• Title/Summary/Keyword: polymer flooding

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An Analysis on Applicability of Geophysical Exploration Methods to Monitoring Polymer-flooding (물리탐사 기법들의 화학공법 모니터링 적용성 분석)

  • Cheon, Seiwook;Park, Chanho;Ku, Bonjin;Nam, Myung Jin;Son, Jeong-Sul
    • Geophysics and Geophysical Exploration
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    • v.18 no.3
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    • pp.143-153
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    • 2015
  • Polymer flooding for enhancing hydrocarbon production injects into a reservoir polymer solution that is viscous. It is very important to monitor the behavior pattern of the polymer solution in order to evaluate the effectiveness of polymer flooding. To monitor the distribution of polymer solution and thus fluid substitution within the reservoir, we first construct seismic and resistivity rock physics models (RPMs), which are functions of reservoir parameters such as rocks and type of fluid, fluid saturation. For the seismic and resistivity RPMs, responses of seismic and electromagnetic (EM) tomography are numerically simulated as polymer injection, using two dimensional (2D) staggered-grid finite difference elastic modeling and 2.5D finite element EM modeling algorithms, respectively. In constructing RPM for EM tomography, three different reservoir rocks are considered: clean-sand, dispersed shale-sand, and sand-shale lamination rocks. The polymer solution is assumed to have 2 wt% of polymer as normally generated, while water is freshwater or saltwater. Further, neutron logging is also considered to check its sensitivity to polymer flooding. The techniques discussed in the paper are important in monitoring not only hydrocarbon but also geothermal reservoirs.

Investigation of Water Droplet Behaviour on GDL Surface and in the Air Flow Channel of a PEM Fuel Cell under Flooding Conditions (플러딩 조건 하에서의 고분자전해질형 연료전지 GDL 표면과 공기극 유로 채널에서의 물방울 유동 특성 고찰)

  • kim, Hansang;Min, Kyoungdoug
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.476-483
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    • 2012
  • Proper water management is crucial for the efficient operation of polymer electrolyte membrane (PEM) fuel cell. Especially, for automotive applications, A novel water management that can avoid both membrane dry-out and flooding is a very important task to achieve good performance and efficiency of PEM fuel cells. The aim of this study is to investigate the liquid water behavior on the gas diffusion layer (GDL) surface and in the cathode flow channel of a PEM unit fuel cell under flooding conditions. For this purpose, a transparent unit fuel cell is devised and fabricated by modifying the conventional PEM fuel cell design. The results of water droplet behavior under flooding conditions are mainly presented. The water distributions in the cathode flow channels with cell operating voltage are also compared and analyzed. Through this work, it is expected that the data obtained from this fundamental study can be effectively used to establish the basic water management strategy in terms of water removal from the flow channels in a PEM fuel cell stack.

Mathematical model and sensitivity analysis for describing emulsification in ASP flooding

  • Zhang, Chengli;Wang, Peng;Song, Guoliang
    • Geosystem Engineering
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    • v.21 no.6
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    • pp.335-343
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    • 2018
  • Alkali-surfactant polymer flooding has become an important technique to improve oil recovery following the development of oil fields while the function of emulsification in enhanced oil recovery is rarely considered in the existing mathematical model for numerical simulation. In this paper, the mechanism of improving the recovery of the emulsification was analyzed in ASP flooding, and a relatively perfect mathematical model with deep filtration-theory was established, in which oil-water volume equation, saturation equation, viscosity equation, and permeability reduction equation are included. The new model is used to simulate the actual block of an oil field; the simulated results of the new model and an old model without considering the emulsification are compared with the actual well history. It is found that new model which is easy to be realized in numerical simulation has a high precision fitting, and the effect of adding oil and decreasing water is obvious. The sensitivity of emulsification was analyzed, and the results show that the water reducing funnel becomes wider and the rate of water cut decreases rapidly with the increase of emulsifying capacity, and then the rate of recovery slows down. The effect of increasing oil and decreasing water is better, and the degree of recovery increases. The emulsification of the ASP flooding is maintained at a moderate level, which corresponds to ${\Phi}=0.2$ in the new model, and the emulsification is applied to realize the general mathematical quantitative description, so as to better guide the oilfield development.

