• Smart Structures and Systems
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• v.30 no.2
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• pp.135-143
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• 2022

The object of this paper is to investigate the free vibration behavior under the effect of carbon nanotube distribution in functionally graded carbon nanotube-reinforced composite (FG-CNTRC) by using higher-order shear deformation theories. In this work, we present a novel distribution method for carbon nanotubes in the polymer matrix by using a new exponential power law distribution of carbon nanotube volume fraction. It is assumed that the SWCNTs are aligned along the beam axial direction and the distribution of the SWCNTs may vary through the thickness of the beam with different patterns of reinforcement. The rule of mixtures is used in order to obtain material properties of the CNTRC beams. Hamilton's principle is used in deriving the equations of motion. The validity of the free Vibration results is examined by comparing them with those of the known data in the literature. The results that obtained indicate that the carbon nanotube volume fraction distribution play a very important role on the free vibrations characteristics of the CNTRC beam.

• Steel and Composite Structures
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• v.25 no.3
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• pp.315-326
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• 2017

In this work, thermoelastic dynamic behavior of functionally graded carbon nanotube reinforced composite (FG-CNTRC) cylinders subjected to mechanical pressure loads, uniform temperature environment or thermal gradient loads is investigated by a mesh-free method. The material properties and thermal stress wave propagation of the nanocomposite cylinders are derived after solving of the transient thermal equation and obtaining of the time history of temperature field of the cylinders. The nanocomposite cylinders are made of a polymer matrix and wavy single-walled carbon nanotubes (SWCNTs). The volume fraction of carbon nanotubes (CNTs) are assumed variable along the radial direction of the axisymmetric cylinder. Also, material properties of the polymer and CNT are assumed temperature-dependent and mechanical properties of the nanocomposite are estimated by a micro mechanical model in volume fraction form. In the mesh-free analysis, moving least squares shape functions are used to approximate temperature and displacement fields in the weak form of motion equation and transient thermal equation, respectively. Also, transformation method is used to impose their essential boundary conditions. Effects of waviness, volume fraction and distribution pattern of CNT, temperature of environment and direction of thermal gradient loads are investigated on the thermoelastic dynamic behavior of FG-CNTRC cylinders.

• Structural Engineering and Mechanics
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• v.67 no.4
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• pp.403-415
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• 2018

In the present study, nonlinear dynamic response of polymer-CNT-fiber multiscale nanocomposite plate resting on elastic foundations in thermal environments using the finite element method is performed. In this regard, the governing equations are derived based on Inverse Hyperbolic Shear Deformation Theory and von $K{\acute{a}}rm{\acute{a}}n$ geometrical nonlinearity. Three type of distribution of temperature through the thickness of the plate namely, uniform linear and nonlinear are considered. The considered element is C1-continuous with 15 DOF at each node. The effective material properties of the multiscale composite are calculated using Halpin-Tsai equations and fiber micromechanics in hierarchy. The carbon nanotubes are assumed to be uniformly distributed and randomly oriented through the epoxy resin matrix. Five types of impulsive loads are considered, namely the step, sudden, triangular, half-sine and exponential pulses. After examining the validity of the present work, the effects of the weight percentage of SWCNTs and MWCNTs, nanotube aspect ratio, volume fraction of fibers, plate aspect, temperature, elastic foundation parameters, distribution of temperature and shape of impulsive load on nonlinear dynamic response of CNT reinforced multi-phase laminated composite plate are studied in details.

• Elastomers and Composites
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• v.46 no.2
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• pp.125-131
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• 2011

The effects of chopped kenaf fiber concentration on mechanical property of polypropylene (PP) composite are investigated. The addition of kenaf increased the tensile strength, flexural modulus, impact strength, specific gravity, and HDT, while decreased the elongation%, flexural strength, and melt flow index. The increase of mechanical properties is due to increased surface area contacting between fiber and polymer matrix and fiber-fiber interaction. Volatile extractives in the kenaf seemed to decrease the interfacial adhesion between kenaf surface and PP.

