• Title/Summary/Keyword: polymer battery

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Development of a Radio Controlled Ornithopter 'Songgolmae' (무선조종 날개짓 비행체 '송골매' 개발)

  • Chang, Jo-Won
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1993-1998
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    • 2004
  • The present study was carried out to develop highly efficient RC ornithopter 'Songgolmae' powered by motor and battery. Designed electric ornithopter weighs 277 grams and has 3 channels radio control. 1t runs on an electric motor by a lithium polymer battery and has a gear ratio of about $75{\sim}95$ to 1 to flap its 88 cm wingspan. The aerodynamic performance of the ornithopter, applied to a flapping motion only, was validated by flight tests. Flight times have exceeded 23 minutes until the battery was used up. The flight test results indicate that the ornithopter developed here has sufficient thrust to propel itself in a forward flight. From the economical point of view and the handling of the RC ornithopter, it can be said that the developed robot ornithopter is an effective RC ornithopter. This radio controlled ornithopter flies its way high into the sky just like a real bird flies.

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Simulation of injection-compression molding for thin and large battery housing

  • Kwon, Young Il;Lim, Eunju;Song, Young Seok
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1451-1457
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    • 2018
  • Injection compression molding (ICM) is an advantageous processing method for producing thin and large polymeric parts in a robust manner. In the current study, we employed the ICM process for an energy-related application, i.e., thin and large polymeric battery case. A mold for manufacturing the battery case was fabricated using injection molding. The filling behavior of molten polymer in the mold cavity was investigated experimentally. To provide an in-depth understanding of the ICM process, ICM and normal injection molding processes were compared numerically. It was found that the ICM had a relatively low filling pressure, which resulted in reduced shrinkage and warpage of the final products. Effect of the parting line gap on the ICM characteristics, such as filling pressure, clamping force, filling time, volumetric shrinkage, and warpage, was analyzed via numerical simulation. The smaller gap in the ICM parting line led to the better dimensional stability in the finished product. The ICM sample using a 0.1 mm gap showed a 76% reduction in the dimensional deflection compared with the normal injection molded part.

Electrochemical Properties of PVdF Gel Polymer Electrolyte with Plasticizer for Lithium/sulfur Battery (리튬 유황 전지용 PVdF 겔 고분자 전해질의 가소제에 따른 전기화학적 특성 평가)

  • Ryu, Ho-Suk;Kim, Jong-Seon;Kim, Dong-Ju;Kim, Dong-Yeon;Kim, Ic-Pyo;Ahn, Hyo-Jun;Kim, Ki-Won;Ahn, Jou-Hyeon;Lee, Gun-Hwan
    • Journal of the Korean Electrochemical Society
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    • v.10 no.3
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    • pp.213-218
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    • 2007
  • In order to find out proper PVdF gel polymer electrolyte for Li/S battery, we investigated PVdF gel polymer electrolytes with various glyme type plasticizer such as polyglyme, tetraglyme, triglyme. The organic solvents as triglyme, tetraglyme, polyglyme (Mn = 250, 500) has different chain length of ethylene oxide(EO) in solvent of glyme system. ionic conductivity decreased as increasing chain length of EO in plasticizers. Ionic conductivity of PVdF gel electrolyte with tetraglyme, triglyme, polyglyme (Mn = 250, 500) at room temperature was $5{\times}10^{-4},\;3{\times}10^{-4},\;6{\times}10^{-5},\;3{\times}10^{-5}\;S/cm$, respectively. Li/S cell with PVdF gel polymer electrolyte using tetraglyme plasticizer had low interfacial resistance and the highest initial discharge capacity of 1232 mAh/g of active sulfur, which was about 70% utilization of theoretical value.

Cycling Performance of Li4Ti5O12 Electrodes in Ionic Liquid-Based Gel Polymer Electrolytes

  • Kim, Jin-Hee;Kang, Yong-Ku;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.608-612
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    • 2012
  • We investigated the cycling behavior of $Li_4Ti_5O_{12}$ electrode in a cross-linked gel polymer electrolyte based on non-flammable ionic liquid consisting of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and vinylene carbonate. The $Li_4Ti_5O_{12}$ electrodes in ionic liquid-based gel polymer electrolytes exhibited reversible cycling behavior with good capacity retention. Cycling data and electrochemical impedance spectroscopy analyses revealed that the optimum content of the cross-linking agent necessary to ensure both acceptable initial discharge capacity and good capacity retention was about 8 wt %.

