• 소음진동
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• 제7권3호
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• pp.411-418
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• 1997

A method to analyze the axisymmetric vibration and the internal pressure of the fluid filled, strength member embedded infinite cylindrical shell under the condition of axial static tension load applied is presented. As an example, the hose wall vibration and the internal pressure variation characteristics of a fluid filled infinite polyurethane hose are analyzed and dicussed, under the effects of the variation of the embedded strength members and the response positions.

• 한국의류산업학회지
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• 제11권2호
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• pp.359-362
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• 2009

This study investigates the behavior of water vapor permeability of a layered system to find out a comfortable combination of a layered system for outdoor activities and examines the water vapor permeability of various types of outdoor clothing fabrics. The layered system includes the base layer such as sportswool and polyester/cotton fabrics, the middle layer such as single and double sided fleece fabrics, and the shell layer such as polyurethane-coated, PTFE-laminated and microfiber fabrics in this experiment. Results show that the layered system was applied, it was working together as a whole having some influence on each other layer, though every layer offered varying degree of water vapor permeability. Water vapor permeability of layered system exactly followed the same trend as the shell layer, which is all vapor permeable water repellent fabrics as a single layer. The rate of water vapor transfer through a layered system is mainly related to the type of vapor permeable water repellent fabrics used for the shell layer.

• 한국염색가공학회지
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• 제15권3호
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• pp.66-66
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• 2003

야외 운동(outdoor activities)복에 사용되는 소재들은 외부로부터 신체를 안전하게 보호해 주어야 될 뿐 아니라 쾌적하게 유지시켜 주어야 한다. 의복착용시 쾌적감에 결정적인 영향을 미치는 인자는 몸의 열적 평형상태를 유지하기 위한 수단인 수분전달 특성이다. 본 연구는 여러 종류의 야외 운동복용 직물에서의 수분전달 현상을 조사하여 규명하므로써 이 직물들이 실제 의복생활에 응용될 의복계 (clothing system)를 형성하였을 때의 수분전달 현상을 설명하고자 하는 기초연구이다. 연구의 결과는 base layer용, mid layer용 직물들이 shell layer로 쓰이는 waterproof breathable 직물보다 수분 전달률이 높았으며, waterproof breathable 직물의 수분 전달률은 microfibre 직물, PTFE-laminated 직물 그리고 polyurethane coated 직물 순 이었다. 또한 polyurethane 직물에서는 back coated 직물이 face-coated 직물보다 수분 전달률이 높았다.

• 한국염색가공학회지
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• 제15권3호
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• pp.192-196
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• 2003

야외 운동(outdoor activities)복에 사용되는 소재들은 외부로부터 신체를 안전하게 보호해 주어야 될 뿐 아니라 쾌적하게 유지시켜 주어야 한다. 의복착용시 쾌적감에 결정적인 영향을 미치는 인자는 몸의 열적 평형상태를 유지하기 위한 수단인 수분전달 특성이다. 본 연구는 여러 종류의 야외 운동복용 직물에서의 수분전달 현상을 조사하여 규명하므로써 이 직물들이 실제 의복생활에 응용될 의복계(clothing system)를 형성하였을 때의 수분전달 현상을 설명하고자 하는 기초연구이다. 연구의 결과는 base layer용, mid layer용 직물들이 shell layer로 쓰이는 waterproof breathable 직물보다 수분 전달률이 높았으며, waterproof breathable 직물의 수분 전달률은 microfibre 직물, PTFE-laminated 직물 그리고 polyurethane coated 직물 순 이었다. 또한 polyurethane 직물에서는 back coated 직물이 face-coated 직물보다 수분 전달률이 높았다.

• 접착 및 계면
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• 제15권3호
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• pp.109-115
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• 2014

본 연구에서는 내부에 이소시아네이트를 포함하는 microcapsule을 합성하였으며, 제조된 microcapsule에 대한 분석 및 폴리우레탄 수지와 병용했을 때의 기계적 물성과 접착특성에 대해서 고찰하였다. 전자현미경을 사용해서 합성된 microcapsule이 구형의 외관을 갖는 것을 확인하였으며, FT-IR과 TGA 분석을 통해서 microcapsule의 core 물질이 IPDI인 것과 각 구성요소들의 성분비를 확인하였다. 폴리우레탄 수지 자체 및 microcapsule을 포함한 경우의 접착력 및 물성을 평가한 결과 접착수지 내에 포함된 microcapsule 내 IPDI의 가교반응에 의해서 폴리우레탄 수지 자체에 비해 접착력, 인장강도, 내마모 특성이 크게 향상되는 것을 확인하였다.

