• Title/Summary/Keyword: polymer battery

Search Result 328, Processing Time 0.032 seconds

Synthesis of Cross-Linked Polyurethane-Based Gel Polymer Electrolyte and Its Electrochemical Properties (가교형 폴리우레탄기 겔 폴리머 전해질의 합성과 전기화학적 특성)

  • Kim, Hyun-Soo;Kim, Sung-Il;Choi, Gwan-Young;Moon, Seong-In;Yun, Mun-Soo;Kim, Sang-Pil
    • Journal of the Korean Electrochemical Society
    • /
    • v.6 no.2
    • /
    • pp.98-102
    • /
    • 2003
  • Urethane acrylate oligomer was synthesized and used in a gel polymer electrolyte (GPE) and then its electrochemical performances were evaluated. $LiCoO_2/GPE/graphite$ cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing $5 vol\%$ curable mixture had a low viscosity relatively. ionic conductivity of the gel polymer electrolyte at room temperature and $-20^{\circ}C$ was ca. $5.9\times10^{-3}S{\cdot}cm^{-1}\;and\;1.4times10^{-3}S{\cdot}cm^{-1}$, respectively. GPE showed good electrochemical stability up to potential of 4.5V vs. RLi/Li^+.\;LiCoO_2/GPE/graphite$ cell showed a good high-rate and low-temperature performance.

Effects of Electrospinning Parameters on the Fiber Formation and Application (전기방사 조건에 따른 나노섬유상의 구조 및 응용)

  • RYU, HO SUK;PARK, JIN SOO
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.29 no.1
    • /
    • pp.71-80
    • /
    • 2018
  • Electrospinning is a versatile technique that utilizes electrostatic forces to produce very thin and fine fibers of polymer ranging from submicron to nanometer scale. The technique can be applied to fibers of a various polymer types. Working parameters in the electrospinning are very important to understand not only the nature of electrospinning but also the conversion of polymer solutions into nanofibers through electrospinning. Those parameters in the electrospinning can be broadly divided into three parts. The first parameter is solution parameters such as molecular weight of polymer, concentration, viscosity, surface tension and conductivity/surface charge density of solution. The second parameter is process such as voltage, distance between the collector and the tip of the syringe, shape of collectors, flow rate. The third parameter is ambient parameters such as humidity and temperature. Fibers which made by electrospinning with working parameters are applied for various fields according to shape such as medical, cloth, photodiode, a sensor technology, catalyst, filtration, battery etc.

Conductivity of PAN/PVDF based Polymer Electrolyte as a Function of Plasticizer Mixed Ratio (가소제 혼합비에 따른 PAN/PVDF계 고분자 전해질의 이온 전도 특성)

  • Lee, Jae-An;Kim, Jong-Uk;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.05b
    • /
    • pp.261-264
    • /
    • 2000
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. This paper describes temperature dependence of conductivity, impedance spectroscopy, electrochemical properties of PAN/PVDF electrolytes as a function of a mixed ratio. PAN/PVDF based polymer electrolyte films were prepared by thermal gellification method of preweighed PAN/PVDF, plasticizer and Li salt. By adding PVDF and as a function of plasticizer mixed ratio to PAN-LiClO4 electrolyte, its conductivity was higher than that of PAN-$LiClO4_4$ electrolyte. The conductivity of PAN/PVDF electrolytes was $10^{-3}S/cm$. $10PAN10PVDFLiClO_4PC_5EC_5$ electrolyte shows the better conductivity of the others. Steady state current method and ac impedance used for the determination of transference numbers in PAN/PVDF electrolyte film. The transference number of $10PAN10PVDFLiClO_4PC_5EC_5$ electrolyte is 0.45.

  • PDF

A Review of Structural Batteries with Carbon Fibers (탄소섬유를 활용한 구조용 배터리 연구 동향)

  • Kwon, Dong-Jun;Nam, Sang Yong
    • Applied Chemistry for Engineering
    • /
    • v.32 no.4
    • /
    • pp.361-370
    • /
    • 2021
  • Carbon fiber reinforced polymer (CFRP) is one of the composite materials, which has a unique property that is lightweight but strong. The CFRPs are widely used in various industries where their unique characteristics are required. In particular, electric and unmanned aerial vehicles critically need lightweight parts and bodies with sufficient mechanical strengths. Vehicles using the battery as a power source should simultaneously meet two requirements that the battery has to be safely protected. The vehicle should be light of increasing the mileage. The CFRP has considered as the one that satisfies the requirements and is widely used as battery housing and other vehicle parts. On the other hand, in the battery area, carbon fibers are intensively tested as battery components such as electrodes and/or current collectors. Furthermore, using carbon fibers as both structure reinforcements and battery components to build a structural battery is intensively investigated in Sweden and the USA. This mini-review encompasses recent research trends that cover the classification of structural batteries in terms of functionality of carbon fibers and issues and efforts in the battery and discusses the prospect of structural batteries.

Electrospinning Technology for Novel Energy Conversion & Storage Materials

  • Jo, Seong-Mu;Kim, Dong-Yeong
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2011.10a
    • /
    • pp.1.1-1.1
    • /
    • 2011
  • Electrospinning has known to be very effective tool for production of versatile one-dimensional (1D) nanostructured materials such as nanofibers, nanorod, and nanotubes and for easily assembly to two-, three-dimensional(2D, 3D) nanostructures such as thin film, membrane, and nonwoven web, etc. We have studied on the electrospinning technology for novel energy storage and conversion materials such as advanced separator, dye sensitized solar cell, supercapacitor, etc. High heat-resistive nanofibrous membrane as a new separator for future lithium ion polymer battery was prepared by electrospinning of PVdF based composite solution. The novel nanofibrous composite nonwovens have tensile strength of above 50 MPa and modulus of above 1.3 GPa. The internal structure of the electrospun composite nanofiber with a diameter of few hundreds nanometer were composed of core-shell nanostructure. And also electrospun $TiO_2$ nanorod/nanosphere based dye-sensitized solar cells with high efficiency are successfully prepared. Some battery performance will be introduced.

