• Bulletin of the Korean Chemical Society
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• v.33 no.11
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• pp.3711-3718
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• 2012

Here, we report a chain-length dependent morphology and pore structure tailing of mesoporous silica templated from organogels, which is formed by primary alkylamine and ethylene glycol at room temperature. As the chain length of alkylamine changes from 12 to 18, the resulted materials exhibit a morphology change from layers to spheres and platelets, respectively. SEM and TEM observation revealed that these shapes appear to be inherited from their parent organogels. Further pore structure characterization by nitrogen sorption analysis demonstrates that all the resulted silicas exhibit typical IV isotherms indicative of uniform mesopores, and their pore sizes are dependent on the chain length of alkylamine used.

• Transactions of the Korean Society of Mechanical Engineers
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• v.11 no.3
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• pp.368-375
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• 1987

Effective thermal conductivity of the porous nuclear fuel has been investigated numerically. Difficulties associated with irregular shape of pore have been overcome by using the Body Fitted Coordinate Systems. A computer code has been developed to solve the governing equation with appropriate boundary conditions by transforming from the Cartesian coordinates to the nonorthogonal curvilinear coordinates. The effects of the porosity have been investigated. For a convenient use of the result, a correlation equation was suggested under the assumption of circular pore. The computation results by the assumption of randomly oriented elliptic pore has been agreed more closely to existing experimental result than that by the assumption of circular pore.

• Geomechanics and Engineering
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• v.39 no.1
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• pp.73-85
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• 2024

There is growing interest in introducing artificial ground freezing (AGF) as a method to temporarily secure unstable ground during tunnel construction. In order to efficiently operate an artificial ground freezing system, basic modeling research is needed on the changes in freezing behavior according to various soil environmental conditions as well as design conditions. In this study, a thermal-hydraulic coupled analysis was performed to simulate the artificial ground freezing process of ground containing salt water. The effect of major variables, including pore water salinity, on artificial ground freezing test performance was investigated. Additionally, an artificial neural network-based prediction model was proposed to estimate the time required to achieve the desired arch thickness. The artificial neural network model demonstrated reliable accuracy (R² = 0.9942) in predicting the time it would take to reach the desired arch thickness. Among the major input variables considered, pore water salinity appeared to be the most influential input variable, and initial soil temperature showed the least importance.

• Biotechnology and Bioprocess Engineering:BBE
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• v.9 no.6
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• pp.495-499
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• 2004

The analyses of peak shapes in chromatography are useful in operating chroma­tographic system. The asymmetry and sharpness of a chromatographic peak are estimated by the reversed-phase adsorption of two standard peptides (angiotensin II bradykinin) on $C_{18}$ In this work, the average particle diameters of $C_{18}$ were 5 and 15 $\mu$m, while the pore sizes were 100 and 300 A. The composition of the mobile phase was $50/50\;vol.\;{\%}$ of a binary mixture of acetonitrile and water with $0.1\%$ TFA, and the particles were packed in a stainless column ($4.6{\times}150$ mm). The third and the fourth central movement were calculated from the chromatographic elution curves by moment analysis. The peak asymmetry was determined by two theoretical calculations: the asymmetry factor by elution peak analysis and skewness with moment analysis. The sharpness was estimated by the fourth central moment. In this work, the most acceptable skewness was calculated when the pore size was 300 A. The large excess was observed on small pore size.

• Geomechanics and Engineering
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• v.21 no.5
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• pp.423-432
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• 2020

Hydraulic conductivity is one of the engineering properties of soil. This study focusses on the influence of cement content on the hydraulic conductivity of cemented sand, which is investigated based on the results from numerical analysis and laboratory testing. For numerical analysis the cemented samples were scanned using X-ray Computed Tomography (CT) while laboratory testing was carried out using a triaxial setup. Numerical analysis enables us to simulate flow through the sample and provides insight to the microstructure. It quantifies the pore volume, proportion of interconnected voids and pore size distribution in both cemented and uncemented samples, which could be computed only through empirical equations in case of laboratory testing. With reduction in global voids, the interconnecting voids within the samples also reduce with cement content. Gamma cumulative distribution function is used to predict the percentage of voids lesser than a given pore volume. Finally, the results obtained from both numerical analysis and laboratory testing are compared.