• Macromolecular Research
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• 제14권4호
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• pp.466-472
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• 2006

The kinetic behavior of emulsion polymerizations of styrene in the presence of sulfonated N-hydroxy ethyl aniline (SHEA) was investigated with two initiators: 2,2'-azobisisobutyronitrile (AIBN) and potassium persulfate (KPS). SHEA was synthesized using a stepwise polyurethane reaction method from 3-hydroxy-1-propane sulfonic acid sodium salt, isophorone diisocyanate (IPDI), and N-(2-hydroxyethyl) aniline. Stable core-shell poly(styrene/sulfonated N-hydroxy ethyl aniline, St/SHEA) latex particles were successfully prepared by using an appropriate amount of AIBN, in which SHEA plays the role of 'surfmer', i.e., acting as both a surfactant in the emulsion polymerization and a monomer in the chemical oxidative polymerization. The kinetic behavior was dissimilar to that of typical emulsion polymerization systems. A long inhibition period and low rate of polymerization were observed due to radical loss by the oxidative polymerization of SHEA. It was concluded, due to the low water-solubility of AIBN and retardation reaction by SHEA, that the initial loci of polymerization were monomer droplets. However, growing polymer particles as polymerization loci became predominant as polymerization proceeded. It was suggested that AIBN was more effective than KPS in the preparation of the core-shell type poly(St/SHEA) latex particles. With KPS, no substantial polymerization was observed in any of the samples.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.393-398
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• 2018

This work offers a promising approach for development of a temperature-responsive colorimetric display platform. For this purpose, uniform thermochromic microcapsules consisting of a cholesteric liquid crystal (CLC) core and a thin polyurethane shell layer were fabricated by conducting in-situ condensation polymerization at the interface of monodisperse CLC-in-water emulsion drops. Colloidal packing-driven microcapsule registry led to exact 2-dimensional positioning of CLC microcapsules into a holes-patterned flexible film stencil. Furthermore, we showed that the designated registry of different color types of CLC microcapsules on the stencil enabled development of a microwriting display technology capable of reversible text representation according to temperature change.

• 플랜트 저널
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• 제10권4호
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• pp.35-41
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• 2014

축열조는 집단에너지를 공급하는 지역의 고도와 열부하에 따라 높이와 용량이 결정된다. 이는 축열조의 수두를 이용하여 열배관망에 압력을 가하고 배관망내의 비등을 방지하며 온도변화에 따라 체적이 팽창하면 이를 흡수하고 수축 시에는 부족한 중온수를 배관망에 공급하는 기능을 해야 하기 때문이다. 또한, 축열조의 역할은 주로 열수요량의 변화가 심한 계절별 주간 야간 시간대에 적절한 용량을 갖추고 잉여 열량을 저장한 후 필요한 시간대에 지역난방 열원으로 이용하면 열생산 설비의 운전 조건에 영향을 받지 않으면서 독자적으로 지역난방 열수요를 공급할 수 있는 장점이 있다. 본 연구는 지역난방에 건설되어 운영 중인 축열조 27기 중 폴리우레탄 폼의 단열 재료로 시공된 18기의 축열조에 대하여 단열재의 재질과 축열조의 운전방법에 따른 단열재의 손상원인에 대한 고찰과 단열재 손상이 축열조 부식에 어떠한 영향을 미치는지 고찰하였다.

• Fibers and Polymers
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• 제7권1호
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• pp.12-19
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• 2006

For thermal adaptable fabrics, the polyurethane-urea microcapsules containing phase-change materials (PCMs: hexadecane, octadecane and eicosane) were successfully synthesized by interfacial polycondensation using 2,4-toluene diisocyanate (TDI)/poly(ethylene glycol) (PEG400)/ethylene diamine (EDA) as shell monomers and nonionic surfactant NP-12 in an emulsion system under stirring rates of $3,000{\sim}13,000$ rpm. The mean particle size of microcapsule decreased significantly with increasing the stirring rate up to 11,000 rpm, and then leveled off. The mean particle size increased with increasing the content and molecular weight (eicosane > octadecane > hexadecane) of PCMs at the same stirring rate. The mean particle sizes of microcapsules were found to decrease with increasing the NP-12 content up to 1.5 wt%, and thereafter increased a little. It was found that the melting temperature ($T_m$) and crystallization temperature ($T_c$) of three kinds of encapsulated PCMs and their enthalpy changes (${\Delta}H_m,{\Delta}H_c$) increased with increasing PCM contents. The encapsulation efficiencies (Ee) of hexadecane microcapsule linearly increased with increasing the content of hexadecane. It was found that the stable microcapsule containing 50 wt% of hexadecane could be obtained in this study. However, Ee of octadecane and eicosane microcapsules increased with increasing PCM's contents up to 40 wt%, and then decreased a little. By considering the encapsulation efficiency, it was found that the maximum/optimum contents of octadecane and eicosane microcapsules were about 40 wt%. By the dynamic thermal performance test, it was found that the maximum buffering levels of Nylon fabrics coated with hexadecane, octadecane, and eicosane microcapsules were about $-2.4/+2.9^{\circ}C,\;-3.6/+3.6^{\circ}C\;and\;-4.0/+4.7^{\circ}C$, respectively.

• 한국염색가공학회지
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• 제34권4호
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• pp.250-260
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• 2022

In this research, a high-elasticity acrylic emulsion binder with core-shell polymerization and self-crosslinking system is mixed with a flame-retardant water-dispersed polyurethane (PUD) binder. In addition, finite element analysis was conducted through virtual engineering software ANSYS by applying three representative nonlinear material models. The most suitable nonlinear material model was selected after the relative comparison between the actual experimental values and the predicted values of the properties derived from simulations. The selected nonlinear material model is intended to be used as a nonlinear material model for computational simulation analysis that simulates the experimental environment of the vibration test (ASTM E1399) and the actual fire safety test (ASTM E1966). When the mass fraction of thermally expandable graphite was 0.7%, the thermal and physical properties were the best. Among the nonlinear material models, the simulation result of the Ogden model showed the closest value to the actual result.