• Title/Summary/Keyword: pore analysis

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Experimental Study on Seismic Performance Evaluation of Lake Dike Structures under Earthquake Loading (지진하중에 의한 방수제 구조물의 내진성능 평가를 위한 실험적 연구)

  • Shin, Eun-Chul;Kang, Hyeon-Hoe;Kim, Tae-Jin;Chae, Young-Su;Park, Jeong-Jun
    • Journal of the Korean Geosynthetics Society
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    • v.10 no.3
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    • pp.53-62
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    • 2011
  • This paper presents the characteristics behavior of dike structure and foundation ground through the shaking table model test. The vibration loadings of design earthquake acceleration of 0.154g was applied to this laboratory model test regarding on dike structure and foundation ground under the structure. The model was formulated with 1/100 design of representative cross section for evaluating the effectiveness of vibration. Based on the test results, we can analysis the behavior of lateral displacement and settlement characteristics of structure under the earthquake loading. The pore water pressure was also monitored in the upper, middle and lower layers of ground. Finally, the actual displacements and pore water pressure of the structure can be predicted by using the results of the laboratory shaking table test.

Synthesis of Aminated Hollow PP-g-GMA Fibrous Ion-Exchanger for Separation of Urokinase (유로키나제 분리를 위한 아민화 HPP-g-GMA 중공사 이온교환체의 합성에 관한 연구)

  • 황택성;이진혁
    • Polymer(Korea)
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    • v.26 no.2
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    • pp.160-167
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    • 2002
  • We synthesized HPP-g-GMA copolymer using pre-irradiation method by E-beam and aminated HPP-g-GMA using amination reaction. Degree of grafting increased with increasing GMA monomer concentration and showed the maximum value of 130% at 1.46 M of GMA. The degree of amination increased with increasing the degree of grafting. When the degree of grafting was 100%, degree of amination showed the maximum value of 37.4%. The ion exchange capacity of aminated HPP-g-GMA was about 3.78 meq/g, and it showed remarkable adsorption ability of hollow fiber ion exchanger. Through the BET analysis, the surface area of aminated HPP-g-GMA was 54.83 $\m^2/g$ and the mean pore size was $26\AA$. These showed the decrease of surface area and the slight increase of the mean pore size. SEM results show that the thickness of fiber increased after the step of reaction and there pore blocking phenomena was not observed. The aminated HPP-g-GMA was synthesized successfully and found to be suitable for the adsorption and separation of anion.

Fabrication of Porous W by Freeze-Drying Process of Camphene Slurries with Spherical PMMA and WO3 Powders (구형 PMMA와 WO3 분말이 혼합된 Camphene 슬러리의 동결건조에 의한 W 다공체 제조)

  • Lee, Han-Eol;Jeon, Ki Cheol;Kim, Young Do;Suk, Myung-Jin;Oh, Sung-Tag
    • Korean Journal of Materials Research
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    • v.25 no.11
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    • pp.602-606
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    • 2015
  • Porous W with spherical and directionally aligned pores was fabricated by the combination of sacrificial fugitives and a freeze-drying process. Camphene slurries with powder mixtures of $WO_3$ and spherical PMMA of 20 vol% were frozen at $-25^{\circ}C$ and dried for the sublimation of the camphene. The green bodies were heat-treated at $400^{\circ}C$ for 2 h to decompose the PMMA; then, sintering was carried out at $1200^{\circ}C$ in a hydrogen atmosphere for 2 h. TGA and XRD analysis showed that the PMMA decomposed at about $400^{\circ}C$, and $WO_3$ was reduced to metallic W at $800^{\circ}C$ without any reaction phases. The sintered bodies with $WO_3$-PMMA contents of 15 and 20 vol% showed large pores with aligned direction and small pores in the internal walls of the large pores. The pore formation was discussed in terms of the solidication behavior of liquid camphene with solid particles. Spherical pores, formed by decomposition of PMMA, were observed in the sintered specimens. Also, microstructural observation revealed that struts between the small pores consisted of very fine particles with size of about 300 nm.

A Study on the Evaluation of Liquefaction of Sandy Soils by the Cyclic Triaxial Compression Test (反復三軸壓縮試驗에 의한 砂質土의 液狀化 評價에 관한 硏究)