• Journal of the Korean Geotechnical Society
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• v.20 no.3
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• pp.33-46
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• 2004

This paper presents the effect of groundwater on tunnel excavation. Fundamental issues in tunneling under high groundwater table are discussed and the effect of groundwater on tunnel excavation was examined using a 3D stress-pore pressure coupled finite-element analysis. Based on the results the interaction mechanism between the tunnelling and groundwater is identified for cases having different lining permeabilities. Examined items include pore pressures around lining and lining stresses. Face deformation behavior as well as ground surface movement patterns was also examined. Besides, the effect of grouting pattern was investigated. The results indicated that the effect of groundwater on tunnel excavation increases lining stresses as well as ground movements, and that the tunnel excavation and groundwater interaction can only be captured through a fully coupled analysis. Implementations of the findings from this study are discussed in great detail.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.03a
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• pp.1060-1067
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• 2009

Previous research on the slope failure has mainly reported that most of the slope failures occur due to surface rainfall infiltration in the rainy season. A slope of which surface is protected by shotcrete or plants, can also fail due to increase in pore water pressure from the ground water flow beneath the surface, rather than from the surface. In this study such case of slope behavior is investigated using the model test and numerical method including strength reduction method. Hydraulic boundary conditions of the slopes is considered using coupled numerical scheme. The failure mechanism of the slope is investigated and the effect of pore water pressure on slope safety is identified. Increase in pore water pressure due to lateral infiltration has significantly reduced the stability of slope.

• Carbon letters
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• v.8 no.1
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• pp.17-24
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• 2007

Microporous carbons with narrow pore size distribution have been successfully synthesized by using hydrolyzed and calcined silica as templates and phenol formaldehyde (pf) resin as carbon precursor. Phenol formaldehyde-silica micro composites were prepared by solution route. Subsesequently, silica templates were removed by HF leaching. Resulting carbons were steam activated. The porous carbons were characterized by nitrogen adsorption-desorption isotherm, SEM, FTIR analysis, iodine adsorption, thermogravimetry analysis, etc. Adsorption isotherms show that the porous carbon prepared from calcined silica as templates are microporous with 88% pores of size <2 nm porosity and are of type I isotherm, while porous carbon prepared by using hydrolyzed silica are microporous with 89% microporosity, shows hysteresis loop at high relative pressure indicating the presence of some mesoporosity in samples. The microporosity in porous carbon materials has a bearing on the nature of silica templates used for pore formation.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.22 no.7
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• pp.448-453
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• 2010

Porous media containing complex fluid passage have especially large surface area per unit volume. This study is aimed to identify the heat transfer characteristics of high-porosity metal foams in a horizontal channel. Experiment is performed under various heat flux, velocity and pore density. Nusselt number decreases with higher pore density. Metal foams shows higher heat transfer coefficients than pin-fin structure with the same porosity. This is due to the more complex flow passage and larger heat transfer area based on the structure of the metal foams. The analysis on the pin-fin structure may not be suitable to the metal foam structure but should be identified extensively through further study.

• Advances in Computational Design
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• v.1 no.3
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• pp.265-274
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• 2016

The present paper describes the results of numerical modeling of a dam founded on loose liquefiable deposit using PLAXIS-3D finite element software. Effect of a different dam water level on parameters like displacements, Excess Pore water pressures, Liquefaction potential and Accelerations is studied. El- Centro earthquake motion is applied as input earthquake motion. The results of this study show that different upstream dam water level greatly affects the displacements, excess pore pressure and displacement tendency of the underlying foundation soils and the dam.