• Korean Journal of Materials Research
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• v.22 no.10
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• pp.526-530
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• 2012

Silica-based ceramic-matrix composites have shown promise as advanced materials for many applications such as chemical catalysts, ceramics, pharmaceuticals, and electronics. $SiO_2$-CuO-$CeO_2$ multi-component powders and their thin film, using an oxalic acid template as a chelating agent, have larger surface areas and more uniform pore size distribution than those of inorganic acid catalysts. $SiO_2$-CuO-$CeO_2$ composite powders were synthesized using tetraethylorthosilicate, copper (II) nitrate hemi (pentahydrate), and cerium (III) nitrate hexahydrate with oxalic acid as template or pore-forming agent. The process of thermal evolution, the phase composition, and the surface morphology of these powders were monitored by thermogravimetry-differential thermal analysis (TG-DTA), X-ray diffractometry (XRD), field-emission scanning electron microscopy (FE-SEM), and energy dispersive X-ray spectrometry (EDXS). The mesoporous property of the powders was observed by Brunner-Emmett-Teller surface (BET) analysis. The improved surface area of this powder template with oxalic acid was $371.4m^2/g$. This multi-component thin film on stainless-steel was prepared by sol-gel dip coating with no cracks.

• Geomechanics and Engineering
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• v.37 no.4
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• pp.359-370
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• 2024

The primary goal of this study is to evaluate the migration of fine granular materials into overlying layers under cyclic loading using a modified large-scale triaxial system as a physical model test. Samples prepared for the modified large-scale triaxial system comprised a 60 mm thick gravel layer overlying a 120 mm thick subgrade layer, which could be either tailings or railway sand. A quantitative analysis of the migration of fine granular materials was based on the mass percentage and grain size of migrated materials collected in the gravel. In addition, the cyclic characteristics, i.e., accumulated axial strain and excess pore water pressure, were evaluated. As a result, the total migration rate of the railway sand sample was found to be small. However, the total migration rate of the sample containing tailings in the subgrade layer was much higher than that of the railway sand sample. In addition, the migration analysis revealed that finer tailings particles tended to be migrated into the upper gravel layer easier than coarser tailings particles under cyclic loading. This could be involved in significant increases in excess pore water pressure at the last cycles of the physical model test.

• Journal of the Korean Ceramic Society
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• v.53 no.2
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• pp.194-199
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• 2016

Presently, for the cement industry, studies that seek to reduce $CO_2$, because of the development of the plastic industry and demand for reduction of energy use, have been actively conducted among them, studies attempting to use Gamma-$C_2S({\gamma}-C_2S)$ to fix $CO_2$ have been actively conducted. The ${\gamma}-C_2S$ compound has an important function in reacting to $CO_2$ and stiffening through carbonatization in the air. The ${\gamma}-C_2S$ compound, reacting to $CO_2$ in the air, generates $CaCO_2$ within the pore structure of cement materials and densifies the pore structure this leads to an improvement of the durability and to the characteristic of resistance against neutralization. Therefore, in this experiment, in order to synthesize ${\gamma}-C_2S$, limestone sludge and waste foundry sands are used these materials are plasticized for 30 or 60 minutes at $1450^{\circ}C$, and are prevented from being cooled in the temperature range of $30{\sim}1000^{\circ}C$ when they are about to be cooled. XRD analysis and XRF analysis are used to determine the effects of this process on ${\gamma}-C_2S$ synthesization, the temperature at which a thing is plasticized, and the conditions for cooling that obtain in the plasticized clinker also, in order to confirm the $CO_2$ capture function, analysis of the major hydration products is conducted through an analysis of carbonatization depth and compressive strength, and through MIP analysis and XRD Rietveld analysis. As a result of these analyses, it is found that when ${\gamma}-C_2S$ was synthesized, the clinker that was plasticized at $1450^{\circ}C$ for one hour demonstrated the highest yield rate the sample with which the ${\gamma}-C_2S$ was mixed generated $CaCO_3$ when it reacted with $CO_2$ therefore, carbonatization depth and porosity were reduced, and the compressive strength was increased.