• Macromolecular Research
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• v.15 no.4
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• pp.343-347
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• 2007

Novel composite membranes, which delivered high separation performance for propylene/propane mixtures, were developed by coating inert poly(ethylene-co-propylene) rubber (EPR) onto a porous polyester substrate, followed by the physical distribution of $AgBF_4$. Scanning electron microscopy-wavelength dispersive spectrometer (SEM-WDS) revealed that silver salts were uniformly distributed in the EPR layer. The physical dispersion of the silver salts in the inert polymer matrix, without specific interaction, was characterized by FT-IR and FT-Raman spectroscopy. The high separation performance was presumed to stem from the in-situ dissolution of crystalline silver ionic aggregates into free silver ions, which acted as an active propylene carrier within a propylene environment, leading to facilitated propylene transport through the membranes. The membranes were functional at all silver loading levels, exhibiting an unusually low threshold carrier concentration (less than 0.06 of silver weight fraction). The separation properties of these membranes, i.e. the mixed gas selectivity of propylene/propane ${\sim}55$ and mixed gas permeance ${\sim}7$ GPU, were stable for several days.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.11a
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• pp.28-31
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• 1999

Carbon fiber/epoxy composites using electrodeposited monomeric and polymeric coupling agents were compared with the dipping and the untreated cases. Treating conditions such as time, concentration and temperature were optimized. Four-fibers embedded micro-composites were prepared for fragmentation test. Interfacial properties of four-fiber composites with different surface treatments were investigated with simultaneous acoustic emission (AE) monitoring. The microfailure mechanisms occurring from fiber break, matrix and interlayer crackings were examined by AE parameters and an optical microscope. It was found that interfacial shear strength (IFSS) of electrodeposited carbon fibers was much higher than the other cases under dry and wet conditions. Well separated and different-shaped AE groups occurs for the untreated and ED treated case, respectively.

• Polymer(Korea)
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• v.24 no.5
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• pp.690-700
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• 2000

In this study, an elastomer-assistered compression molding process was investigated by experiments as well as modeling for the long-fiber reinforced thermoset composites. The consolidation pressure generated by fixed-volume and variable-volume conditions was thermodynamically derived for both elastomer and curing prepregs, and was compared with the pressure measured during curing of epoxy matrix. Exhibiting non-linear viscoelastic characteristics in the compressive stress-strain tests, the measured stress was well compared with a modifed KWW (Kohlrausch-Williame-Watts) equation, which is based on the Maxwell viscoelastic model. Using the developed model equations, the consolidation pressure generated by the elastomer was successfully predicted for the compression molding process of thermoset composite materials in tile closed mold system.

• Korean Membrane Journal
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• v.10 no.1
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• pp.20-25
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• 2008

Proton conducting composite membranes were prepared by solution blending of poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-poly(sulfopropyl methacrylate) (P(VDF-CTFE)-g-PSPMA) graft copolymer and heteropolyacid (HPA). The P(VDF-CTFE)-g-PSPMA graft copolymer was synthesized by atom transfer radical polymerization (ATRP) using direct initiation of the secondary chlorines of P(VDF-CTFE). FT-IR spectroscopy revealed that HPA nanoparticles were incorporated into the graft copolymer via hydrogen bonding interactions. The water uptake of membranes continuously decreased with increasing HP A concentration up to 45wt%, after which it slightly increased. It is presumably due to the decrease in number of water absorption sites due to hydrogen bonding interaction between the HP A particles and the polymer matrix. The proton conductivity of membranes increased with increasing HPA concentration up to 45wt%, resulting from both the intrinsic conductivity of HP A particles and the enhanced acidity of the sulfonic acid of the graft copolymer.

• Composites Research
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• v.18 no.3
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• pp.1-6
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• 2005

Carbon nanofiber exhibits superior and of ien unique characteristics of mechanical, electrical, chemical and thermal properties. Despite of the excellent properties of carbon nanofiber, the properties of carbon nanofiber filled polymer composites were not increased largely. The reason is that it is still difficult to ensure the uniform dispersion of carbon nanofiber in a polymer matrix. In this study, for improvement of the mechanical properties of composites, carbon nanofiber reinforced hybrid composites was investigated. For the dispersion of carbon nanofiber. solution blending method using ultrasonic was used. Dispersion of carbon nanoifiber was observed by scanning electron microscope (SEH). Mechanical properties were measured by universal testing machine(UTM).

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.26 no.11
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• pp.790-800
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• 2013

The optimal structure of 1-3 piezocomposites has been determined by controlling polymer properties, ceramic volume fraction, thickness of composite and aspect ratio of the composite to maximize the TVR (transmitting voltage response), RVS (receiving voltage sensitivity) and FBW (fractional bandwidth) of underwater acoustic transducers. Influence of the design variables on the transducer performance was analyzed with equivalent circuits and the finite element method. When the piezocomposite is vibrating in a pure thickness mode, inter-pillar resonant modes are likely to occur between lattice-structured piezoceramic pillars and polymer matrix, which significantly deteriorate the performance of the piezocomposite. In this work, a new method to design the structure of the 1~3 type piezocomposite was proposed to maximize the TVR, RVS and FBW while preventing the occurrence of the inter-pillar modes. Genetic algorithm was used in the optimal design.