Thermally Crosslinked Polyimide Binders for Si-alloy Anodes in Li-ion Batteries

  • Chang, Hyeong-Seok;Ji, Sang-Gu;Rho, Miso;Lee, Byoung-Min;Kim, Sung-Soo;Choi, Jae-Hak
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.339-346
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    • 2022
  • Silicon (Si) has attracted considerable attention due to its high theoretical capacity compared to conventional graphite anode materials. However, Si-based anode materials suffer from rapid capacity loss due to mechanical failure caused by large volume change during cycling. To alleviate this phenomenon, crosslinked polymeric binders with strong interactions are highly desirable to ensure the electrode integrity. In this study, thermally crosslinked polyimide binders were used for Si-alloy anodes in Li-ion batteries. The crosslinked polyimide binder was found to have high adhesion strength, resulting in enhanced electrode integrity during cycling. Therefore, the Si-alloy anodes with crosslinked polyimide binder provide enhanced electrochemical performance, such as Coulombic efficiency, capacity retention, and cycle stability.

Synthesis of Organic Radical Copolymers Based on Polystyrene and Their Performance for Batteries (폴리스티렌 기반 유기 라디칼 공중합체의 합성과 전지특성)

  • Yang, Eui-Seok;Ryu, Sang-Woog
    • Journal of the Korean Electrochemical Society
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    • v.19 no.4
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    • pp.141-147
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    • 2016
  • In this study, homo and copolymers of 2,2,6,6-tetramethyl-4-piperidyl methacrylate(TMA) and synthesized styrene derivative, 2,2,6,6-tetramethylpiperidine-4-vinylbenzyl ether(TVBE) were obtained by radical polymerization and oxidized to produce corresponding polymer radicals. The polymer radicals were mixed with carbon black, binders and coated onto Al current collector. The battery performance is then characterized by fabricating coin cells. As results, the polystyrene based organic radicals show lower oxidize efficiency and discharge capacity than methacrylate based one. However, the former shows better capacities from discharge experiments performed at $60^{\circ}C$ which suggests a possible way to overcome the high temperature fade out of performance in usual organic radical batteries. Also as expected, an excellent C-rate performance is observed in all the cells consisted of organic polymer radicals.

Fabrication and Characterization of Thermal Battery using Porous MgO Separator Infiltrated with Li based Molten Salts

  • Kim, Kyungho;Lee, Sungmin;Im, Chae-Nam;Kang, Seung-Ho;Cheong, Hae-Won;Han, Yoonsoo
    • Journal of Powder Materials
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    • v.24 no.5
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    • pp.364-369
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    • 2017
  • Ceramic powder, such as MgO, is added as a binder to prepare the green compacts of molten salts of an electrolyte for a thermal battery. Despite the addition of a binder, when the thickness of the electrolyte decreases to improve the battery performance, the problem with the unintentional short circuit between the anode and cathode still remains. To improve the current powder molding method, a new type of electrolyte separator with porous MgO preforms is prepared and characteristics of the thermal battery are evaluated. A Spherical PMMA polymer powder is added as a pore-forming agent in the MgO powder, and an organic binder is used to prepare slurry appropriate for tape casting. A porous MgO preform with $300{\mu}m$ thickness is prepared through a binder burnout and sintering process. The particle size of the starting MgO powder has an effect, not on the porosity of the porous MgO preform, but on the battery characteristics. The porosity of the porous MgO preforms is controlled from 60 to 75% using a pore-forming agent. The batteries prepared using various porosities of preforms show a performance equal to or higher than that of the pellet-shaped battery prepared by the conventional powder molding method.

Preparation and Electrochemical Performances Comparison of Carbon and Hydrogel Electrocatalysts for Seawater Battery (해수 전지용 탄소계 촉매와 Hydrogel 촉매의 제조 및 이들의 전기화학적 특성 비교)

  • Kim, Kyoungho;Na, Young Soo;Lee, Man Sung
    • Journal of the Korean Electrochemical Society
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    • v.21 no.4
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    • pp.61-67
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    • 2018
  • As emerging the new electric devices, the commercial lithium ion batteries have faced with various challenges. In this regard, many efforts to solve challenges have been tried. In order to solve the above problems in terms of development of a new secondary battery, we successfully demonstrated the two electrocatalysts, such as MCWB and PPY hydrogel, PPY hydrogel and MCWB showed typical H3-type BET isotherm, indicating that micro- and mesopores existed. Especially, in terms of voltage efficiency at the first cycle, PPY hydrogel was higher than that of MCWB, but lower than that of PtC. More interestingly, the PPY hygrogel based seawater battery exhibited charge-discharge reversibility during 20 cycles, and the voltage efficiencies ranged from 70.32 % to 77.35 % in cyclic performance test.