• Applied Chemistry for Engineering
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• v.26 no.4
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• pp.458-462
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• 2015

It is essential to employ a binder to prepare transparent films from conductive polymer such as poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT/PSS). In this paper, poly(vinyl alcohol) (PVA), poly(vinyl pyrrolidone) (PVP), and PSS were selected as a binder, and their effects were investigated. The formation of the film was found to be primarily dependent on the surface tension of coating solution including PEDOT/PSS and a binder. When PSS was used as a binder, the film was not formed. In case of using PVP, it was easily peeled off from the substrate. However, when using the PVA or the mixtures of PVA and PSS or PVA and PVP as a binder, films with good transparency and uniform surface resistances were produced. Based on adhesion and long-term stability tests, we concluded that the mixture of PVA and PSS is the best binder for preparing antistatic films of PEDOT/PSS.

• Applied Chemistry for Engineering
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• v.25 no.6
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• pp.581-585
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• 2014

We conducted investigation on the hybridization of poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate) (PEDOT : PSS) with graphene derivative (G-PSS), which has been prepared by wrapping reduced graphene oxide (RGO) with PSS. In situ polymerization of PEDOT/PSS in the presence of G-PSS afforded the PEDOT/PSS and graphene hybrid (GP). The analysis of XPS, IR and Raman spectroscopies for GP showed that PEDOT/PSS was successfully synthesized and hybridized with graphene. Compared to the G-PSS, GP showed an enhanced electrical conductivity of $4.46{\times}10^2S/m$ with a good wter-dispersity.

• Polymer(Korea)
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• v.33 no.5
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• pp.452-457
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• 2009

Hybrid nanomaterials consisting of multi-walled carbon nanotube(MWNT) and/or PEDOT of conductive polymer were prepared in this study. In the presence of catalyst and ligand, the MWNT-Br compound prepared by the successive surface treatment reaction was mixed with MMA to initiate the atom transfer radical polymerization process. PMMA was covalently linked to the surface of MWNT for the formation of MWNT/PMMA nanocomposites. The EDOT and oxidant were added in the aqueous emulsion of PS produced via a miniemulsion polymerization process and then it proceeded to carry out the oxidative chemical polymerization of EDOT for the preparation of PEDOT/PS nanoparticles with the core-shell structure. The aqueous dispersion of PEDOT:poly(styrene sulfonate) (PSS) was mixed with the silica particles treated with a silane compound and thus PEDOT:PSS-clad silica nanoparticles were prepared by the surface chemistry reaction. The hybrid nanomaterials were analyzed by using TEM, FE-SEM, TGA, EDX, UV, and FT-IR.

• Applied Chemistry for Engineering
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• v.26 no.6
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• pp.640-647
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• 2015

As the need for next-generation flexible electronics grows, novel materials and technologies that can replace conventional indium tin oxide (ITO) for transparent electrodes have been of great interest. Among them, a conducting polymer, especially poly(3,4-ethylenedioxythiophene) : poly(styrene sulfonate) (PEDOT : PSS) is one of the most promising candidates because it is mechanically flexible, inexpensive, and capable of being processed in solution. Currently, there are a lot of research efforts on enhancing its electrical conductivity to the level of ITO or metal electrodes through chemical and/or physical processing. In this review article, we present various additives and pre-/post-deposition processing methods for improving the electrical conductivity of PEDOT : PSS. Some of representative reports are also introduced, which demonstrated the use of conductivity-enhanced PEDOT : PSS as transparent electrodes in electronics and energy conversion.

• 한국정보디스플레이학회:학술대회논문집
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• 2002.08a
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• pp.766-769
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• 2002

We have seen the effects of hole-injection buffer layer in organic light-emitting diodes using copper phthalocyanine(CuPc), poly(vinylcarbazole)(PVK), and Poly(3,4-ethylenedioxythiophene):poly(styrene-sulfonate)(PEDOT:PSS) in a device structure of ITO/buffer/TPD/$Alq_3$/Al. Polymer PVK and PEDOT:PSS buffer layer was made using spin casting method and the CuPc layer was made using thermal evaporation. Current-voltage characteristics, luminance-voltage characteristics and efficiency of device were measured at room temperature with a thickness variation of buffer layer. We have obtained an improvement of the external quantum efficiency by a factor of two, four, and two and half when the CuPc, PVK, and PEDOT:PSS buffer layer are used, respectively. The enhancement of the efficiency is attributed to the improved balance of holes and elelctrons due to the use of hole-injection buffer layer. The CuPc and PEDOT:PSS layer functions as a hole-injection supporter and the PVK layer as a hole-blocking one.