  • PDF

New Analysis of Electrochemical Impedance Spectroscopy for Lithium-ion Batteries

  • Osaka, Tetsuya;Nara, Hiroki;Mukoyama, Daikichi;Yokoshima, Tokihiko
    • Journal of Electrochemical Science and Technology
    • /
    • v.4 no.4
    • /
    • pp.157-162
    • /
    • 2013
  • First of all, we express our deepest sympathies for the passing of Professor Su-Moon Park. In the present paper, an electrochemical impedance spectroscopy (EIS), which Professor Su-Moon Park also used frequently for the investigation of electroconducting polymer, is introduced as a recent evaluation tool for a commercially available lithium-ion battery (LIB). The paper surveys how to design equivalent circuits while explaining physical and chemical phenomena in the LIB and how to get more accurate impedance spectra with varying the measuring temperatures. Additionally, a square current EIS (SC-EIS) technique, which we have suggested, is introduced for the larger LIB system as a promising technique for the future.

Study of Energy Consumption Efficiency of Electric Two-wheeled Vehicle by Change of Environment Variation (환경변화에 따른 전기이륜차의 에너지소비효율에 관한 연구)

  • Kil, Bum-Soo;Kim, Gang-Chul
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.20 no.2
    • /
    • pp.56-63
    • /
    • 2012
  • Environment has become a main issue nowadays. People began to show big interest in "futuristic means of transportation", which is an efficient method in $CO_2$ emissions reduction and decreasing use of oil. Due to the noise and emissions of two-wheel vehicle of internal combustion engine, electric two-wheeled vehicles have been supplied in downtown. The electric two-wheeled vehicles use battery as power source. The performance of lithium-ion battery changes as the ambient temperature changes. In this paper, analysis of performance variance of electric two-wheeled vehicles influenced by the temperature using the chassis dynamometer and the environmental chamber was carried out.

Current Collectors for Flexible Lithium Ion Batteries: A Review of Materials

  • Kim, Sang Woo;Cho, Kuk Young
    • Journal of Electrochemical Science and Technology
    • /
    • v.6 no.1
    • /
    • pp.1-6
    • /
    • 2015
  • With increasing interest in flexible electronic devices and wearable appliances, flexible lithium ion batteries are the most attractive candidates for flexible energy sources. During the last decade, many different kinds of flexible batteries have been reported. Although research of flexible lithium ion batteries is in its earlier stages, we have found that developing components that satisfy performance conditions under external deformation stress is a critical key to the success of flexible energy sources. Among the major components of the lithium ion battery, electrodes, which are connected to the current collectors, are gaining the most attention owing to their rigid and brittle character. In this mini review, we discuss candidate materials for current collectors and the previous strategies implemented for flexible electrode fabrication.

A Study on Efficient Charging Method to Extend the Life of Battery (배터리의 수명을 연장할 수 있는 효율적인 충전방법에 관한 연구)

  • Kim, Jae-Jin;Hur, Hwa-ra
    • Proceedings of the Korean Society of Computer Information Conference
    • /
    • 2017.07a
    • /
    • pp.390-391
    • /
    • 2017
  • 본 논문에서는 배터리의 수명을 연장할 수 있는 효율적인 충전방법에 대해 제안하였다. 제안된 방법은 우선 충전하고자 하는 배터리의 전압과 전류를 측정한다. 측정된 배터리의 전압과 같은 값에서 1.5배 값까지 단계적으로 전압을 상승시켜 배터리의 상태를 검사한다. 배터리의 반응 상태들 중에서 충전이 가장 안정적인 전압을 결정한다. 전압이 결정되면 배터리의 전류 값을 배터리 용량의 1/3에서 1/10까지 단계적으로 조율하여 충전을 하도록 한다. 이러한 방법은 배터리를 보호하면서 충전 시간을 축소시켜 효율적으로 배터리를 관리할 수 있는 방법이다. 제안된 방법의 효율성을 입증하기 위해 핸드폰 보조배터리로 가장 많이 사용되고 있는 리튬 폴리머 배터리를 이용하여 실험하였다. 실험 결과 충전시간의 감소와 안전성 등의 효율성이 입증되었다.

  • PDF

Effects of the composition and the pressing rate of electrode on the internal resistance and the battery characteristic (전극 조성 및 압착율에 의한 내부저항과 전지특성)

  • 정재국;진봉수;문성인;윤문수;남효덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.421-424
    • /
    • 2000
  • We have examined the impedance characteristics and the rate characteristics of LPB. As results, the impedance of LPB decreased with increased pressing rate of electrodes, adding amounts of PVdF and VGCF. And the rate characteristics of LPB increased with the a increase of pressure-rate, PVdF and VGCF contents. The rate characteristics of LPB was improved by pressing of electrode and adding of VGCF content. And specific capacity of anode was increased with adding amounts of PVdF. Higher pressing rate of electrodes, higher adding amounts of PVdF and VGCF was necessitated good rate characteristics for lithium polymer battery.

  • PDF