The Analysis for the Effect of Effective Compressibility on Oil Recovery in Polymer Flooded Heterogeneous Reservoir (폴리머 공법 적용 불균질 저류층에서의 유효 압축률이 오일생산에 미치는 영향 분석)

  • Baek, Soohyun;Jung, Woodong;Sung, Wonmo;Seo, Junwoo
    • Economic and Environmental Geology
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    • v.47 no.3
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    • pp.247-254
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    • 2014
  • The compressibility of fracture in naturally fractured reservoir is larger than the compressibility of matrix in rock, although the compressibility of a typical rock is very small. The effective compressibility including the fracture compressibility should be considered to predict oil recovery correctly. It is hard to quantify changes of fracture aperture and pore volume in reservoir without the effective compressibility. In this study, oil recovery is analyzed by commercial simulator concerning the fracture compressibility based on fracture properties. We found that the effective compressibility affects oil recovery with change of polymer flooding factors such as polymer molar weight, concentration and injection rate. The estimated cumulative oil production is smaller with the effective compressibility than without it. Also, bottomhole pressure decreases rapidly without considering effective fracture compressibility.

Strength properties of concrete permeability blocks using polymer PVA (폴리머 PVA 사용에 따른 콘크리트 투수블록의 강도 특성)

  • Lee, Won-Gyu;Pyeon, Su-Jeong;Yoo, Byeong-Yong;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.29-30
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    • 2018
  • Recent impervious pavements on roads and sidewalks cause rainwater to not penetrate into the ground, deplete groundwater, or flood the rivers, causing urban flood damage. In order to solve these problems, the amount of installed pitcher block is increasing, but the existing pitcher block is made with cement base and causes many problems. In the cement permeable block, the efflorescene phenomenon occurs due to the acid component, and the pore of the permeable block is clogged and the permeability is lost. As a result, the service life of the pitcher block is shortened and the replacement period is shortened. The purpose of this study is to analyze the basic properties of polymer concrete by replacing cement with polymer in order to solve the problem of cement - based concrete permeable block.

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Experimental Study on Rainfall Runoff Reduction Effects by Permeable Polymer Block Pavement (투수성 폴리머 블록 포장에 의한 우수 유출 저감 효과에 관한 실험적 연구)

  • Sung, Chan-Yong;Kim, Young-Ik
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.2
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    • pp.157-166
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    • 2012
  • Most of the roads are paved with impermeable materials such as asphalt concrete and cement concrete, and in the event of heavy rainfall, rainwater directly flows into river through a drainage hole on the pavement surface. This large quantity of rainwater directly spilled into the river frequently leads to the flooding of urban streams, damaging lowlands and the lower reaches of a river. In recent years there has been a great deal of ongoing research concerning water permeability and drainage in pavements. Accordingly, in this research, a porous polymer concrete was developed for permeable pavement by using unsaturated polyester resin as a binder, recycled aggregate as coarse aggregate, fly ash and blast furnace slag as filler, and its physical and mechanical properties were investigated. Also, 3 types of permeable polymer block by optimum mix design were developed and rainfall runoff reduction effects by permeability pavement using permeable polymer block were analyzed based on hydraulic experimental model. The infiltration volume, infiltration ratio, runoff initial time and runoff volume in permeability pavement with permeable polymer block of $300{\times}300{\times}80$ mm were evaluated for 50, 100 and 200mm/hr rainfall intensity.

