs obtained in the results were investigated according to the combined effect of excavation and groundwater depression. Subsequently, a new curve is suggested to consider elastic settlement in the modified Gaussian curve. The results show that the effects of groundwater depression are considerable as the settlement trough gets deeper and wider compared to the trough obtained only due to excavation. The relationships of maximum settlement and infection point with the reduced pore pressure at tunnel centerline are also suggested.

• The Journal of Korean Medicine
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• v.25 no.1
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• pp.161-171
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• 2004

Objectives: Sasang Constitutional Medicine is popularly appliedto treatment in Korea. Constitution is a holistic concept contained internal and external characteristics, and physical traits including ordinary symptoms. Skin is one of constitutional property elements. So we researched a correlation female facial skin and sasang constitution. This is a basic study to find constitution can be a major factor to care and manage skin. Methods: We examined sasang constitution and facial skin condition of 100 healthy women who aged from 30 to 59. Hydration and sebum of facial skin was measured by skin diagnostic instrument and skin type was calculated from the data. Keratin, pore size, acne, and brightness of face was measured by skin magnifying lens and subjective skin troubles in ordinary times was also investigated. Constitution diagnosis and Skin diagnosis was investigated separately as a blind test andthe data was statistically analyzed with chi-square test, Correlation analysis, One-way analysis of variance. Results: 1. In sasang constitution, Taeeumingroup bad significant tendencies of larger hydration and sebum amount, combination degree of forehead and cheek was also higher than other constitutions(p<0.05). 2. Facial skin type was significantly different according to Sasang Constitution, Soeumin and Soyangin had a tendency of dry skin comparatively, but Taeeumin had mainly a tendency of combination skin and secondly dry skin(p<0.05). On the other hand, there was no correlation between age and skin type. 3. In subjective skin trouble, Soeumin group had less acne trouble than Soyangin and Taeeumin group(p<0.1). Pore size trouble was more frequent in Soyangin group than Soeumin group(p<0.05). Keratin trouble was more frequent in Soeumin group than Soyangin and Taeumin group(p<0.1). Conclusions: Korean healthy women's skin condition was different according to sasang constitution.

• Journal of the Korean Applied Science and Technology
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• v.22 no.4
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• pp.306-314
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• 2005

In this study, spherical $pre-BaTiO_3$ particles are prepared by gelation and aging process in autoclave without catalysts. The (Ba-Ti) gel used as a starting material was prepared by aging mixtures of titanyl acylate with barium acetate aqueous solution([glacial acetic acid (AcOH)]/[titanium isopropoxide (TIP)] 4, [barium acetate]/[TIP] 1) at $45^{\circ}C$ for 48hrs. XRD and SEM results for the (Ba-Ti) gel sample at aging process showed that the gel was formed via aggregation of the fine particles. It seems to be the primary particles of bulk (Ba-Ti) gel amorphous, but the spatial arrangement of barium and titanium in the (Ba-Ti) gel is similar to that in crystalline $BaTiO_3$ particles. From XRD and FT-IR. spectroscopy analysis it was found that the crystal structure of the prepared particles continuously transformed from amorphous to tetragonal as the calcination temperature increased, and crystallized spherical cubic and tetragonal $BaTiO_3$ powder obtained at the very low calcination temperature between $500^{\circ}C$ and $900^{\circ}C$ after 1hrs of heat treatment respectively. According to BET analysis result, final particle have pore structure of ink bottle shape which is produced by aggregation of fine spherical particles with surface area of $280m^2/g$ and average pore size of 130nm.

• Journal of the Korean Geosynthetics Society
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• v.9 no.3
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• pp.39-45
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• 2010

When the ground temperature drops below $0^{\circ}C$, wet soils expand due to the ice formation in their porous space. This results in frost heave which causes structural stability problems. Frost heave is attributed by several factors such as physical soil properties and heat transfer including pore water phase change. Due to the complex physical phenomena, reliable and verified multi-dimensional numerical models for frost heave problems are still in a research stage. This study presents an efficient and simple method of overcoming numerical problems associated with sudden jump of heat capacity due to the phase change from water to ice in the pore space. This paper proposes heat transfer equation and finite element method when the saturated soils or porous rocks are subjected to freezing. Numerical analyses using the proposed method agree well with the known closed form solution and the laboratory test results.

• Geomechanics and Engineering
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• v.20 no.2
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• pp.87-101
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• 2020

The construction of combined pile-raft foundations is considered as the main option in designing foundations in high-rise buildings, especially in soils close to the ground surface which do not have sufficient bearing capacity to withstand building loads. This paper deals with the geotechnical report of the Northern Fereshteh area of Tabriz, Iran, and compares the characteristics of the single pile foundation with the two foundations of pile group and geogrid. Besides, we investigate the effects of five principal parameters including pile diameter and length, the number of geogrid layers, the depth of groundwater level, and pore water pressure on vertical consolidation settlement and pore water pressure changes over a year. This study assessed the mechanism of the failure of the soil under the foundation using numerical analysis as well. Numerical analysis was performed using the two-dimensional finite element PLAXIS software. The results of fifty-four models indicate that the diameter of the pile tip, either as a pile group or as a single pile, did not have a significant effect on the reduction of the consolidation settlement in the soil in the Northern Fereshteh Street region. The optimum length for the pile in the Northern Fereshteh area is 12 meters, which is economically feasible. In addition, the construction of four-layered ten-meter-long geogrids at intervals of 1 meter beneath the deep foundation had a significant preventive impact on the consolidation settlement in clayey soils.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.1C
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• pp.1-10
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• 2011

This paper simulates the piping effect, found levees with large difference in coefficient of permeability within the foundation such as the Gim-po Levee, via centrifuge model test which is a model test. We have also conducted a numerical analysis under the same conditions as the centrifuge model test to compare its results. First, we decided to use the centrifuge model based on the Gim-po Levee, and the tests were executed on a model levee with pore water pressure transducers. We have found that most of the water flows through the permeable layer and causes the piping effect. Via video camera footage, we have found that the piping effect occurred at the toe of the model levee. The characteristic of pressure head distribution, obtained from the pore water pressure transducers, also proves the occurrence of the piping effect. The numerical analysis results also showed the same results as the centrifuge model test. We have simulated the piping effect via centrifuge model test and believe that the centrifuge model test is viable for various tests, predictions and evaluation of the levee problems.

• Journal of Electrochemical Science and Technology
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• v.2 no.3
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• pp.131-135
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• 2011

It is, in general, believed that during the activation process, the proton conductivity increases due to wetting effect and the electrochemical resistance reduction, resulting in an increase in the fuel cell performance with time. However, until now, very scant information is available on the understanding of activation processes. In this study, dominant variables that effect on the performance increase of membrane electrode assemblies (MEAs) during the activation process were investigated. Wetting, pore restructuring and active metal utilization were analyzed systematically. Unexpectedly, the changes for both ohmic and reaction resistance characterized by the electrochemical impedance spectroscopy (EIS) after initial wetting process were much smaller when considering the degree of cell performance increases. However, the EIS spectra represents that the pore opening of electrode turns into gas transportable structure more easily. The increase in the performance with activation cycles was also investigated in a view of active metals. Though the particle size was grown, the number of effective active sites might be exposed more. The impurity removal and catalytic activity enhancement measured by cyclic voltammetry (CV) could be a strong evident. The results and analysis revealed that, not merely wetting of membrane but also restructuring of electrodeand catalytic activity increase are important factors for the fast and efficient activation of the polymer electrolyte fuel cells.