  • Koh, Jae-Man;Doh, Duk-Hyun
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.33 no.3
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    • pp.51-62
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    • 1991
  • A comprehensive laboratory investigation of the liquefaction characteristics of Jumunjin standard sand. Seoul sand and Hongsung sand was peformed by the undrained cyclic triaxial compression test under different relative densities, confining pressures and cyclic deviator stresses. The results obtained are as follows ; 1. Liquefaction potential was dominated by the stress ratio at a given number of cycle. That is, the number of cycle required to cause initial liquefaction became samller as the stress ratio increased. 2. Liquefaction potential of a sand was infliuenced by initial relative density or void ratio. Under a given relative density. liquefaction potential of Jumunjin standard sand and Seoul sand was smaller than that of Hongsung sand. 3. The pore pressure ratio of Hongsung sand was the smallest three under a given relative density and stress ratio, and it showed higher value when the cyclic stress and the shear strain were high. 4. An excessive pore pressure ratio not found when initial shear was smaller than 0.01%, and the pore pressure ratio started to increase when initial shear became greater than 0.01%. 5. Soil texture is an important factor to cause liquefaction, and liquefaction potential decreased a the mean grain size decreased. however the sand having fine grain such as Hongsung sand showed somewhat higher liquefaction potential. 6. Based on the analysis of the specimens whose number of the cycles to cause liquefaction was 8~12, it was found that the relationship between density and stress ratio was linear. The curves for Hongsung sand was steeper than the other. 7. From the above results and the method suggested by Seed-Idriss, it may be considered that the damages by Hongsung earthquake was not directly caused by liquefaction.

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Application of Optimum Design Technique in Determining the Coefficient of Consolidation Using Piezocone Test (피에조 콘 시험을 이용정회원, 한국과학기술원 토목공학과 부교수, 정회원, 한국과학기술원 토목공학과 박사 후 과정한 망일계수 결정시 최적화 기법의 적용)

  • Kim, Yeong-Sang;Lee, Seung-Rae;Kim, Yun-Tae
    • Geotechnical Engineering
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    • v.13 no.4
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    • pp.95-108
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    • 1997
  • For normally consolidated clay, several researchers have developed a number of theoretical time factors to determine the coefficient of consolidation However, depending on the assumptions and analytical techniques, it could considerably vary even for a specific degree of consolidation. In this paper, a method is proposed to determine a consistent coefficient of consolidation over all ranges of degree of consolidation by applying the concept of the Optimum Design Technique. The initial excess pore pressure distribution is assumed to be obtainable by the successive spherical cavity expansion theory. The dissipation of pore pressure is simulated by means of two dimensional linear-uncoupled axisymmetric consolidation analysis. The minimization of the differences between the measured and the predicted excess pore pressures was carried by BFGS unconstrained optimum design algorithm with one dimensional golden section search technique. By analyzing numerical and real field examples, it can be found that the adopted optimum technique gives a consistent and convergent results.

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Electrochemical properties and Estimation of $LiMnO_{2}$ Active Material Synthesis for Secondary Batteries (2차 전지용 $LiMnO_{2}$ 활물질 합성의 전기화학적 특성과 평가)

  • Wee, Sung-Dong;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.210-215
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    • 2002
  • This thesis is contents on the crystal grown by the solide phase method at $925^{\circ}C$ with orthorhombic structure that $LiMnO_{2}$ active material synthesised with precurse $Mn_{2}O_{3}$ and $LiOH.H_{2}O$ material to get three voltage level. The porosity analysis of the grown crystal in secondary batteries $LiMnO_{2}$ thin film is $1.323E+02\AA$ of the average pore diameter of powder particles and its structure to be taken the pore diameter was prepared. Adding voltage area to get properties of charge and discharge of which experiment result of $LiMnO_{2}$ thin film area 2.2V~4.3V, current and scan speed were 0.1mAh/g and $0.2mV/cm^{2}$ respectively, and properties of the charge and discharge to be got optimum experiment condition parameter and density rate of Li for analyze that unit discharge capacity with metal properties is 87mAh/g was 96.9[ppm] at 670.784[nm] wavelength, and density rate of Mn analyzed 837[ppm] at 257.610[nm]. It can be estimated the quality of thin film that wrong cell reject from the bottle of electrolyte. The results of SEM and XRD were the same that of original researchers.

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Effect of Milling Time on Pore Size and Distribution of Ti-Nb-Zr Biomaterials with Space Holder Consolidated by Spark Plasma Sintering

  • Kim, Dong-Gun;Woo, Kee-Do;Kang, Dong-Soo;Lee, Tack
    • Korean Journal of Materials Research
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    • v.24 no.2
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    • pp.111-115
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    • 2014
  • Titanium and its alloys are useful for implant materials. In this study, porous Ti-Nb-Zr biomaterials were successfully synthesized by powder metallurgy using a $NH_4HCO_3$ as space holder and $TiH_2$ as foaming agent. Consolidation of powder was accomplished by spark plasma sintering process(SPS) at $850^{\circ}C$ under 30 MPa condition. The effect of high energy milling time on pore size and distribution in Ti-Nb-Zr alloys with space holder($NH_4HCO_3$) was investigated by optical microscope(OM), scanning electron microscope(SEM) & energy dispersive spectroscopy(EDS) and X-ray diffraction(XRD). Microstructure observation revealed that, a lot of pores were uniformly distributed in the Ti-Nb-Zr alloys as size of about $30-100{\mu}m$ using mixed powder and milled powders. In addition, the pore ratio was found to be about 5-20% by image analysis, using an image analyzer(Image Pro Plus). Furthermore, the physical properties of specimens were improved with increasing milling time as results of hardness, relative density, compressive strength and Young's modulus. Particularly Young's modulus of the sintered alloy using 4h milled powder reached 52 GPa which is similar to bone elastic modulus.