Pore-network Study of Liquid Water Transport through Multiple Gas Diffusion Medium in PEMFCs (고분자 연료전지의 다공성층 내에서의 액상수분 이동에 관한 공극-네트워크 해석 연구)

  • Kang, Jung-Ho;Lee, Sang-Gun;Nam, Jin-Hyun;Kim, Charn-Jung
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.46-53
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    • 2011
  • Water is continuously produced in polymer electrolyte membrane fuel cell (PEMFC), and is transported and exhausted through polymer electrolyte membrane (PEM), catalyst layer (CL), microporous layer (MPL), and gas diffusion layer (GDL). The low operation temperatures of PEMFC lead to the condensation of water, and the condensed water hinders the transport of reactants in porous layers (MPL and GDL). Thus, water flooding is currently one of hot issues that should be solved to achieve higher performance of PEMFC. This research aims to study liquid water transport in porous layers of PEMFC by using pore-network model, while the microscale pore structure and hydrophilic/hydrophobic surface properties of GDL and MPL were fully considered.

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Numerical Study of Land/Channel Flow-Field Optimization in Polymer Electrolyte Fuel Cells (PEFCs) (II) - The Effects of Land/Channel Flow-Field on Temperature and Liquid Saturation Distributions - (고분자전해질형연료전지의 가스 채널 최적화를 위한 수치적 연구 (II) - 가스 채널 치수가 온도와 액체포화 분포에 미치는 영향성 -)

  • Ju, Hyun-Chul;Nam, Jin-Moo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.9
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    • pp.688-698
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    • 2009
  • Using the multi-dimensional, multi-phase, nonisothermal Polymer Electrolyte Fuel Cell (PEFC) model presented in Part I, the effects of land/channel flow-field on temperature and liquid saturation distributions inside PEFCs are investigated in Part II. The focus is placed on exploring the coupled water transport and heat transfer phenomena within the nonisothermal and two-phase zone existing in the diffusion media (DM) of PEFCs. Numerical simulations are performed varying the land and channel widths and simulation results reveal that the water profile and temperature rise inside PEFCs are considerably altered by changing the land and channel widths, which indicates that oxygen supply and heat removal from the channel to the land regions and liquid water removal from the land toward the gas channels are key factors in determining the water and temperature distributions inside PEFCs. In addition, the adverse liquid saturation gradient along the thru-plane direction is predicted near the land regions by the numerical model, which is due to the vapor-phase diffusion driven by the temperature gradient in the nonisothermal two-phase DM where water evaporates at the hotter catalyst layer, diffuses as a vapor form and then condenses on the cooler land region. Therefore, the vapor phase diffusion exacerbates DM flooding near the land region, while it alleviates DM flooding near the gas channel.

Numerical Study on Comparison of Serpentine and Parallel Flow Channel in High-temperature Proton Exchange Membrane Fuel Cells (고온형 고분자전해질형 연료전지에서의 사형 유로와 평행 유로 성능비교에 대한 수치해석적 연구)

  • AHN, SUNGHA;OH, KYEONGMIN;JU, HYUNCHUL
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.1
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    • pp.41-55
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    • 2018
  • General polymer electrolyte fuel cell (PEMFC) operates at less than $80^{\circ}C$. Therefore liquid phase water resulting from electrochemical reaction accumulates and floods the cell which in turn increases the mass transfer loss. To prevent the flooding, it is common to employ serpentine flow channel, which can efficiently export liquid phase water to the outlet. The major drawback of utilizing serpentine flow channel is the large pressure drop that happens between the inlet and outlet. On the other hand, in the high temperature polymer electrolyte fuel cell (HT-PEMFC), since the operating temperature is 130 to $180^{\circ}C$, the generated water is in the state of gas, so the flooding phenomenon is not taken into consideration. In HT-PEMFCs parallel flow channel with lower pressure drop between the inlet and outlet is employed therefore, in order to circulate hydrogen and air in the cell less pumping power is required. In this study we analyzed HT-PEMFC's different flow channels by parallel computation using previously developed 3-D isothermal model. All the flow channels had an active area of $25cm^2$. Also, we numerically compared the performance of HT-PEMFC parallel flow channel with different manifold area and Rib interval against the original serpentine flow channel. Results of the analysis are shown in the form of three-dimensional contour polarization curves, flow characteristics in the channel, current density distribution in the Membrane, overpotential distribution in the catalyst layer, and hydrogen and oxygen concentration distribution. As a result, the performance of a real area fuel cell was predicted.