• Journal of Korean Tunnelling and Underground Space Association
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• v.15 no.3
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• pp.333-344
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• 2013

This paper discussed about the effect of permeability reduction of the jointed rock mass in the vicinity of a tunnel which is one of the reasons making large difference between the estimated ground-water inflow rate and the measured value. Current practice assumes that the jointed rock mass around a tunnel is a homogeneous, isotropic porous medium with constant permeability. However, in actual condition the permeability of a jointed rock mass varies with the change of effective stress condition around a tunnel, and in turn effective stress condition is affected by the ground water flow in the jointed rock mass around the tunnel. In short time after tunnel excavation, large increase of effective tangential stress around a tunnel due to stress concentration and pore-water pressure drop, and consequently large joint closure followed by significant permeability reduction of jointed rock mass in the vicinity of a tunnel takes place. A significant pore-water pressure drop takes place across this ring zone in the vicinity of a tunnel, and the actual pore-water pressure distribution around a tunnel shows large difference from the value estimated by an analytical solution assuming the jointed rock mass around the tunnel as a homogeneous, isotropic medium. This paper presents the analytical solution estimating pore-water pressure distribution and ground-water inflow rate into a tunnel based on the concept of hydro-mechanically coupled behavior of a jointed rock mass and the solution is verified by numerical analysis.

• Journal of the Korean Geotechnical Society
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• v.19 no.6
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• pp.363-369
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• 2003

The purpose of this study is to understand the dissipation pattern of excess pore pressure after liquefaction and to estimate the variation in permeability during shaking load, which should be known for settlement predictions of the ground undergoing liquefaction. In this study, 1-g shaking table tests were carried out for 5 different kinds of sands, all of which had high liquefaction potentials. During the tests excess pore pressure at various depths, and surface settlements were measured. The measured dissipation curve of the excess pore pressure after liquefaction was linearly simulated using the solidification theory, and from the analysis of the slopes of linearly simulated curves, the correlation between dissipation velocity and the gradation characteristics was obtained. By substituting this correlation and the measured settlement to the dissipation velocity equation recommended in solidification theory, the permeability during dissipation was calculated, which was used for estimating the permeability variation during shaking load. The dissipation velocity of excess pore pressure after liquefaction had a linear correlation with the effective grain size divided by the coefficient of uniformity. The permeability during dissipation and liquefaction increased by 1.1∼2.8 times and 1.4∼5 times compared to the initial permeability of the original ground, respectively. And the amount of increase became greater as the effective grain size of the test sand increased and the coefficient of uniformity decreased.

• Journal of the Korean Geotechnical Society
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• v.31 no.8
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• pp.5-15
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• 2015

One-dimensional rainfall laboratory tests using gneissic weathered soil were conducted to investigate effect of antecedent rainfall on infiltration characteristics. Experimental results using samples from Chuncheon and Chungju sites showed that rainfall onto the ground surface decreased initial negative pore water pressure of unsaturated soils, which recovered gradually after the end of rainfall. Rainfall intensity increases water infiltration rate, and infiltration rate during main rainfall is faster than that of the preceding rainfall. It is considered that higher water saturation after antecedent rainfall increases water infiltration rate during main rainfall. In particular, Chungju sample with higher clay content had slower recovery of negative pore water pressure and infiltration rate. Numerical results using finite element slope stability analysis showed that reduction of initial negative pore pressure due to rainfall infiltration deteriorates slope stability, and diffusion of pore water pressure after the end of rainfall further reduces FS of the slope in the short term. Main rainfall after prior rainfall further reduced factor of safety of the unsaturated slope. Pattern of antecedent rainfall has a significant impact on the magnitude and distribution of initial pore water pressure in unsaturated soils which are controlling factor to assess factor of safety of unsaturated slope during rainfall.