Influence of the Pore Properties on Carbon Dioxide Adsorption of PAN-based Activated Carbon Nanofibers (폴리아크릴로니트릴계 활성나노탄소섬유의 기공특성이 이산화탄소 흡착에 미치는 영향)

  • Lee, Dayoung;Cho, Seho;Kim, Yesol;Lee, Young-Seak
    • Polymer(Korea)
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    • v.37 no.5
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    • pp.592-599
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    • 2013
  • In this study, polyacrylonitrile (PAN)-based porous carbon nanofibers were prepared from PAN polymer solution by electrospinning and KOH activation with various concentrations, and the characterization of pore structures and carbon dioxide adsorption was investigated. Manufactured PAN-based activated carbon nanofibers tend to decrease diameter and increase surface oxygen functional groups depending on the increasing concentration of KOH solution. In addition, according to the results of nitrogen adsorption for pore properties analysis, it indicated increase of the specific surface area in conformity with increasing concentration of KOH solution. Micropore volume of treated activated carbon nanofibers (ANCF) by 4 M KOH was the largest compared with other samples and mesopore volume of treated ANCF by 8 M KOH was the largest volume, respectively. The concentration of KOH effects textural and surface properties, as represented by BET and XPS, which enhance carbon dioxide adsorption capacity at 0 and $25^{\circ}C$.

Treatment Characteristics of Acid Mine Drainage by Porous Ceramics using Wood Flour as Pore-forming Agent (목분 기포제를 이용한 산업부산물 소재 다공성 세라믹에 의한 산성광산배수의 처리특성 연구)

  • Lee, Yeong-Nam;Yim, Soo-Bin
    • Journal of Environmental Science International
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    • v.27 no.2
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    • pp.109-122
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    • 2018
  • This study was conducted to investigate the removal characteristics of heavy metals and sulfate ion from acid mine drainage by porous zeolite-slag ceramics (ZS ceramics) that was prepared by adding wood flour as pore-foaming agent while calcining the mixtures of natural zeolite and converter slag. The batch test showed that the removal efficiency of heavy metals by pellet-type porous ZS ceramics increased as the particle size of wood flour was decreased and as the weight mixing ratio of wood flour to ZS ceramics was increased. The optimal particle size and weight mixing ratio of wood flour were measured to be $75{\mu}m$ and 7~10%, respectively. The removal test with the porous ZS ceramics prepared in these optimal condition showed very high removal efficiencies: more than 98.4% for all heavy metals and 73.9% for sulfate ion. Relative to nonporous ZS ceramics, the increment of removal efficiency of heavy metals by porous ZS ceramics with $75{\mu}m$ and 10% wood flour was 5.8%, 60.5%, 36.9%, 87.7%, 10.3%, and 57.4% for Al, Cd, Cu, Mn, Pb, and Zn, respectively. The mechanism analysis of removal by the porous ZS ceramics suggested that the heavy metals and sulfate ion from acid mine drainage are eliminated by multiple reactions such as adsorption and/or ion exchange as well as precipitation and/or co-precipitation.

Consolidation Behaviour of Dredged Clay Ground Improved by Horizontal Drain Method (수평배수공법에 의해 개량된 준설점토지반의 압밀거동에 관한 연구)

  • 김형주;원명수
    • Geotechnical Engineering
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    • v.13 no.1
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    • pp.137-146
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    • 1997
  • In this study, a large consolidation test was carried out to estimate the consolidation behaviour of dredged clay ground improved by horizontal drain using plastic board drain with a vacuum pressure. The test results were analyzed by a numerical simulation using potential consolidation theory applied to a hollow cylinder. The rapid decreases in pore pressure and the drain speed in the plastic board indicate that the consolidation occurred quickly after the vacuum state was applied to the test soil. According to the numerical analysis obtained by applying the linear potential consolidation theory to a clay hollow cylinder with external radial drainage, the pore pressure is affected by the strain and the permeability of the soil rather than by the diffusion types. Therefore, measured surface settlement agreed with the numerical solution at the point where consolidation pressure increasing rate u: -0.5. Also the behaviour of the clay layer settlement in the place where the drain was installed was similar to that shown in Barron's consolidation theory. Finally, the design and construction procedure including the selection of the appropriate arrangement of horizontal drains were discussed based on the results of the laboratory tutsts. It is also shown that the potential consolidation theory make it possible to predict consolidation behaviour in the field using horizontal drains exactly.

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