• Journal of the Korean Applied Science and Technology
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• v.30 no.4
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• pp.664-671
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• 2013

Determination of xanthan gum as watersoluble-polymer in commercial cosmetic samples was carried out by High Perfomance Liquid Chromatography(HPLC). An $C_{18}$ reversed-phase column and the selected ELSD detector was applied. The 25mM ammonium acetate/acetonitrile was used for the mobile phase of gradient conditions. The analysis results of HPLC showed good linearity with correlation coefficient of $r^2=0.9993$ in the rage of $50.3{\sim}604.1{\mu}g/ml$ and detection limit of $12.0{\mu}g/ml$.

• Journal of Information Display
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• v.3 no.2
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• pp.1-5
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• 2002

A CMOS driving circuit for active matrix type polymer electroluminescent displays was designed to develop an on-chip microdisplay on the single crystal silicon wafer substrate. The driving circuit is a conventional structure that is composed of the row, column and pixel driving parts. 256 gray scales were implemented using pulse amplitude modulation method. The 2-transistor driving scheme was adopted for the pixel driving part. The layout was carried out considering the compatibility with the standard CMOS process. Judging from the layout of the driving circuit, it turns that it is possible to implement a high-resolution display about 400 ppi resolution. Through the HSPICE simulation, it was verified that this circuit is capable of driving a VGA signal mode display and implementing 256 gray levels.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.10
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• pp.694-702
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• 2013

The purpose of this study is to evaluate a de-watering filtrate treatment and the possibility of securing biological treatment capacity by changing the structure of the secondary clarifier. Accordingly, the column test was conducted to determine the effect of polymer in the de-watering filtrate on sludge sedimentation. Also, the characteristics of de-watering filtrate processing was evaluated through batch test and continuous processing operation. The results showed that sludge settling velocity increased with higher polymer concentration, and that effluent SS concentration was found to decrease. Regarding processing characteristics of de-watering filtrate, the removal efficiency of TSS and TBOD5 increased as the length of secondary clarifier was longer. Also, comparing injections into anoxic tank and secondary clarifier, de-watering filtrate by continuous infusion treatment process showed stability in both conditions. Therefore, by modifying the structure of secondary clarifier, efficient processing of de-watering filtrate is expected to be possible and processing capacity of small sewage treatment plants is considered to be improved.

• International Journal of Concrete Structures and Materials
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• v.7 no.1
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• pp.35-50
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• 2013

Rapid and effective repair methods are desired to enable quick reopening of damaged bridges after an earthquake occurs, especially for those bridges that are critical for emergency response and other essential functions. This paper presents results of tests conducted as a proof-of-concept in the effectiveness of a proposed method using externally bonded carbon fiber reinforced polymer (CFRP) composites to rapidly repair severely damaged RC columns with different damage conditions. The experimental work included five large-scale severely damaged square RC columns with the same geometry and material properties but with different damage conditions due to different loading combinations of bending, shear, and torsion in the previous tests. Over a three-day period, each column was repaired and retested under the same loading combination as the corresponding original column. Quickset repair mortar was used to replace the removed loose concrete. Without any treatment to damaged reinforcing bars, longitudinal and transverse CFRP sheets were externally bonded to the prepared surface to restore the column strength. Measured data were analyzed to investigate the performance of the repaired columns compared to the corresponding original column responses. It was concluded that the technique can be successful for severely damaged columns with damage to the concrete and transverse reinforcement. For severely damaged columns with damaged longitudinal reinforcement, the technique was found to be successful if the damaged longitudinal reinforcement is able to provide tensile resistance, or if the damage is located at a section where longitudinal CFRP strength can be developed.

• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.447-452
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• 2013

In this study we report a new method for the synthesis of a silica monolithic column bed with bimodal pores (throughpores and mesopores). The template induced synthesis method was used to direct bimodal pores simultaneously instead of the usual post base-treating method. Block polymer Pluronic F127 was chosen as a dual-function template to form hierarchically porous silica monolith with both macropores and mesopores. This is a simplification of the method of monolithic column preparation. Poly(ethylene glycol) was used as a partial substitute for F127 can effectively prevent shrinkage during the monolith aging process without losing much surface area (944 $m^2/g$ to 807 $m^2/g$). More importantly, the resultant material showed a much narrower mesopore size (centered at 6 nm) distribution than that made using only F127 as the template reagent, which helps the mass transfer process. The solvent washing method was used to remove the remaining organic template, and it was proved to be effective enough. The new synthesis method makes the fabrication of the silica monolithic column (especially capillary column) much easier. All the structure parameters indicate that monolith PFA05 prepared by the above method is a good material for separation, with the merits of much higher surface area than usual commercial HPLC silica particles, suitable mesopore volume, narrow mesopore size distribution, low shrinkage and it is easily prepared.