• Korean Chemical Engineering Research
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• v.47 no.4
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• pp.418-423
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• 2009

MWCNT(multi-wall carbon nanotube)-doped PEDOT:PSS(poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)), used as a HIL(hole injection layer) material in OLEDs(organic light emitting diodes), was spin-coated on to the ITO glass to form PEDOT:PSS-MWCNT nano composite thin film. Morphology and transparency characteristics of nano composite thin films with respect to the loading percent of MWCNT have been investigated using FT-IR, UV-Vis and SEM. Furthermore, ITO/PEDOT:PSS-MWCNT/NPD/$Alq_3$/Al devices were fabricated, and then J-V and L-V characteristics were investigated. Functional group-incorporated MWCNT was prepared by acid treatment and showed good dispersion property in PEDOT:PSS solution. PEDOT:PSS-MWCNT thin films possessed good transparency property. For multi-layered devices, it was shown that as the loading percent of MWCNT increased, the current density increased but the luminance dramatically decreased. It might be conclusively suggested that the enhanced charge mobility by MWCNT could increase the current density but the hole trapping property of MWCNT could dramatically decrease the hole mobility in the current devices.

• Applied Chemistry for Engineering
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• v.27 no.1
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• pp.45-49
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• 2016

In the presence of poly(4-styrene sulfonate) (PSS) and excess amount of graphene oxide (GO), we conducted in-situ polymerization of 3,4-ethylenedioxythiophene (EDOT) without an oxidant. XPS and IR spectroscopies of the product (GO-P) showed that PEDOT/PSS was successfully synthesized by oxidative polymerization of EDOT and hybridized with GO. GO-P displayed a stable aqueous suspension, however, the high content (42%) of GO in GO-P diminished electrical conductivity down to $15S{\cdot}m^{-1}$. Annealing of GO-P films at $200^{\circ}C$ for 8 hr induced partial reduction of GO and finally enhanced electrical conductivity up to $212S{\cdot}m^{-1}$.

• Applied Chemistry for Engineering
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• v.27 no.4
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• pp.402-406
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• 2016

In order to investigate the thermal stability of electro-conductive poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT/PSS), we have prepared films by casting PEDOT/PSS aqueous solution without using a binding material and measured surface resistances of the films while annealing at $200^{\circ}C$. Electrical properties of films were improved by annealing, and the maximum conductivity ($540S{\cdot}m^{-1}$) after annealing for 2 hrs was found to be approximately 3 times higher than that ($180S{\cdot}m^{-1}$) of the original film. The conductivities, however, dramatically decreased with an increase in annealing time and dissipated after 24 hrs of annealing. On the other hand, PEDOT/PSS films hybridized with graphene oxide (GO) displayed a salient improvement in conductivity by annealing, which was measured to be around $600S{\cdot}m^{-1}$ even after 30 hrs of annealing at $200^{\circ}C$. We tentatively conclude that hybridization with GO enhances the thermal stability of PEDOT/PSS.

• Proceedings of the Korean Society Of Semiconductor Equipment Technology
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• 2006.10a
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• pp.154-157
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• 2006

ITO(indium tin oxide)/glass 기판 위에 PEDOT:PSS[poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)]와 PVK[poly(N-vinyl carbazole)] 고분자 물질을 정공 주입 및 수송층으로, 발광층으로 PFO-poss[Poly(9,9-dioctylfluorenyl-2,7-diyl) end capped with POSS]를 사용하여 스핀코팅법과 열 증착법으로 ITO/PEDOT:PSS/PVK/PFO-poss/LiF/Al 구조의 고분자 발광 다이오드를 제작하였다. PFO-poss 유기발광 층의 열처리 조건 (온도, 시간)이 PLED 소자의 전기적, 광학적 특성에 미치는 영향을 조사하였다. 1 wt%의 농도를 갖는 PFO-poss 유기물 발광 층을 200C 온도로 3시간 열처리 할 경우 11 V 인가전압에서 $1497\;cd/m^2$의 최대 휘도를 나타내었다. 동일온도에서 열처리 시간을 1시간에서 3시간으로 증가시킬 경우 휘도의 증가와 함께 발광 개시온도가 감소하는 경향을 보여주었다. 또한 열처리 온도와 시간을 증가시킬 경우 제2발광피크인 excimer 피크가 크게 나타났으며 청색에서 황색 발광 쪽으로 천이되는 경향을 나타내었다.

• Applied Chemistry for Engineering
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• v.29 no.6
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• pp.734-739
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• 2018

We successfully coated poly(3,4-ethylenedioxythiophene) : poly(styrene sulfonate) (PEDOT : PSS) on CVD graphene by adding poly(vinyl alcohol) (PVA) to PEDOT : PSS. Extensive studies on the wettability of coating solutions and electrical properties of formed films led us to conclude that PVA with 89% of the degree of saponification and the molecular weight of less than $100,000gmol^{-1}$ produced optimum results. Furthermore, the optimum content of PVA was found to be 5% of PEDOT : PSS by the solid weight. The film coated by PEDOT : PSS with PVA on CVD graphene displayed a conspicuous improvement in the surface roughness, adhesive property, bending durability and stability in resistance at $160^{\circ}C$, compared to those of using CVD graphene films.