• Analytical Science and Technology
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• v.25 no.6
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• pp.395-401
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• 2012

This study presents a method for the quantitative analysis of residual vinyl chloride monomer (VCM) in PVC products. In elution solvent, the extraction efficiency was similar by ethanol, THF, and acetone, but using n-hexane, it indicated relatively low extraction efficiency. Measuring VCM in the pulverized PVC samples, it showed reasonable results in both the direct injection method and headspace method with GC/MS. Regarding analysis of VCM in the intermediate sponge samples, five laboratories showed good results, and from the results, it was considered that VCM quantitative method in this study was reliable.

• Elastomers and Composites
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• v.54 no.4
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• pp.294-298
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• 2019

A three-layered PVC sheet consisting of polyvinyl chloride (PVC) and woven polyester fabric was prepared by extrusion and calendering. The flexibility and durability of the PVC were tuned by adding plasticizers, additives, and surface coatings. The tensile and tear strengths of the three-layered PVC sheet were higher than those of commercial two-layered sheet, while exhibiting low weight. The concentrations of the total volatile organic compounds (TVOCs) and formaldehyde (HCHO) emitted from the sheet were also lowered. The PVC sheet remained stable after prolonged exposure to UV light, signifying that the PVC sheet is suitable for cargo screen applications.

• The Journal of the Acoustical Society of Korea
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• v.29 no.3E
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• pp.140-145
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• 2010

In the present study, tubular polyvinyl chloride (PVC) cortical bone mimics that simulate the cortical shell of long bones were used to validate the axial transmission technique for assessing the cortical thickness by measuring the ultrasonic velocities along the cortical shell of long bones. The ultrasonic velocities in the 9 PVC cortical bone mimics with wall thicknesses from 4.0 to 16.1 mm and inner diameters from 40 to 300 mm were measured as a function of the thickness by using a pair of custom-made transducers with a diameter of 12.7 mm and a center frequency of 200 kHz. In order to clarify the measured behavior, they were also compared with the predictions from a theory of guided waves in thin plates. This phantom study using the PVC cortical bone mimics provides useful insight into the dependencies of ultrasonic velocities on the cortical thickness in human long bones.

• YAKHAK HOEJI
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• v.33 no.4
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• pp.211-218
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• 1989

Twenty-six injectable drug products, many of which are administered by i.v. infusion, were studied for loss from aqueous solutions stored in polyvinyl chloride (PVC) infusion bags for various periods of time. The PVC infusion bags were stored in the dark room at room temperature for up to one month. Drugs stored in glass bottle served as controls. The solutions were assayed Spectrophotometrically at regular intervals. The effect of drug concentration and pH on the loss of drug from solution were studied. Octanol-water partition coefficients were used as a guage of lipid solubility of drugs. The elution of di(2-ethylhexyl)phthalate(DEHT) from PVC infusion bags was studied. For most of the drug studied, minimal loss from the aqueous solutions were observed over periods of storage time. Six of the drug products - Thiopental sodium, Hydralazine HCl, Thioridazine HCl, Trifluoperazine 2HCl, Metronidazole, Chlorpromazine HCl - were found to be lost a substantial extent. DEHP was found to be migrating from PVC infusion bags.

• Journal of Industrial and Engineering Chemistry
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• v.67
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• pp.358-364
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• 2018

An isotropic pitch precursor for fabricating carbon fibres was prepared by co-carbonization of ethylene bottom oil(EBO) and polyvinyl chloride (PVC). Various pre-treatments of EBO and PVC, and a high heating rate of $3^{\circ}C/min$ with no holding time, were evaluated for their effects on the oxidative stabilization process and the mechanical stability of the resulting fibres. Our stabilization process enhanced the volatilization, oxidative reaction and decomposition properties of the precursor pitch, while the addition of PVC both decreased the onset time and accelerated the oxidative reaction. Aliphatic carbon groups played a critical role in stabilization. Microstructural characterization indicated that these were first oxidised to carbon-oxygen single bonds and then converted to carbon-oxygen double bonds. Due to the higher heating rate and lack of a holding step during processing,the resulting thermoplastic fibers did not completely convert to thermoset materials, allowing partially melted, adjacent fibres to fuse. Fiber surfaces were smooth and homogeneous. Of the various methods evaluated herein, carbon fibers derived from pressure-treated EBO and PVC exhibited the highest tensile strength. This work shows that enhancing the naphthenic component of a pitch precursor through the co-carbonization of pre-treated EBO with PVC improves the oxidative properties of the resulting carbon fibers.