• Applied Chemistry for Engineering
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• v.29 no.2
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• pp.237-243
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• 2018

The surface chemistry of WCK-AC, WCN-AC and WCZ-AC which are activated carbons prepared from waste citrus peel using KOH, NaOH, and $ZnCl_2$ as activating chemicals were investigated. Also the relationships between the adsorption capacities of the target gases such as acetone, benzene and methyl mercaptan (MM) by the prepared activated carbons and the pore characteristics of each activated carbon were examined. According to XPS analysis of the prepared activated carbons, graphite and phenolic were the main surface functional groups of C1, and the sum of phenol, carbonyl and carboxyl groups increased in the order of WCK-AC > WCN-AC > WCZ-AC. The breakthrough curves obtained from the adsorption experiments for the three target gases in the fixed bed adsorption reactor were well simulated by the empirical equations proposed by Yoon and Nelson. The adsorption capacity for acetone, benzene and MM was larger for activated carbons with the larger sum of surface functional groups. The larger the specific surface area and the pore volume of activated carbons and the smaller the pore size, the better the adsorption performance. In particular, the specific surface area was the best criterion for the adsorption performance of activated carbons used in this study.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.8 no.3
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• pp.91-100
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• 1988

Assuming that tidal level is constantly changed with an amplitude of 10 meters and a cycle of 12 hours, the slope stability for a typical dyke is analysed. The variation of pore water pressure within the dyke during the tidal change is obtained using a computer program, FLUMP, which is incorporated with saturated-unsaturated and transient flow. The results show that the variation of free water surface and distribution of pore water pressure within the dyke during the tidal fluctuations can be clearly predicted with the computer program. When a tide is lowered to the minimum level, the predicted pressure head is higher than the level of the free water surface in some parts of the dyke; that is, excess pore water pressure is generated in a zone affected by the tidal change. Also an unsaturated zone which shows negative pore water pressure is temporally created when a tide is lowered. The shear strength of the zone can be predicted based on the proposal suggested by Fredlund et al. It is emphasized that the excess pore water pressure generated during tidal fluctuations and strength parameters for the unsaturated zone should be considered in analyzing the slope stability of dykes. When those are considered, the critical slip surface seems to be located below the free water surface obtained when a tide is at the lowest.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.28 no.6
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• pp.361-374
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• 2016

When the seabed around and under gravity structures such as submerged breakwater is exposed to a large wave action long period, the excess pore pressure is generated significantly due to pore volume change associated with rearrangement soil grains. This effect leads a seabed liquefaction around and under structures as a result from decrease in the effective stress, and the possibility of structure failure is increased eventually. These facts shown above have been investigated in the previous studies related to regular and irregular waves. This study suggested a concrete mat for preventing the seabed liquefaction near the submerged breakwater. The concrete mat was mainly used as a countermeasure for scouring protection in riverbed. According to installation of the concrete mattress, the time and spatial series of the deformation of submerged breakwater, the pore water pressure, and the pore water pressure ratio in the seabed were investigated. Their results were also compared with those of the seabed unprotected with the concrete mat. The results presented were confirmed that the liquefaction potential of seabed under the concrete mattress is significantly reduced under regular wave field.

• Economic and Environmental Geology
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• v.40 no.5
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• pp.551-561
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• 2007

This case study is about the sampling and interpretation of soil pore water in order to understand and to predict the diffusion and behavior of soil pollution. For the measurement of polycyclic aromatic hydrocarbons(PAHs) in two representative hydrocarbon-contaminated sites, the extraction system of the soil pore water was set up with respect to soil depths and the behavior of contaminants was interpreted. The soil solution extraction system consisted of peristaltic pump, and extraction and sampling compartment, and can measure simultaneously the soil water pressure. The concentration of PAHs with respect to extraction pressure and time decreased due to dilution through soil pore water. Particularly, the concentration of PAHs was more reduced under the unsaturated oxic condition than saturated anoxic condition. Therefore, the soil solution extraction with respect to soil water pressure can interpret the extent of equilibrium between porewater and soil surface.