• Polymer(Korea)
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• v.26 no.5
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• pp.551-558
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• 2002

It was observed that adsorption characteristics of sulfonated fabric ion-exchanger for separating nickel ion from electroplating rinse water. Swelling ratio was increased by increasing degree of sulfonation and polarity of solvent. Ion-exchange capacity was also increased by increasing degree of sulfonation and showed 3.38 meq/g at 16% sulfonated ion-exchanger. There was little effects of pH. Adsorption equilibrium was attained within 10 min, and adsorption rate was 7.5 mg/min. Adsorption capacity was not changed after 7 cycles of regeneration process. Regeneration adsorption capacity was slightly decreased to 2.01 meq/g. It confirmed that durability of sulfonated fabric ion-exchanger was suitable for adsorption process. Adsorption equilibrium time was linearly increased by increasing L/D and adsorption capacity showed the ion exchange capacity within the range of 2.71 ∼ 3.01 meq/g in continuous process. Design of adsorption column could be possible for L/D<2. Under constant L/D condition, there is no little pH effect when rinse water is acidic solution, and operation condition of adsorption process was optimized under pH 5.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.2
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• pp.151-159
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• 2015

In this study, experimental research was carried out to evaluate and improve the seismic performance of reinforced concrete beam-column joint regions using strengthening materials (CFRP sheet, AFRP sheet, embedded CFRP rod) in existing reinforced concrete structure. Therefore it was constructed and tested seven specimens retrofitting the beam-column joint regions using such retrofitting materials. Specimens, designed by retrofitting the beam-column joint regions of existing reinforced concrete structure, were showed the stable failure mode and increase of load-carrying capacity due to the effect of crack control at the times of initial loading and confinement of retrofitting materials during testing. Specimens LBCJ-CRUS, designed by the retrofitting of CFRP Rod and CFRP Sheet in reinforecd beam-column joint regions were increased its maximum load carrying capacity by 1.54 times and its energy dissipation capacity by 2.36 times in comparison with standard specimen LBCJ for a displacement ductility of 4 and 7. And Specimens LBCJ-CS, LBCJ-AF series were increased its energy dissipation capacity each by 2.04~2.34, 1.63~3.02 times in comparison with standard specimen LBCJ for a displacement ductility of 7.

• International Journal of Highway Engineering
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• v.4 no.4 s.14
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• pp.23-39
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• 2002

This study dealt with developing a new approach for finding properties which might represent rut resistance characteristics of asphalt mixture under static loading. Two aggregates, a normal asphalt (pen 60-80) and 5 polymer-modified asphalts were used in preparation of 12 dense-graded mixtures. Marshall mix design was used in determination of OAC and each mixture at the OAC was prepared for a newly-developed Kim test on Marshall specimen (S=10cm) and gyratory specimen (S=15cm), and for wheel tracking test. Kim test used Marshall loading frame and specimens were conditioned for 30min at $60^{\circ}C$ before loading through Kim tester an apparatus consisting of a loading column and a specimen and column holder Diameter (D) of column was 3cm and 4cm with each column having different radius (r) of round cut at the bottom. The static load was applied at 50mm/min in axial direction of the specimen, not in diametral direction. The maximum load ($P_{max}$) and vertical deformation (y) at $P_{max}$ point were obtained from the test. A strength value was calculated based on the $P_{max}$ r, D and y by using the equation $K_D = 4P_{max}/{\pi}(D-2(r-\sqrt{2ry-y^2}))^2$ and is defined as the deformation strength ($kgf/cm^2$). The values of $P_{max}$/y and $K_I=K_D/y$ were also calculated. In general the leading column diameter and radius of round cut were significant factors affecting $K_D$ and $P_{max}$ values while specimen diameter was not. The statistical analyses showed the $K_D$ had the best correlation with rut depth and dynamic stability. The next best correlation was found from $P_{max}$ which was followed by $P_{max}$/y and $K_I$ in order.

• Bulletin of the Korean Chemical Society
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• v.29 no.6
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• pp.1173-1178
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• 2008

A simple and sensitive high-performance liquid chromatographic method was developed for the simultaneous identification of enrofloxacin and its active metabolite ciprofloxacin in chicken muscle. Norflorxacin imprinted polymers synthesized in water-containing systems show high selectivity to enrofloxacin and ciprofloxacin in an aqueous environment. Using these water-compatible imprinted polymers as selective adsorbents in the solid-phase extraction of enrofloxacin and ciprofloxacin from chicken samples, the remaining biological matrix could be quickly washed out from the imprinted column while enrofloxacin and ciprofloxacin were selectively retained and enriched. Analytical separation was performed on a $C_{18}$ column using acetonitrile-water as a mobile phase and fluorescence detection. Good linearity was obtained from 0.8 to 500 ng/g (r > 0.998) with relative standard deviation of less than 3.9%. The mean recoveries of enrofloxacin and ciprofloxacin from chicken muscle were 80.6-94.5% and 77.8-91.8% at three different concentrations. The limits of determinations based on S/N=3 were 0.07 ng/g and 0.09 ng/g, which are below the maximum residue limits established in many countries.

• Applied Chemistry for Engineering
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• v.4 no.3
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• pp.583-590
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• 1993

O-Diethylaminoethyl chitosan containing weak cation exchange group had been synthesized. It was used to separate albumin and lysozyme as stationary phase in liquid chromatography column. The separation of acidic and basic dyes were preliminarily conducted to investigate the effect of polarity parameter of solvents. Based on this result, we investigated various factors on the separation efficiency of chromatography in column. In the case of using water-methanol as cosolvent, the resolution factor depended on the polarity parameter. The best resolution factor was 1.42 for DEAE-chitosan with the degree of substitution of 0.23.