• 수도
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• s.60
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• pp.36-42
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• 1993

• Advances in nano research
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• v.15 no.3
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• pp.253-261
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• 2023

This study investigates the application of nano-composite materials in physical education, specifically focusing on improving the performance of sports hall flooring. The research centers on carbon nanotube reinforced polyvinyl chloride (PVC) composites, which offer enhanced mechanical properties and durability. The incorporation of carbon nanotubes as reinforcements in the PVC matrix provides notable benefits, including increased strength, improved thermal stability, electrical conductivity, and resistance to fatigue. The key parameters examined in this study are the weight percentage of carbon nanotubes and the temperature during the fabrication process. Through careful analysis, it is found that higher weight percentages of carbon nanotubes contribute to a more uniform dispersion within the PVC matrix, resulting in improved mechanical properties. Additionally, higher fabrication temperatures aid in repairing macroscopic defects, leading to enhanced overall performance. The findings of this study indicate that the utilization of carbon nanotube reinforced PVC composites can significantly enhance the strength and durability of sports hall flooring. By employing these advanced materials, the safety and suitability of physical education environments can be greatly improved. Furthermore, the insights gained from this research can contribute to the optimization of composite material design and fabrication techniques, not only in the field of physical education but also in various industries where composite materials find applications.

• Nuclear Engineering and Technology
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• v.56 no.10
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• pp.4097-4102
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• 2024

A dosimetry system's ability to monitor absorbed doses is crucial for the quality assurance and control of products that have been exposed to radiation. Here, we propose a polyvinyl chloride (PVC)-methyl yellow (MY) film as a potential dosimeter for irradiation facilities. The PVC-MY film was prepared with a simple solvent-casting method at different MY concentrations from 0.3 to 1.2 mM. To evaluate the dosimeter's performance, the film was exposed to gamma-irradiation with irradiation doses of 0-25 kGy. The optical characteristics of the films examined using a UV-Vis spectrophotometer showed that the color of the films changed from yellow to red with increasing irradiation doses, and the color change sensitivity of the films increased with increasing MY concentrations. The absorption spectra of the irradiated PVC-MY films showed three maximum absorption peaks at 417, 522, and 547 nm. As irradiation doses increased, the film absorption at 417 nm decreased, while the film absorption at 522 and 547 nm increased. The film's stability studies suggest storage of the irradiated film in a cold-dark conditions is recommended to prevent damage and maintain response stability. The findings in this study emphasize the potential of the PVC-MY film as a dosimeter for irradiation facilities.

• Resources Recycling
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• v.25 no.3
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• pp.74-81
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• 2016

Study on chlorination of ilmenite ore were carried out by using PVC(polyvinyl chloride) as the chlorinating agent in a static bed reactor for selective removal of iron. The effect of amount of PVC and reaction temperature were investigated. It was found that the removal ratio of iron increased with amount of PVC and temperature. After reaction with HCl gas generated from PVC, porous surface of the specimens were observed. As a result, HCl gas could react with iron in the central portion of ilmenite particle through these pores. Examination of data using kinetic model suggest that the selective chlorination rate is controlled by chemical reaction at the interface of particles. The activation energy for the selective chlorination of ilmenite using PVC was calculated as 20.47 kJ/mol.

• Journal of Environmental Science International
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• v.14 no.10
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• pp.919-928
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• 2005

This study introduces the development of new supercritical water oxidation(SCW)(multiple step oxidation) to destruct recalcitrant organic substances totally and safely by using sodium nitrate as an oxidant. This method has solved the problems of conventional SCW, such as precipitation of salt due to lowered permittivity, pressure increase following rapid rise of reaction temperature, and corrosion of reactor due to the generation of strong acid. Destruction condition and rate in the supercritical water were examined using Polyvinyl Chloride(PVC) and ion exchange resins as organic substances. The experiment was carried out at $450^{\circ}C$ for 30min, which is relatively lower than the temperature for supercritical water oxidation $(600-650^{\circ}C)$. The decomposition rates of various incombustible organic substances were very high [PVC$(87.5\%)$, Anion exchange resin$(98.6\%)$, Cationexchange resin$(98.0\%)$]. It was observed that hetero atoms existed in organic compounds and chlorine was neutralized by sodium (salt formation). However, relatively large amount of sodium nitrate (4 equivalent) was required to raise the decomposition ratio. For complete oxidation of PCB was intended, the amount of oxidizer was an important parameter.